Preparation and Luminescence of Yttrium Aluminoborate Doped with Eu 3+ Ions

Chin J Mater Res

2010, Vol. 24

Issue (2): 213-216 DOI:

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Preparation and Luminescence of Yttrium Aluminoborate Doped with Eu ³⁺ Ions

JIA Linyan^1;2; SHAO Zhongbao²

1.Mudanjiang Normal University; Mudangjiang 157012
2.College of science; Northeastern University; Shenyang 110004

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JIA Linyan SHAO Zhongbao. Preparation and Luminescence of Yttrium Aluminoborate Doped with Eu ³⁺ Ions. Chin J Mater Res, 2010, 24(2): 213-216.

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Abstract

The red phosphor yttrium aluminoborate doped with Eu ³⁺ was prepared by high temperature ball milling method. The phosphor was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and luminescence spectroscopy. The results show that Y ³⁺ ions are replaced by Eu ³⁺ ions in view of their similar sizes and valence state, the Eu ³⁺ ions are non-centrosymmetric sites in YAl₃(BO₃)₄:Eu³⁺.The synthesis temperature of high temperature ball milling method is 700^oC , which is obviously decreased in contrast to that of nitrate salts decomposition method (900^oC ) and conventional solid state reaction method (1200^oC ). The particles are approximately nanometer-sized with narrow distribution range and spherical morphology. In the emission spectra under 394 nm excitation, the strongest peak at 618 nm is due to the forced electric dipole transition ⁵D_0→ ⁷F₂ of Eu ³⁺ ions.

Key words: inorganic non-metallic materials luminescence high temperature ball milling YAl₃(BO₃)₄Eu³⁺

Received: 10 December 2009

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https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2010/V24/I2/213

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