Preparation and friction properties of two short chain self-assembled monolayers on titanium metal films

Chin J Mater Res

2009, Vol. 23

Issue (1): 6-12 DOI:

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Preparation and friction properties of two short chain self-assembled monolayers on titanium metal films

SUN Changguo; ZHANG Huichen; GAO Yuzhou

Department of Mechanical Engineering; Dalian Maritime University; Dalian 116026

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SUN Changguo ZHANG Huichen GAO Yuzhou. Preparation and friction properties of two short chain self-assembled monolayers on titanium metal films. Chin J Mater Res, 2009, 23(1): 6-12.

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Abstract

Two kinds of self-assembled monolayers (SAMs) with same length of molecule chain and different functional groups are prepared on titanium metal film by self-assembled method and radiated by ultraviolet radiation treatment for different times. The characterization and friction properties measurement of titanium metal film and SAMs are explored. The effects of ultraviolet radiation, functional groups, sliding velocity and load on friction properties of SAMs are investigated. The results show that compact SAMs can be prepared by hydroxylation in titanium film surface with ultraviolet radiation, hydrolysis and condensation of self-assembled molecules. Two kinds of short chain SAMs can reduce friction and the friction properties of APS SAMs is better than MPS SAMs, The friction force of SAMs with 5 min ultraviolet radiation is the lowest because the organic contamination at surface is vaporized which results in decrease of the adhesive force to tip and deformation of tip reduced. Lubrication effects of SAMs with 15 min ultraviolet radiation are weakened because of the destroy of compact net structure of SAMs. The friction forces increase slightly with the increasing of sliding velocity and decrease with the increasing of load, but change not significantly.

Key words: organic polymer materials surface and interface in the materials friction self-assembled monolayers(SAMs) titanium metal film

Received: 11 March 2008

ZTFLH:

TB324

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Supported by National Natural Science Foundation of China No.50275015.

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https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2009/V23/I1/6

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