Synthesis and Mechanical Properties of Ti-Zr-Cu-Pd-Mo Amorphous Alloy Based Composites with In-situ Autogenous β-Ti Phase

doi:10.11901/1005.3093.2023.227

Chinese Journal of Materials Research

2024, Vol. 38

Issue (2): 105-110 DOI: 10.11901/1005.3093.2023.227

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Synthesis and Mechanical Properties of Ti-Zr-Cu-Pd-Mo Amorphous Alloy Based Composites with In-situ Autogenous β-Ti Phase

YU Sheng¹, GUO Wei¹^,²^,³(

), LV Shulin¹, WU Shusen¹

^1.State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
^2.Research Institute of Huazhong University of Science and Technology in Shenzhen, Shenzhen 518057, China
^3.State Key Laboratory for Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049, China

Cite this article:

YU Sheng, GUO Wei, LV Shulin, WU Shusen. Synthesis and Mechanical Properties of Ti-Zr-Cu-Pd-Mo Amorphous Alloy Based Composites with In-situ Autogenous β-Ti Phase. Chinese Journal of Materials Research, 2024, 38(2): 105-110.

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Abstract

Ti-based amorphous alloys possess excellent properties such as low density, good biocompatibility and high corrosion resistance, which makes them one kind of promising materials used as biomedical materials. However, the room-temperature brittleness of Ti-based amorphous alloys limits their application. In order to improve the room-temperature plasticity of Ti-based amorphous alloys, the present study, a small amount of Mo (a β-Ti stabilizing element) is added to the Ti₄₀Zr₁₀Cu₃₆Pd₁₄ amorphous alloy so that the plastic β-Ti phase particles may be precipitated in-situ within the alloy during the solidification process. It is expected that in the subsequent deformation process, the plastic β-Ti phase can effectively impede the rapid propagation of the main shear band in the matrix, causing deflects, branching or multiplication of it. The multiple shear bands significantly improved the room-temperature mechanical properties. Finally, the optimal room-temperature mechanical properties were obtained for the amorphous alloy (Ti_0.4Zr_0.1Cu_0.36Pd_0.14)₉₅Mo₅which showed the fracture strength of 2630 MPa and plastic strain of 7.3%, namely 32.0% and 508% higher than that of the base alloy, respectively.

Key words: metallic materials amorphous alloy matrix composites room-temperature plasticity shear band

Received: 18 April 2023

ZTFLH:

TG146.2

Fund: National Natural Science Foundation of China(52101138);Shenzhen Science and Technology Program(JCYJ20220530160813032);State Key Lab of Advanced Metals and Materials(2020-Z01);State Key Laboratory for Mechanical Behavior of Materials(20202205);Guangdong Basic and Applied Basic Research Foundation(2020A1515110531)

Corresponding Authors: GUO Weil, Tel: 18627710273, E-mail: weiguo@hust.edu.cn

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https://www.cjmr.org/EN/10.11901/1005.3093.2023.227 OR https://www.cjmr.org/EN/Y2024/V38/I2/105

Fig.1 XRD patterns of Ti-based amorphous composites

Fig.2 SEM images of samples at different Mo contents (a) Mo0; (b) Mo1; (c) Mo2 and (d) distribution of Mo element in (c) -plot

Fig.3 SEM images of Mo5 specimens (a) and corresponding elemental face sweeps of Ti (b), Zr (c), Cu (d), Pd (e) and Mo (f)

Fig.4 Room temperature compression true stress-strain curves for specimens with different Mo contents

Table 1 Young′s modulus E, fracture strength σ_f, yield strength σ_y, fracture strain ε_f, yield strain ε_p and work hardening index n of Ti-based amorphous composites with different Mo contents

Fig.5 Compression fractures of the samples with different Mo contents and their lateral SEM images (a, b) Mo0; (c, d) Mo5

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