Preparation and Performance of TiS3 Nanoflakes as Anode Material for Lithium-ion Batteries

doi:10.11901/1005.3093.2021.281

Chinese Journal of Materials Research

2022, Vol. 36

Issue (11): 821-828 DOI: 10.11901/1005.3093.2021.281

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Preparation and Performance of TiS₃ Nanoflakes as Anode Material for Lithium-ion Batteries

XIAO Lan, YU Wenhua, HUANG Hao(

), WU Aimin, JIN Xiaozhe

Key Laboratory of Energy Materials and Devices (Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China

Cite this article:

XIAO Lan, YU Wenhua, HUANG Hao, WU Aimin, JIN Xiaozhe. Preparation and Performance of TiS₃ Nanoflakes as Anode Material for Lithium-ion Batteries. Chinese Journal of Materials Research, 2022, 36(11): 821-828.

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Abstract

TiH_1.924 nanometer powder was prepared by DC arc method, and then taking TiH_1.924 as precursor,TiS₃ nanometer flakes with laminar structure was prepared by solid-gas reaction. The structure and performance of TiS₃ nanoflakes as anode material for lithium-ion batteries were characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), atomic force microscopy (AFM), Raman spectroscopy and performance testing. The performance of TiS₃ nanoflakes as anode for lithium-ion battery was also investigated. The results show that the TiS₃ nanoflake has a special nano-laminar structure, and its thickness is about 35 nm. The lithium-ion battery using TiS₃ nanoflakes as anode material has good electrochemical performance with the remained capacity of 430 mAh/g after 300 cycles at a current density of 500 mA/g. When the current density is 5 A/g the discharge capacity is 240 mAh/g and when the current density is restored to 100 mA/g, the discharge capacity is stable at 500 mAh/g. The good magnification properties of TiS₃ are due to its special nano-flake structure. The mono-laminar structure can better adapt to the volume change caused by the strain in the process of multiple discharge/charging at high current density, so as to prevent the electrode from crushing.

Key words: inorganic non-metallic materials TiS₃ DC arc discharge lithium-ion battery cathode nano materials

Received: 30 April 2021

ZTFLH:

O646

Fund: Fundamental Research Funds for the Central Universities(DUT20LAB123);Natural Science Foundation of Jiangsu Province(BK20191167)

About author: HUANG Hao, Tel: 13700111620, E-mail: huanghao@dlut.edu.cn

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	Lan XIAO
	Wenhua YU
	Hao HUANG
	Aimin WU
	Xiaozhe JIN

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.281 OR https://www.cjmr.org/EN/Y2022/V36/I11/821

Fig.1 Crystalline structure of TiS₃

Fig.2 XRD patterns of TiH_1.924 (a) and TiS₃ (b)

Fig.3 Raman spectra of TiS₃ nanosheets

Fig.4 SEM (a) and TEM images (c) of TiH_1.924 and SEM (b) and TEM images of TiS₃ (d, e)

Fig.5 TEM (a) andAFM images (b) of TiS₃ andthe thickness of TiS₃ nanosheets (c~d)

Fig.6 Cycling performance of TiS₃ nano powder at 500 mA/g (a) and rate performance (b) of TiS₃ nanosheet

Fig.7 SEM image of TiS₃ electrode (a) before cycle， (b) after 500 cycles

Fig.8 Charge/discharge voltage-specific capacity curves of TiS₃ nano powder (a) and cyclic voltammograms of TiS₃ nano powder (b)

Fig.9 Ex situ XRD pattern from 5° to 55° of TiS₃ electrodes at different discharge-charge states

Fig.10 EIS curves of the TiS₃ electrode after different number of cycles (a) before cycle、1^st cycle、5^th cycle, (b) before cycle、10^thcycle、20^th cycle、50^th cycle

Fig.11 Equivalent analog circuits of TiS₃ electrode before cycle (a) and after cycle (b)

Table 1 Equivalent circuit parameters of TiS₃ nanoparticles electrode

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