Synthesis of Nano-Pd Particles in a Quaternary System with a Hexagonal Liquid Crystal as Template and Their Electrocatalytic Activity for Oxidation of Ethanol

doi:10.11901/1005.3093.2013.869

Chinese Journal of Materials Research

2014, Vol. 28

Issue (6): 413-419 DOI: 10.11901/1005.3093.2013.869

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Synthesis of Nano-Pd Particles in a Quaternary System with a Hexagonal Liquid Crystal as Template and Their Electrocatalytic Activity for Oxidation of Ethanol

Yanli WANG^1,^**(

),Dexin TAN²,Sen CHEN¹,Ling BIAN¹

1. Institute of Materials Science and Engineering, Anhui University of Science and
Technology, Huainan 232001
2. Institute of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001

Cite this article:

Yanli WANG,Dexin TAN,Sen CHEN,Ling BIAN. Synthesis of Nano-Pd Particles in a Quaternary System with a Hexagonal Liquid Crystal as Template and Their Electrocatalytic Activity for Oxidation of Ethanol. Chinese Journal of Materials Research, 2014, 28(6): 413-419.

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Abstract

Nano-Pd catalyst have been synthesized by slow reduction of Pd²⁺ in a quaternary system of brine-cyclohexane-surfactant-cosurfactant with a hexagonal lyotropic liquid crystal as template in a dark place under soft condition. Then the synthesized Pd nano-particles were characterized by optical microscopy、XRD、TEM、and HRTEM with selected area electron diffraction (SAED). The electrocatalytic properties of the nano-Pd modified glassy carbon electrode (Pd/GCE) for ethanol oxidation had been also investigated by cyclic voltammetry. The results show that the synthesized nano-Pd particles after reaction for 24 h show more or less the same shape with regular morphology with a mean size of (31±1) nm. This material exhibits the excellent electrocatalytic activity and anti-poisoning ability for the ethanol oxidation.

Key words: metallic materials hexagonal mesophases palladium ethanol electrocatalysis

Received: 19 November 2013

Fund: *Supported by the National Natural Science Foundation of China No. 51303005, the Educational Commission of Anhui Province of China No. KJ2013A087 & KJ2013A095, and the Doctor Foundation of the Anhui University of Science and Technology.

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	Yanli WANG
	Dexin TAN
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	Ling BIAN

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https://www.cjmr.org/EN/10.11901/1005.3093.2013.869 OR https://www.cjmr.org/EN/Y2014/V28/I6/413

Fig.1 The phase diagrams (weight percent) of SDS/water (brine)//n-C₅H₁₁OH/cyclohexane

Fig.2 Optical microscopy pictures of lyotropic liquid crystal texture of (a) A₁, (b) A₂, (c) A₃, (d) A₄ and (e) A₅ in Fig.1

Fig.3 Low-angel XRD spectra of sample. (a) A₃ and (b) A₃with PdCl₂

Fig.4 XRD spectra for nano-Pd

Fig.5 TEM images of nano-Pd: (a) TEM image and the corresponding SAED pattern; (b) high-magnification TEM image; (c) HRTEM image of nano-Pd

Fig.6 TEM images of nano-Pd. (a) 8 h; (b) 12 h; (c) 18 h; (d) 24 h

Fig.7 Cyclic voltammograms (CV) of ethanol at different electrodes

Table 1 Data analysis of cyclic voltammetric curves for different electrodes

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