Please wait a minute...
材料研究学报  2009, Vol. 23 Issue (2): 158-164    
  研究论文 本期目录 | 过刊浏览 |
低Re含量第二代柱晶高温合金DZ59的蠕变断裂性能
赵坦1;2; 张匀2; 陈光1; 楼琅洪2
1.南京理工大学 南京 210094
2.中国科学院金属研究所 沈阳110016
The creep rupture properties of a low Re content second-generation directionally solidified superalloy DZ59
ZHAO Tan1;2;   ZHANG Yun2;   CHEN Guang1;   LOU Langhong2
1.School of Materials Science and Engineering; Nanjing University of Science and Technology; Nanjing 210094
2.Institute of Metal Research; Chinese Academy of Sciences; Shenyang 110016
引用本文:

赵坦 张匀 陈光 楼琅洪. 低Re含量第二代柱晶高温合金DZ59的蠕变断裂性能[J]. 材料研究学报, 2009, 23(2): 158-164.
, , . The creep rupture properties of a low Re content second-generation directionally solidified superalloy DZ59[J]. Chin J Mater Res, 2009, 23(2): 158-164.

全文: PDF(1379 KB)  
摘要: 

采用液态金属冷却(LMC)工艺和成分优化设计, 制备出一种高温性能优异的低Re含量第二代柱晶高温合金DZ59, 通过扫描电镜(SEM), 透射电镜(TEM)等方法对其组织特征及蠕变断裂进行了表征, 研究了合金的蠕变断裂性能. 结果表明, DZ59合金的高温蠕变断裂性能超过一代单晶合金, 并接近二代单晶合金的水平. 发现柱晶高温合金的二次晶界反应(SGRZ)现象, 表明SGRZ受温度和应力的控制, 由于增加了合金横向晶界的受力界面, 在高负荷下可能成为蠕变空洞萌生和扩展的位置.

关键词 金属材料第二代定向柱晶 蠕变断裂 二次晶界反应区拓扑密排相(TCP)    
Abstract

Assisted by the advanced LMC process and an optimum composition design, a highperformance second-generation directionally solidified superalloy DZ59 with low Re content has been developed. The high temperature creep properties of the superalloy are better than first-generation single crystal alloys and is close to the level of second-generation single crystal alloys. The microstructure and creep rupture feature of the DZ59 alloy have been analysed in detail by SEM and TEM. The SGRZ was first discovered in the second-generation directionally solidified superalloys. The results showed that SGRZ is controlled by the temperature and stress. Because SGRZ increases the area of transverse grain boundary, creep voids may initiate and propagate in the SGRZ location under high stress.

Key wordsmetallic materials    2nd generation DS superalloy    creep rupture    second grain reaction zone(SGRZ)    TCP phase
收稿日期: 2008-10-17     
ZTFLH: 

TG111

 
1 ZHENG Yunrong, HAN Yafang, Cost considerations of single crystal superalloys for gas tubine, Acta Metall Sin., 38(11), 1203(2002) (郑运荣, 韩雅芳, 燃气涡轮单晶高温合金的成本因素, 金属学报,  38(11), 1203(2002)) 2 K.Harris, G.L.Erickon, S.L.Sikkenga, W.D.Brentnall, J.M.Aurrecoechea, K.G.Kubarych, In Superalloys 1992, Development of the rhenium containing superalloys CMSX-4 & CM186LC for single crystal blade and directionally solidified vane applications in advanced turbine engines, Edited by S.D. Antolovich, R.W.Stusrud, R.A.Mackay, D.L.Anton, T.Khan, R.D.Kissinger, D.L.Klarstrom (The Minerals, Metals & Materials Society , Pennsylvania, 1992) p.297 3 A.D.Cetel, D.N.Duhl, In Superalloys 1992, Second generation columnar grain nikel-base superalloy, Edited by S.D.Antolovich, R.W.Stusrud, R.A.Mackay, D.L.Anton, T.Khan, R.D.Kissinger, D.L.Klarstrom (The Minerals, Metals & Materials Society, Pennsylvania, 1992) p.287 4 E.W.Ross, K.S.OHara, In Superalloys 1992, Rene142: A High strength, oxidation resistant DS turbine airfoil alloy, Edited by S.D.Antolovich, R.W.Stusrud, R.A.Mackay, D.L.Anton, T.Khan, R.D. Kissinger, D.L. Klarstrom (The Minerals, Metals & Materials Society, Pennsylvania, 1992) p.257 5 R.B¨urgel, J.Grossmann, O.L¨useberink, H.Mugurabi, F.Pyczak, R.F.Singer, A.Volek, In Superalloys 2004, Development of a new alloy for directional solidification of large industrial gas turbine blades, Edited by K.A.Green, T.M.Pollock, H.Harada, T.E.Howson, R.C.Reed, J.J.Schirra, S.Walston (The Minerals, Metals & Materials Society, Pennsylvania, 2004) p.25 6 CHENG Guohua, ZHAO Jingchen, SUN Jiahua, SHI Zhengxing, Effects of withdrawal rate on solidification precipitation and microstructure of single crystal Ni-base superalloy, Acta Metall Sin., 33(12), 1233(1997) (程国华, 赵京晨, 孙家华, 史正兴, 拉晶速率对单晶高温合金凝固析出行为及显微组织的影响, 金属学报, f 33(12), 1233(1997)) 7 J.Zhang, L.H.Lou, Directional solidification assisted by liquid metal cooling journal of material science and technology, 23, 289(2007) 8 A.J.Elliott, S.Tin, W.T.King, S.C.Huang, M.F.X.Gigliotti, Directional solidification of large superalloy castings with radiation and liquid-metal cooling, Metall.trans.A, 35A(10), 3221(2004) 9 ZHAO Tan, Research on a second generation directionally solidified Ni base superalloy DZ59, Ph. D thesis, Nanjing University of Science and Technology(2009) (赵坦, 第二代定向柱晶高温合金DZ59研究, 博士学位论文, 南京理工大学(2009)) 10 Pollock, T.M., The growth and elevated temperature stability of hegh refractory nikel-base single crystal, Mater Sci Eng.B, 32B, 255(1995) 11 W.S.Walston, J.C.Schaeffer, W.H.Murphy, In Superalloys 1996, A New type of microstructural instability in superalloys-SRZ, Edited by R.D.Kissnger, D.J.Deye, D.L.Abton, A.D.Cetel, M.V.Nathal, T.M.Pollock, D.A.Woodford (The Minerals, Metals & Materials Society ,Pennsylvania, 1996) p.9 12 O.Lavigne, C.Ramusat, S.Drawin, P.Caron, D.Boivin, J.L.Pouchou, In Superalloys 2004, Relationships between microstructural instabilities and mechanical behaviour in new generation nikel-based single crystal superalys, Edited by K.A.Green, T.M.Pollock, H.Harada, T.E.Howson, R.C.Reed, J.J.Schirra, S.Walston (The Minerals, Metals & Materials Society, Pennsylvania, 2004) p.667 13 Y.H.Kong, Q.Z.Chen, Effect of minor additions on the formation of TCP phases in modified RR2086 SX superalloys, Mater. Sci. Eng.A, 381 A, 143(2004) 14 C.M.F.Rae, M.S.Hook, R.C.Reed, The effect of TCP morphology on the development of aluminide coated superalloys, Mater. Sci. Eng.A, 396A, 231(2004) 15 CHEN Rongzhang, Development status of single crystal superalloys, Mater. Eng., 8, 1(1995) (陈荣章, 单晶高温合金的发展现状, 材料工程,   8, 1(1995))
[1] 毛建军, 富童, 潘虎成, 滕常青, 张伟, 谢东升, 吴璐. AlNbMoZrB系难熔高熵合金的Kr离子辐照损伤行为[J]. 材料研究学报, 2023, 37(9): 641-648.
[2] 宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125CO2 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[3] 赵政翔, 廖露海, 徐芳泓, 张威, 李静媛. 超级奥氏体不锈钢24Cr-22Ni-7Mo-0.4N的热变形行为及其组织演变[J]. 材料研究学报, 2023, 37(9): 655-667.
[4] 邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[5] 幸定琴, 涂坚, 罗森, 周志明. C含量对VCoNi中熵合金微观组织和性能的影响[J]. 材料研究学报, 2023, 37(9): 685-696.
[6] 欧阳康昕, 周达, 杨宇帆, 张磊. LPSOMg-Y-Er-Ni合金的组织和拉伸性能[J]. 材料研究学报, 2023, 37(9): 697-705.
[7] 徐利君, 郑策, 冯小辉, 黄秋燕, 李应举, 杨院生. 定向再结晶对热轧态Cu71Al18Mn11合金的组织和超弹性性能的影响[J]. 材料研究学报, 2023, 37(8): 571-580.
[8] 熊诗琪, 刘恩泽, 谭政, 宁礼奎, 佟健, 郑志, 李海英. 固溶处理对一种低偏析高温合金组织的影响[J]. 材料研究学报, 2023, 37(8): 603-613.
[9] 刘继浩, 迟宏宵, 武会宾, 马党参, 周健, 徐辉霞. 喷射成形M3高速钢热处理过程中组织的演变和硬度偏低问题[J]. 材料研究学报, 2023, 37(8): 625-632.
[10] 由宝栋, 朱明伟, 杨鹏举, 何杰. 合金相分离制备多孔金属材料的研究进展[J]. 材料研究学报, 2023, 37(8): 561-570.
[11] 任富彦, 欧阳二明. g-C3N4 改性Bi2O3 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[12] 王昊, 崔君军, 赵明久. 镍基高温合金GH3536带箔材的再结晶与晶粒长大行为[J]. 材料研究学报, 2023, 37(7): 535-542.
[13] 刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO2 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[14] 秦鹤勇, 李振团, 赵光普, 张文云, 张晓敏. 固溶温度对GH4742合金力学性能及γ' 相的影响[J]. 材料研究学报, 2023, 37(7): 502-510.
[15] 刘天福, 张滨, 张均锋, 徐强, 宋竹满, 张广平. 缺口应力集中系数对TC4 ELI合金低周疲劳性能的影响[J]. 材料研究学报, 2023, 37(7): 511-522.