SnO2@Ti3C2Tx 负极材料的制备及其应用

doi:10.11901/1005.3093.2021.443

材料研究学报

2022, Vol. 36

Issue (8): 602-608 DOI: 10.11901/1005.3093.2021.443

研究论文

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SnO₂@Ti₃C₂T_x 负极材料的制备及其应用

李玲芳¹(

), 原志朋², 范长岭²

^1.湖南文理学院机械工程学院常德 415000
^2.湖南大学材料科学与工程学院长沙 410082

Preparation of SnO₂@Ti₃C₂T_x and Its Application in Lithium Ion Battery as Anode Material

LI Lingfang¹(

), YUAN Zhipeng², FAN Changling²

^1.College of Mechanical Engineering, Hunan University of Arts and Science, Changde 415000, China
^2.College of Materials Science and Engineering, Hunan University, Changsha 410082, China

引用本文:

李玲芳, 原志朋, 范长岭. SnO₂@Ti₃C₂T_x 负极材料的制备及其应用[J]. 材料研究学报, 2022, 36(8): 602-608.
Lingfang LI, Zhipeng YUAN, Changling FAN. Preparation of SnO₂@Ti₃C₂T_x and Its Application in Lithium Ion Battery as Anode Material[J]. Chinese Journal of Materials Research, 2022, 36(8): 602-608.

全文: PDF(7257 KB) HTML

摘要:

通过超声辅助和低温热处理在二维Ti₃C₂T_x 纳米片层间原位生长SnO₂纳米颗粒,制备出纳米结构的SnO₂@Ti₃C₂T_x 复合材料。使用X射线衍射、X射线光电子能谱和高分辨透射电子显微镜等手段对其表征,研究了这种材料的结构和性能。结果表明,SnO₂纳米粒子密集分布在Ti₃C₂T_x 片层表面与片层之间,Ti₃C₂T_x 纳米薄片突出的限制效应和良好的类石墨层状结构抑制了SnO₂纳米粒子的体积膨胀和团聚,加速了锂离子和电子的跃迁。同时,嵌入在片层之间的SnO₂纳米粒子防止纳米片层在锂插入/脱出过程中重新堆积,使Ti₃C₂T_x 基体的纵向结构稳定性提高。SnO₂@Ti₃C₂T_x 复合材料两组分之间的协同效应,使其具有良好的倍率性能与长循环性能。

关键词 ：复合材料, SnO₂/Ti₃C₂T_x, 超声辅助, 负极材料

Abstract：

SnO₂ nanopoints were in-situ grown on and between Ti₃C₂T_x layers, and the nanostructured SnO₂@Ti₃C₂T_x composites were prepared by ultrasonic adsorption and low temperature heat treatment. SnO₂@Ti₃C₂T_x composites were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and high resolution transmission electron microscopy (HRTEM). Results show that SnO₂ nanoparticles are densely distributed between the layers of Ti₃C₂T_x. Ti₃C₂T_xowns outstanding limiting effect and graphite-like structure, it inhibits the volume expansion and agglomeration of SnO₂ and accelerates the transition of lithium ions and electrons. In addition, SnO₂ is embedded between the layers to improve the longitudinal structural stability of Ti₃C₂T_x by preventing the restacking. Therefore, SnO₂@Ti₃C₂T_x shows a synergistic effect between the two components and has good rate and cycle performance as anode of LIBs.

Key words： composite SnO₂/Ti₃C₂T_x ultrasound-aided anode material

收稿日期: 2021-08-13

ZTFLH:

TM912.9

基金资助:国家自然科学基金(51802096);湖南省自然科学基金(2020JJ4449);湖南省教育厅重点项目(20A346)

作者简介: 李玲芳,女,1981年生

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https://www.cjmr.org/CN/10.11901/1005.3093.2021.443 或 https://www.cjmr.org/CN/Y2022/V36/I8/602

图1 Ti3C2Tx 的扫描电镜和透射电镜照片

图2 ultra-Sn-MX的扫描电镜照片、透射电镜照片和Sn-MX的扫描电镜照片

图3 试样的成分分析

图4 试样的电化学性能

图5 Ti3C2Tx 和ultra-Sn-MX的前三次循环和100次循环后的CV曲线以及三者的电化学阻抗谱

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