<strong>TiZr</strong>基非晶<strong>/TC21</strong>双层复合材料的制备和力学性能

doi:10.11901/1005.3093.2021.704

材料研究学报

2023, Vol. 37

Issue (3): 193-202 DOI: 10.11901/1005.3093.2021.704

研究论文

本期目录 | 过刊浏览

TiZr基非晶/TC21双层复合材料的制备和力学性能

林师峰¹^,², 徐东安³, 庄艳歆¹, 张海峰¹^,², 朱正旺²(

)

^1.东北大学材料科学与工程学院沈阳 110819
^2.中国科学院金属研究所师昌绪先进材料创新中心沈阳 110016
^3.陆军装备部驻沈阳地区军事代表局驻沈阳地区第二军事代表室沈阳 110004

Preparation and Mechanical Properties of TiZr-based Bulk Metallic Glass/TC21 Titanium Alloy Dual-layered Composites

LIN Shifeng¹^,², XU Dongan³, ZHUANG Yanxin¹, ZHANG Haifeng¹^,², ZHU Zhengwang²(

)

^1.School of Material Science and Engineering, Northeastern University, Shenyang 110819, China
^2.Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^3.Military Representative Office of the Army Equipment Department in Shenyang, Shenyang 110004, China

引用本文:

林师峰, 徐东安, 庄艳歆, 张海峰, 朱正旺. TiZr基非晶/TC21双层复合材料的制备和力学性能[J]. 材料研究学报, 2023, 37(3): 193-202.
Shifeng LIN, Dongan XU, Yanxin ZHUANG, Haifeng ZHANG, Zhengwang ZHU. Preparation and Mechanical Properties of TiZr-based Bulk Metallic Glass/TC21 Titanium Alloy Dual-layered Composites[J]. Chinese Journal of Materials Research, 2023, 37(3): 193-202.

全文: PDF(5466 KB) HTML

摘要:

用渗流法制备TiZr基非晶/TC21钛合金双层复合材料，并对其微观组织和力学性能进行深入的研究。结果表明，TiZr基非晶(ZT3, Ti₃₂_.₈Zr₃₀_.₂Ni₅_.₃Cu₉Be₂₂_.₇)合金熔体与TC21钛合金之间的界面结合良好且有良好的润湿性。制备温度对双层复合材料的微观结构和力学性能有极大的影响。随着制备温度的提高，界面层的厚度和TC21钛合金的溶解量增加，非晶基体中枝晶相的体积分数增大、晶粒粗化。这种双层复合材料的强度随着温度的提高而降低，在室温下具有良好的弯曲塑性，其弯曲强度达到2177 MPa、动态压缩强度达到1326 MPa。

关键词 ：金属材料, 非晶复合材料, 制备温度, 微观结构, 弯曲性能, 动态压缩性能

Abstract：

Dual-layered composites of TiZr-based bulk metallic glass /TC21 Ti-alloy were successfully prepared by infiltration method, and their microstructure and mechanical property were investigated in detail. The results show that there is a good wettability of ZT3 (Ti_32.8Zr_30.2Ni_5.3Cu₉Be_22.7) melt with TC21 Ti-alloy, and the as-prepared dual-layered composites show an excellent interfacial bonding between BMGs and TC21 Ti-alloys. The temperature of preparation plays a critical role for the microstructure and mechanical property of the dual-layered composites. With the increasing temperature for preparation, the interfacial layers become thicker moreover, the TC21 Ti-alloy may dissolve increasingly into the BMGs matrix so that the dendrites precipitate significantly increase and they become coarser with the increasing temperature. The dual-layered composites exhibit a satisfied flexural mechanical property, namely a flexural strength of 2177 MPa with outstanding flexural plasticity. Additionally, the prepared dual-layered composites show the dynamic compressive strength up to 1326 MPa at ambient temperature, but decreases as the temperature increasing.

Key words： metallic materials bulk metallic glass composites preparation temperature microstructure flexural mechanical property dynamic compressive mechanical property

收稿日期: 2021-12-24

ZTFLH:

TB331

基金资助:国家自然科学基金(52074527)

通讯作者: 朱正旺，研究员，zwzhu@imr.ac.cn，研究方向为非晶与高熵合金

Corresponding author: ZHU Zhengwang, Tel: (024)23971782, E-mail: zwzhu@imr.ac.cn

作者简介: 林师峰，男，1992生，博士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2021.704 或 https://www.cjmr.org/CN/Y2023/V37/I3/193

图1 润湿角与温度和时间的关系

图2 在不同温度制备的双层复合材料的示意图和界面处的微观结构扫描图

图3 在1173 K制备的双层复合材料界面处的微观结构线性扫描图和对应的成分分布

表1 在1123 K制备的双层复合材料界面处的枝晶相与非晶基体的含量。

图4 ZT3非晶合金和在不同温度制备的双层复合材料的弯曲应力-挠度曲线和在1173 K制备的复合材料的弯曲应力-挠度曲线的局部放大图

图5 在不同温度制备的双层复合材料样品弯曲失效后的侧面扫描图

图6 在不同温度处理的TC21钛合金的拉伸应力-应变曲线

图7 在不同温度制备的双层复合材料的动态压缩应力-应变曲线和在动态压缩过程中试样的应变速率与时间的关系

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