Please wait a minute...
材料研究学报  2017, Vol. 31 Issue (10): 743-750    DOI: 10.11901/1005.3093.2015.602
  研究论文 本期目录 | 过刊浏览 |
双连续TiC/Fe复合材料的制备和性能
赖建宏, 周洋(), 郑涌, 王嘉琪, 黄振莺, 李世波, 翟洪祥
北京交通大学机电学院 北京 100044
Preparation and Property of Bi-continuous Phase TiC/Fe Composite
Jianhong LAI, Yang ZHOU(), Yong ZHENG, Jiaqi WANG, Zhenying HUANG, Shibo LI, Hongxiang ZHAI
School of Mechanical and Electronic Control Engineering, Beijing Jiaotong University, Beijing 100044, China
引用本文:

赖建宏, 周洋, 郑涌, 王嘉琪, 黄振莺, 李世波, 翟洪祥. 双连续TiC/Fe复合材料的制备和性能[J]. 材料研究学报, 2017, 31(10): 743-750.
Jianhong LAI, Yang ZHOU, Yong ZHENG, Jiaqi WANG, Zhenying HUANG, Shibo LI, Hongxiang ZHAI. Preparation and Property of Bi-continuous Phase TiC/Fe Composite[J]. Chinese Journal of Materials Research, 2017, 31(10): 743-750.

全文: PDF(1479 KB)   HTML
摘要: 

以聚氨酯海绵为前驱体,以TiC微粉为原料并添加少量还原铁粉、羰基铁粉及钛粉为烧结助剂,用有机前驱体浸渍法制备具有三维网络结构的TiC多孔陶瓷,研究了聚氨酯海绵的孔径、浆料涂覆次数等因素对TiC多孔陶瓷的孔隙率和孔棱直径的影响。在此基础上采用无压浸渗工艺将Fe基体与TiC多孔陶瓷复合,制备出一种双连续结构的TiC/Fe复合材料。分析了复合材料的物相组成,观察了其宏观结构与微观结构,并测试了复合材料内的硬度分布。结果表明,TiC多孔陶瓷的结构完整,孔隙率和孔棱直径可控;复合材料具有双连续结构,TiC与Fe结合良好,两相结合区的硬度呈梯度变化。

关键词 复合材料双连续结构有机前驱体浸渍法无压浸渗碳化钛    
Abstract

Porous TiC-ceramics of three-dimensional network structure were prepared by organic precursor impregnation method using polyurethane sponge as precursor with a small amount of powders of reduced iron, carbonyl iron and titanium as the sintering additives. The influence of the pore size of polyurethane sponge and times of slurry-applying on the porosity and skeleton diameter of porous TiC-ceramics was investigated. Then composite of Bi-continuous phase TiC/Fe was prepared by pressureless infiltration method. The phase composition, the macro- and micro-structure as well as the hardness distribution of the composite were assessed. Results show that the prepared porous TiC-ceramics is integrated in structure, while their porosity and size of TiC-skeleton are controllable. The composite of TiC/Fe exhibited a perfect bi-continuous phase structure with a good combination between TiC and Fe. A gradient hardness distribution of two-phase combining areas was observed.

Key wordscomposites    bi-continuous phase    organic precursor impregnation    pressureless infiltration    TiC
收稿日期: 2016-10-27     
ZTFLH:  TB333  
基金资助:国家自然科学基金(51472024、51372015)
作者简介:

作者简介 赖建宏,男,1989年生,硕士

Raw material Purity / % Particle size Content / %
TiC powder 95 2~3 μm 75
Reduced iron powder 99 400 mesh 8
Carbonyl iron powder 99 3~5 μm 2
Ti powder 99.5 200 mesh 15
表1  原料的纯度、粒度及多孔陶瓷配方
图1  无压浸渗示意图
图2  不同PPI值的多孔陶瓷的形貌和孔棱结构
图3  多孔陶瓷的孔棱横断面形貌
图4  多孔陶瓷烧结前后的XRD谱
Phase TiC Fe Ti Fe3C
Before sintering 75% 10% 15% 0
After sintering 90% 0% 0% 10%
表2  多孔陶瓷烧结前后各物相的质量分数
图5  用经过多次涂覆后的30PPI的海绵制备的TiC多孔陶瓷的形貌
图6  多孔陶瓷的孔棱直径与涂覆次数的关系
图7  多孔陶瓷的孔隙率与涂覆次数的关系
图8  TiC/Fe复合材料剖面背散射SEM照片
图9  TiC/Fe复合材料剖面XRD谱
图10  陶瓷骨架、铁基体复合材料以及两者结合部位的维氏硬度压痕照片
图11  复合材料各区域的维氏硬度
[1] Zhang D, Zhang G D, Li Z Q.The current state and trend of metal matrix composites[J]. Materials China, 2010, 29(4): 2(张荻, 张国定, 李志强. 金属基复合材料的现状与发展趋势[J]. 中国材料进展, 2010, 29(4): 2)
[2] Wang H Y, Jiang Q C, Zhao Y Q.Fabrication of TiB2 and TiB2-TiC particulates reinforced magnesium matrix composites[J]. Mater. Sci. Eng. A, 2004, 372: 109
[3] Trojanova Z, Lukac P, Riehemann W, et al.Study of relaxation of residual internal stress in Mg composites by internal friction[J]. Mater. Sci. Eng. A, 2002, 324: 122
[4] Xu Z R, Chawla K K, Neuman A, et al.Stiffness loss and density decrease due to thermal cycling in an alumina fiber/magnesium alloy composites[J]. Mater. Sci. Eng. A, 1995, 75: 203
[5] Konopka K, Olszówka-Myalska A, Szafran M.Ceramic-metal composites with an interpenetrating network[J]. Mater. Chem. Phys., 2003, 81: 329
[6] Zhang W, Dai B Y, Shang J L, et al.Preparation technology and application prospects of three dimensional continuous Ceramic metal composite materials[J]. Special Casting & Nonferrous Alloys, 2013, 33(1): 64(张伟, 戴斌煜, 商景利等. 三维连续网络陶瓷金属复合材料的制备及应用前景[J]. 特种铸造及有色合金, 2013, 33(1): 64)
[7] Zhang J S, Cao X M, Hu W P. Application of double continuous-phase composite in braking disc and lining for high speed train [J]. Electric Drive for Locomotives, 2003, Sup: 39(张劲松, 曹小明, 胡宛平. 双连续相复合材料在高速列车制动盘及闸片中的应用[J]. 机车电传动, 2003, 增刊: 39)
[8] Jiang Q C, Wang H Y, Wang J G, et al.Fabrication of TiCP/Mg composites by the thermal explosion synthesis reaction in molten magnesium[J]. Mater. Lett., 2003, 57: 2580
[9] Filho A L, Atkinson H, Jones H.Hot isostatic pressing of metal reinforced metal matrix composites[J]. J. Mater. Sci., 1998, 33: 517
[10] Ferkel H, Mordike B L.A-structure materials properties microstructure and processing[J]. Mater. Sci. Eng. A, 2001, 298: 193
[11] Lemster K, Delporte M, Graule T, et al.Activation of alumina foams for fabricating MMCs by pressureless infiltration[J]. Ceramics International, 2007, 33: 1179
[12] Wang H Y, Jiang Q C, Li X L, et al.Fabrication of TiC particulate reinforced magnesium matrix composites[J]. Scrpta. Mater., 2003, 48: 1349
[13] Wang J, Fu S J, Ding Y C.Microstructure and wear property of TiC particles reinforced iron matrix composite produced in-situ[J]. Journal of Sichuan University (Engineering Science) , 2008, 40(5): 111(王静, 伏思静, 丁义超. 原位合成TiC/Fe基复合材料的组织结构和磨损性能[J]. 四川大学学报, 2008, 40(5): 111)
[14] Srinivasa R B, Jayaram V.Pressureless infiltration of Al-Mg based alloys into Al2O3 preforms: mechanisms and phenomenology[J]. Acta Mater., 2001, 49: 2373
[15] Chen W P, Yang S F, Han M Y.Research development of ceramic/Fe-based alloy composites[J]. The Chinese Journal of Nonferrous Metals, 2010, 20(2): 257(陈维平, 杨少锋, 韩孟岩. 陶瓷/铁基合金复合材料的研究进展[J]. 中国有色金属学报, 2010, 20(2): 257)
[16] Chen H Y, Zou Z G, Mai L Q.Progress in research of TiC composition[J]. Powder Metallurgy Industry, 2001, 11(3): 38(陈寒元, 邹正光, 麦立强. TiC复合材料的研究进展[J]. 粉末冶金工业, 2001, 11(3): 38)
[17] Hou S Z, Bao C G, Fu Q R, et al.Interfacial characteristics and abrasive wear behavior of cemented carbide/high-Cr white cast iron composite[J]. Journal of Xi’an Jiaotong University, 2012, 46(5): 45(侯书增, 鲍崇高, 付青然等. 硬质合金/高铬铸铁基复合材料的界面特性及磨损性能研究[J]. 西安交通大学学报, 2012, 46(5): 45)
[18] Zhang J S, Cao X M, Tian C, et al.Preparation method of foam SiC/metal co-continuous phase composite friction material components [P]. China, ZL200610046242.X, 2006(张劲松, 曹小明, 田冲等. 泡沫碳化硅/金属双连续相复合摩擦材料构件的制备方法 [P]. 中国, ZL200610046242.X, 2006)
[19] Ren Z H, Jin P, Cao X M, et al.Preparation and performance of SiC foam ceramic/Fe matrix Co-continuous phase composites[J]. Chinese Journal of Materials Research, 2014, 28(11): 815(任志恒, 金鹏, 曹小明等. SiC泡沫陶瓷/Fe基双连续相复合材料的制备和性能[J]. 材料研究学报, 2014, 28(11): 815)
[20] Liu Y, Huang Z R, Dong S M, et al.The effect of surface treatment on the hanging pulp properties of silicon carbide foam ceramic[J]. Journal of Inorganic Materials, 2006, 21(5): 1185(刘岩, 黄政仁, 董绍明等. 表面处理对碳化硅泡沫陶瓷挂浆性能的影响[J]. 无机材料学报, 2006, 21(5): 1185)
[21] Wang S R, Geng H R, Gao S P.Technology and the progress of preparing network ceramic precast body of metal matrix composites by precursor impregnation method[J]. Shandong Ceramics, 2005, 28(1): 9(王守仁, 耿浩然, 高绍平. 前驱体浸渍法制备金属基复合材料网络陶瓷预制体的工艺及进展[J]. 山东陶瓷, 2005, 28(1): 9)
[22] Lin J P, Zhang Y, Chen G L.Effect of fabrication technology on the structures and properties of TiC ceramic foam[J]. Powder Metallurgy Technology, 2000, 18(1): 12(林均品, 张勇, 陈国良. 制备工艺对TiC泡沫陶瓷结构及性能影响[J]. 粉末冶金技术, 2000, 18(1): 12)
[23] Jian F Q, He G F, Yu H.Study of improving the iron alloy sintered density by adding the carbonyl iron powder[J]. Powder Metallurgy Technology, 1994, 12(4): 276(骞福全, 何高风, 于海. 添加羰基铁粉提高铁合金烧结密度的研究[J]. 粉末冶金技术, 1994, 12(4): 276)
[1] 潘新元, 蒋津, 任云飞, 刘莉, 李景辉, 张明亚. 热挤压钛/钢复合管的微观组织和性能[J]. 材料研究学报, 2023, 37(9): 713-720.
[2] 刘瑞峰, 仙运昌, 赵瑞, 周印梅, 王文先. 钛合金/不锈钢复合板的放电等离子烧结技术制备及其性能[J]. 材料研究学报, 2023, 37(8): 581-589.
[3] 季雨辰, 刘树和, 张天宇, 查成. MXene在锂硫电池中应用的研究进展[J]. 材料研究学报, 2023, 37(7): 481-494.
[4] 王伟, 解泽磊, 屈怡珅, 常文娟, 彭怡晴, 金杰, 王快社. Graphene/SiO2 纳米复合材料作为水基润滑添加剂的摩擦学性能[J]. 材料研究学报, 2023, 37(7): 543-553.
[5] 张藤心, 王函, 郝亚斌, 张建岗, 孙新阳, 曾尤. 基于界面氢键结构的石墨烯/聚合物复合材料的阻尼性能[J]. 材料研究学报, 2023, 37(6): 401-407.
[6] 邵萌萌, 陈招科, 熊翔, 曾毅, 王铎, 王徐辉. C/C-ZrC-SiC复合材料的Si2+ 离子辐照行为[J]. 材料研究学报, 2023, 37(6): 472-480.
[7] 张锦中, 刘晓云, 杨健茂, 周剑锋, 查刘生. 温度响应性双面纳米纤维的制备和性能[J]. 材料研究学报, 2023, 37(4): 248-256.
[8] 王刚, 杜雷雷, 缪自强, 钱凯成, 杜向博文, 邓泽婷, 李仁宏. 聚多巴胺改性碳纤维增强尼龙6复合材料的界面性能[J]. 材料研究学报, 2023, 37(3): 203-210.
[9] 林师峰, 徐东安, 庄艳歆, 张海峰, 朱正旺. TiZr基非晶/TC21双层复合材料的制备和力学性能[J]. 材料研究学报, 2023, 37(3): 193-202.
[10] 苗琪, 左孝青, 周芸, 王应武, 郭路, 王坦, 黄蓓. 304不锈钢纤维/ZL104铝合金复合泡沫的孔结构、力学、吸声性能及其机理[J]. 材料研究学报, 2023, 37(3): 175-183.
[11] 张开银, 王秋玲, 向军. FeCo/SnO2 复合纳米纤维的制备及其吸波性能[J]. 材料研究学报, 2023, 37(2): 102-110.
[12] 周聪, 昝宇宁, 王东, 王全兆, 肖伯律, 马宗义. (Al11La3+Al2O3)/Al复合材料的高温性能及其强化机制[J]. 材料研究学报, 2023, 37(2): 81-88.
[13] 罗昱, 陈秋云, 薛丽红, 张五星, 严有为. 钠离子电池双层碳包覆Na3V2(PO4)3 正极材料的超声辅助溶液燃烧合成及其电化学性能[J]. 材料研究学报, 2023, 37(2): 129-135.
[14] 刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C3N4/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[15] 谢东航, 潘冉, 朱士泽, 王东, 刘振宇, 昝宇宁, 肖伯律, 马宗义. 增强颗粒尺寸对B4C/Al-Zn-Mg-Cu复合材料微观组织及力学性能的影响[J]. 材料研究学报, 2023, 37(10): 731-738.