Please wait a minute...
材料研究学报  2015, Vol. 29 Issue (7): 496-504    DOI: 10.11901/1005.3093.2014.795
  本期目录 | 过刊浏览 |
基于热加工图的喷射成形含铌高速钢的热变形
卢林1,侯陇刚1(),王和斌1,张金祥1,崔华1,黄进峰1,张永安2,张济山1
1. 北京科技大学 新金属材料国家重点实验室 北京 100083
2. 北京有色金属研究总院 有色金属材料制备加工国家重点实验室 北京 100088
Hot Deformation of Spray-Formed Nb-Containing High Speed Steel—A Study Using Processing Map
Lin LU1,Longgang HOU1,**(),Hebin WANG1,Jinxiang ZHANG1,Hua CUI1,Jinfeng HUANG1,Yongan ZHANG2,Jishan ZHANG1
1. State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China
2. State Key Laboratory of Non-Ferrous Metals and Process, General Research Institute for Non-Ferrous Metals, Beijing 100088, China
引用本文:

卢林,侯陇刚,王和斌,张金祥,崔华,黄进峰,张永安,张济山. 基于热加工图的喷射成形含铌高速钢的热变形[J]. 材料研究学报, 2015, 29(7): 496-504.
Lin LU, Longgang HOU, Hebin WANG, Jinxiang ZHANG, Hua CUI, Jinfeng HUANG, Yongan ZHANG, Jishan ZHANG. Hot Deformation of Spray-Formed Nb-Containing High Speed Steel—A Study Using Processing Map[J]. Chinese Journal of Materials Research, 2015, 29(7): 496-504.

全文: PDF(8048 KB)   HTML
摘要: 

结合以铌代替部分钒的合金化思路和用喷射成形快速凝固技术制备出新型M3: 2高速钢, 研究了合金在950-1150℃和0.001-10 s-1条件下的热变形。根据实验得到的真应力-真应变曲线, 基于动态材料模型(DDM)建立合金热加工图并结合动力学分析和组织观察, 将加工图分为塑性失稳区(>1 s-1)、低应变速率区(0.001 s-1)、低变形温度区(<1000℃)和加工安全区, 重点讨论了低应变速率区和低变形温度区内裂纹产生的机制, 并由此确定了合金可进行热加工的区间为1050-1150℃, 0.01-0.1 s-1。为了得到晶粒细小、碳化物呈颗粒状且分布均匀的组织, 优化后的热变形加工参数为1150℃, 0.1 s-1。喷射成形含铌M3: 2高速钢经锻造和热处理后, 其硬度和弯曲强度等性能优于同等成分的粉末冶金高速钢。

关键词 金属材料 喷射成形高速钢热变形热加工图    
Abstract

The hot deformation behavior of as spray-formed Nb-containing AISI M3: 2 high speed steel has been investigated by compression tests at a temperature range of 950-1150℃ and a strain range of 0.001-10 s-1 with 50% reduction. Processing maps were developed according to the principles of Dynamic Material Model. It was found that the flow curves assumed the classic shape of dynamic recrystallization (DRX)-rising to a peak, following a softening to a steady state. The hot working process of the steel can be carried out safely in the domain of (Td: 1050-1150℃, : 0.01-0.1 s-1). To obtain microstructures of the steel with fine grains and uniform distribution of fine granular carbides, the hot working process should be carried out at 1150℃ and strain rate of 0.1 s-1. The flow instability took place when strain rates exceed 1 s-1. After a proper hot working and heat treatment, the hardness and bending strength of the spray-formed Nb-containing M3:2 high speed steel is 67 HRC and 3467 MPa, respectively.

Key wordsmetal materials    spray forming    high speed steel    hot deformation    processing map    niobium
收稿日期: 2014-12-31     
基金资助:* 国家重点基础研究发展计划2011CB606303资助项目。
图1  喷射成形高速钢沉积态组织SEM像
图2  喷射成形高速钢在不同温度下的真应力-真应变曲线
图3  应变为0.6时应力与应变速率、温度的关系图
图4  喷射成形高速钢的热加工图, 阴影部分为塑性失稳区, 等高线的数字代表能量耗散效率( ε =0.6)
图5  塑性失稳区内的变形组织
图6  动态再结晶区域内的变形组织
图7  应变速率为0.1 s-1时不同温度下的变形组织
图8  应变速率为0.001 s-1下的变形组织
图9  喷射成形含铌M3:2高速钢的锻造态组织
Steel Hardness/HRC Bend strength/MPa Impact toughness/J
SFM3:2 67.0 3467.6 20.98
Sintering ASP23[28] 63-66 2750 -
HIP ASP23[29] 64 3500 32.5-42
Con M3:2[29] 64 2500 -
表1  喷射成形高速钢力学性能
1 SONG Xiaolong, AN Jiru, New Handbook of Metal Materials at Home and Abroad, 2nd Edition, (Beijing, Chemical Industry Press, 2012)
1 (
2 Catalogue thyssen edelstahl service gmbh,GER Pat, G0168/1(1997)
3 P. Beiss,PM(Powder Metallurgy) methods for the production of high speed steels, Met Powder Rep., 38(4), 185(1983)
4 I. C. Ernst, D. Duh,ESP4 and TSP4, a comparison of spray formed with powder metallurgically produced cobalt free high-speed steel of type 6W-5Mo-4V-4Cr, Journal of Materials Science, 39(22), 6831(2004)
5 LI Junchen,PENG Xiaodong, LIU Junwei, YANG Yan, ZENG Li, Deformation behavior of alloy Mg-9Li-3Al-2.5Sr at elevated temperature, Chinese Journal of Materials Research, 26(3), 309(2012)
5 (李俊辰, 彭晓东, 刘军威, 杨 艳, 曾利,Mg-9Li-3Al-2.5Sr 合金的热变形行为, 材料研究学报, 26(3), 309(2012))
6 K. P. Rao, Y. V. R. H. Prasad, K. Suresh,Anisotropy of flow during isothermal forging of rolled AZ31B magnesium alloy rolled plate in three orthogonal directions: Correlation with processing maps, Mater. Sci. Eng., A558, 30(2012)
7 K. Suresh, K. P. Rao, Y. V. R. H. Prasad, N. Hort, K. U. Kainer,Effect of calcium addition on the hot working behavior of as-cast AZ31 magnesium alloy, Mater. Sci. Eng., A588, 272(2013)
8 C. Dharmendra, K. P. Rao, F. Zhao, Y. V. R. H. Prasad, N. Hort, K. U. Kainer,Effect of silicon content on hot working, processing maps, and microstructural evolution of cast TX32-0.4 Al magnesium alloy, Mater.Sci.Eng., A606, 11(2014)
9 O. Sivakesavam, Y. V. R. H. Prasad,Hot deformation behaviour of as-cast Mg-2Zn-1Mn alloy in compression: a study with processing map, Mater. Sci. Eng., A362, 118(2003)
10 N. Srinivasan, Y. V. R. H. Prasad, P. P. Rao,Hot deformation behaviour of Mg-3Al alloy, a study using processing map, Mater. Sci. Eng., A476, 146(2008)
11 T. Zhong, K. P. Rao, Y. V. R. H. Prasad, F. Zhao, M. Gupta,Hot deformation mechanisms, microstructure and texture evolution in extruded AZ31-nano-alumina composite, Mater. Sci. Eng., A589, 41(2014)
12 KONG Fantao,CUI Ning, CHEN Yuyong, XIONG Ningning, The hot deformation behavior of Ti-43Al-9V-Y alloy, Acta. Metall. Sin., 49(11), 1363(2012)
12 (孔凡涛, 崔 宁, 陈玉勇, 熊宁宁,Ti-43Al-9V-Y合金的高温变形行为研究, 金属学报, 49(11), 1363(2012))
13 T. Seshacharyulu, S.C. Medeiros, J.T. Morgan, J.C. Malas, W.G. Frazier, Y.V.R.H. Prasad,Hot deformation and microstructural damage mechanisms in extra-low interstitial (ELI) grade Ti-6Al-4V, Mater. Sci . Eng., A279(1), 289(2000)
14 F. W. Kang, G. Q. Zhang, Z. Li, J. F. Sun,Hot deformation of spray formed nickel-base superalloy using processing maps, Trans .Nonferrous Met. Soc. China, 18(3), 531(2008)
15 H. R. Ezatpour, S. A. Sajjadi, M. Haddad-sabzevar, G. R. Ebrahimi,Hot deformation and processing maps of K310 cold work tool steel, Mater. Sci . Eng., A550, 152(2012)
16 S. Venugopal, S.L. Mannan, Y. V. R. H. Prasad,Optimization of hot workability in stainless, Metall. Trans., 23A, 3039(1992)
17 G. Meng, B. L. Li, H. M. Li, H. Huang, Z. R. Nie,Hot deformation and processing maps of an Al-5.7 wt.%Mg alloy with erbium, Mater.Sci.Eng., A517, 132(2009)
18 WANG Hebin,ZHANG Jinxiang, LU Lin, HOU Longgang, CUI Hua, HUANG Jinfeng, ZhANG Jishan, High-temperature thermal deformation and microstructure evolution of spray formed M4 high speed steel, Chinese Journal of Materials Research, 27(2), 167(2013)
18 (王和斌, 张金祥, 卢 林, 侯陇刚, 崔 华, 黄进峰, 张济山, 喷射成形M4高速钢的高温热变形及组织演变, 材料研究学报, 27(2), 167(2013))
19 Y. H. Liu, Y. Q. Ning, Z. K. Yao, M.W. Fu,Hot deformation behavior of the 1.15 C-4.00 Cr-3.00 V-6.00 W-5.00 Mo powder metallurgy high speed steel, Mater. Des., 54, 854(2014)
20 Y. V. R. H. Prasad, H. L. Gegel, S. M. Doraivelu, J. C Malas, J. T. Morgan, K. A. Lark, D. R. Barker,Modeling of dynamic material behavior in hot deformation: forging of Ti-6242, Metall. Trans. A, 15, 1883(1984)
21 Y. V. R. H. Prasad,Recent advances in the science of mechanical processing, Indian J. Technol., 28, 435(1990)
22 C. A. C. Imbert, H. J. McQueen,Peak strength, strain hardening and dynamic restoration of A2 and M2 tool steels in hot deformation, Mater. Sci. Eng., A313, 88(2001)
23 H. J. McQueen, S. Yue, N. D. Ryan, E. Fry,Hot working characteristics of steels in austenitic state, J. Mater. Process Technol., 53, 293(1995)
24 R. Raj,Development of a processing map for use in warm-forming and hot-forming processes, Metall. Trans. A, 12, 1089(1981)
25 C. Gandhi,On fracture initiation mechanisms and dynamic recrystallization during hot deformation of pure nickel, Metall.Trans. A, 13, 1233(1982)
26 Y. V. R. K. Prasad, T. Seshacharyulu,Modelling of hot deformation for microstructural control, Int. Mater. Rev., 43(6), 243(1998)
27 H. J. McQueen, C. A. C. Imbert,Dynamic recrystallization: plasticity enhancing structural development, J. Alloys Compd., 378(1), 35(2004)
28 YU Yipeng,Study on microstructures and properties of spray formed Nb-containing M3 high speed steel, PhD thesis, University of Science and Technology Beijing, 2012
28 (于一鹏, 喷射成形M3型高速钢组织性能研究,博士论文, 北京科技大学(2012))
29 R. A. Mesquita, C. A. Barbosa,High-speed steels produced by conventional casting, spray forming and powder metallurgy, Mater. Sci. Forum, 498, 244(2005)
[1] 赵政翔, 廖露海, 徐芳泓, 张威, 李静媛. 超级奥氏体不锈钢24Cr-22Ni-7Mo-0.4N的热变形行为及其组织演变[J]. 材料研究学报, 2023, 37(9): 655-667.
[2] 刘继浩, 迟宏宵, 武会宾, 马党参, 周健, 徐辉霞. 喷射成形M3高速钢热处理过程中组织的演变和硬度偏低问题[J]. 材料研究学报, 2023, 37(8): 625-632.
[3] 于森, 陈乐利, 罗锐, 袁志钟, 王爽, 高佩, 程晓农. 高温合金GH4169的动态再结晶和组织演化机制[J]. 材料研究学报, 2023, 37(3): 211-218.
[4] 胡海波, 朱丽慧, 段元满, 吴晓春, 顾炳福. 原位研究M2高速钢微裂纹的萌生和扩展[J]. 材料研究学报, 2022, 36(5): 365-372.
[5] 朱海勇, 张伟. 锰掺杂和氧化铌种子层对铌酸钾钠薄膜电性能的影响[J]. 材料研究学报, 2022, 36(12): 945-950.
[6] 潘晓宇, 杨银辉, 倪珂, 曹建春, 钱昊. 18.5%CrMn型节镍双相不锈钢大变形热压缩的组织和再结晶行为[J]. 材料研究学报, 2021, 35(5): 381-393.
[7] 段元满, 朱丽慧, 吴晓春, 顾炳福. 深冷处理时间对M2高速钢红硬性的影响[J]. 材料研究学报, 2021, 35(1): 17-24.
[8] 王伟, 宫鹏辉, 张浩泽, 史亚鸣, 王萌, 张晓锋, 王快社. 电子束冷床熔炼TC4钛合金的热变形行为[J]. 材料研究学报, 2020, 34(9): 665-673.
[9] 程晓农, 桂香, 罗锐, 徐桂芳, 袁志钟, 周宇森, 高佩. 新型奥氏体耐热钢CHDG-A的动态再结晶行为及其动力学模型[J]. 材料研究学报, 2020, 34(8): 611-620.
[10] 李沐泽, 柏春光, 张志强, 赵建, 徐东生, 王岩峰. TC2钛合金的高温热变形行为[J]. 材料研究学报, 2020, 34(12): 892-904.
[11] 张拓,滕铝丹,臧其玉,杨弋涛. 含铌中铬耐磨铸钢的摩擦磨损行为[J]. 材料研究学报, 2019, 33(4): 313-320.
[12] 欧阳德来,崔霞,鲁世强,徐勇. 锻态TB6钛合金β相区压缩变形行为和动态再结晶[J]. 材料研究学报, 2019, 33(3): 218-224.
[13] 杨雨童,罗锐,程晓农,桂香,陈乐利,王威,郑琦. 新型含铝奥氏体耐热合金的高温塑性变形行为和热加工性能[J]. 材料研究学报, 2019, 33(3): 232-240.
[14] 毕金凤, 李祖来, 山泉, 蒋业华, 韦贺, 焦岩. Si-Mn-Cr-B合金钢的高温变形行为及组织演变研究*[J]. 材料研究学报, 2016, 30(8): 595-602.
[15] 王立新,李花兵,李国平,唐正友,马明. 2205和2507双相不锈钢双道次热压缩条件下的微观组织演变及变形行为*[J]. 材料研究学报, 2016, 30(12): 888-896.