Please wait a minute...
材料研究学报  2008, Vol. 22 Issue (1): 87-92    
  论文 本期目录 | 过刊浏览 |
聚醚砜/MC尼龙6原位复合材料的制备和性能
钱浩; 洪国莹; 林志勇
华侨大学材料科学与工程学院 泉州
引用本文:

钱浩; 洪国莹; 林志勇. 聚醚砜/MC尼龙6原位复合材料的制备和性能[J]. 材料研究学报, 2008, 22(1): 87-92.

全文: PDF(979 KB)  
摘要: 用阴离子原位聚合法制备聚醚砜/MC尼龙6原位复合材料,研究了聚醚砜与己内酰胺、尼龙6各组分之间的相互作用.结果表明,依靠其组分之间强烈的作用力,使PES能以较小的相畴均匀的分散在尼龙6基体中;酰胺基团上的氢原子能与聚醚砜中的砜基之间产生氢键作用,从而促进了聚醚砜在己内酰胺熔体中的溶解.聚醚砜与尼龙6之间的这种氢键互作用,强烈抑制了尼龙6的分解过程,提高了复合材料的热稳定性,2%PES时,其分解温度提高了79℃.较小含量的PES对复合材料的力学性能影响较小,当其含量超过4%时,尽管复合材料的强度有所下降,但韧性显著提高,体现了刚性有机粒子增韧的作用.
关键词 复合材料MC尼龙6聚醚砜阴离子原位聚合    
Key words
收稿日期: 1900-01-01     
1 B.Nandan,K.N.Pandey,G.D.Pandey,A.Singh, L.D.Kandpa,G.N.Mathur,Miscibility behaviour of poly(ether sulphone)/nylon-6 blends,Journal of Thermal Anaylsis and Calorimetry,64,529 (2001)
2 V.L.Rao,P.U.Sabeena,M.R.Rao,K.N.Ninan,Synthesis and characterization of poly(ether sulfone)and poly(ether sulfone ketone)copolymers,Journal of Applied Polymer Science,73(11),2113(1999)
3 H.Chen,G.Belfort,Surface modification of poly(ether sulfone)ultrafiltration membranes by low-temperature plasma-induced graft polymerization,Journal of Applied Polymer Science,72(13),1699(1999)
4 R.Kumar,U.De,R.Prasad,Physical and chemical re- sponse of 70 MeV carbon ion irradiated polyether sulphone polymer,Nuclear Instruments and Methods in Physics Re- search Section B:Beam Interactions with Materials and Atoms,248(2),279(2006)
5 ZHANG Jun,HE Jiasong,The interfacial compatibiliza- tion for PSF/LCP blends by a maleic anhydride modified polysulfone,Chemical Research in Chinese Universities, 22(8),1419(2001) (张军,何嘉松,酸酐化聚砜对聚砜/液晶聚合物共混物的界面增容作用,高等学校化学学报,22(8),1419(2001))
6 LIU Yanjun,JIAN Xigao,LIU Shengjun,Synthesis and characterization of poly(ether sulfone ketone ketone)con- taining phthalazinone moiety,Chinese Journal of Material Research,14(1),100(2000) (刘彦军,蹇锡高,刘圣军,含二氮杂萘结构聚醚砜酮酮的合成及表征,材料研究学报,14(1),100(2000))
7 J.E.Harris,E.Ga,G.T.Brooks,Process for miscible blends of imide containing polymers with poly(aryl sulfones), United States Patent,5134202(1992)
8 M.J.E1-Hibri,R.Ga,J.L.Melquist,Blends of poly- ether solfones and copolymides,United States Patent, 5026311(1993)
9 D.W.Van Krevelen,Properties of Polymers:Their Es- timation and Correction with Chemical Structure(New York:Hsevier Scientific Publishing Company,1976)p.95
10 Y.Minoura,T.Hanada,T.Kasabo,Y.Ueno,Cationic graft copolymerization of styrene onto chlorinated butyl rubber, J.Polym.Sci.,Polym.Chem.,4(7),1665(1966)
11 Allan Francis Murray Barton,Handbook of Polymer- Liquid Interaction Parameters and Solubility Parameters (CRC Press Inc,1990)p.72
12 WANG Honghua,LUO Faliang,BO Shuqin,CHEN Tianlu,Cyclo-depolymerization of several amorphous aro- matic polyether sulfone(ketone)and ring-opening poly- merization of the products,Acta Chimica Sinica,62(14), 1344(2004) (王红华,罗发亮,薄淑琴,陈天禄,几种无定型聚芳醚矾(酮)的成环解聚及产物的开环聚合,化学学报,62(14),1344(2004))
13 G.Beamson,D.Baiggs,High Resolution XPS of Organic Polymers-The Scienta ESCA300 Database(NewYork, John Wiley & Sons Press,1995)p.87
14 T.O.Ahn,S.C.Hong,H.M.Jeong,J.H.Kim,Nylon 6- polyethersulfone-nylon 6 block copolymer:synthesis and application as compatibilizer for polyethersulfone/nylon 6 blend,Polymer,38(1),207(1997)
15 P.Charoensirisomboon,T.Chiba,K.Torikai,H.Saito, T.Ougizawa,T.Inoue,M.Weber,Morphology-interface- toughness relationship in polyamide/polysulfone blends by reactive processing,Polymer,40(25),6965(1999)
16 T.Kyu,Z.L.Zhou,G.C.Zhu,Y.Tajuddin,S.Qutubuddin, Novel filled polymer composites prepared from in situ polymerization via a colloidal approach:I.Kaolin/nylon-6 in situ composites,J.Polym.Sci.,Part B:Polym.Phys., 34(10),1761(1996)
17 K.Yano,A.Usuki,A.Okada,T.Kurauchi,O.Kamigaito, Synthesis and properties of polyimide-clay hybrid,J. Polym.Sci.,Part A:Polym.Chem.,31(10),2493(1993)
18 J.C.Angola,Y.Fujita,T.Sakai,T.Inoue,Compatibilizer- aided toughening in polymer blends consisting of brittle polymer particles dispersed in a ductile polymer matrix, J.Polym.Sci.,Part B:Polym.Phys.,26(4),807(1988)
19 T.Kurauchi,T.Ohta,Energy absorption in blends of poly- carbonate with ABS and SAN,Journal of Materials Sci- ence,19(5),1699(1988)
20 S.Lumlong,K.Kuboyama,T.Chiba,T.Ougizawa,Brittle- ductile transition in reactive PBT/SAN blends,Macro- molecular Symposia,233(1),17(2006)
[1] 潘新元, 蒋津, 任云飞, 刘莉, 李景辉, 张明亚. 热挤压钛/钢复合管的微观组织和性能[J]. 材料研究学报, 2023, 37(9): 713-720.
[2] 刘瑞峰, 仙运昌, 赵瑞, 周印梅, 王文先. 钛合金/不锈钢复合板的放电等离子烧结技术制备及其性能[J]. 材料研究学报, 2023, 37(8): 581-589.
[3] 季雨辰, 刘树和, 张天宇, 查成. MXene在锂硫电池中应用的研究进展[J]. 材料研究学报, 2023, 37(7): 481-494.
[4] 王伟, 解泽磊, 屈怡珅, 常文娟, 彭怡晴, 金杰, 王快社. Graphene/SiO2 纳米复合材料作为水基润滑添加剂的摩擦学性能[J]. 材料研究学报, 2023, 37(7): 543-553.
[5] 张藤心, 王函, 郝亚斌, 张建岗, 孙新阳, 曾尤. 基于界面氢键结构的石墨烯/聚合物复合材料的阻尼性能[J]. 材料研究学报, 2023, 37(6): 401-407.
[6] 邵萌萌, 陈招科, 熊翔, 曾毅, 王铎, 王徐辉. C/C-ZrC-SiC复合材料的Si2+ 离子辐照行为[J]. 材料研究学报, 2023, 37(6): 472-480.
[7] 张锦中, 刘晓云, 杨健茂, 周剑锋, 查刘生. 温度响应性双面纳米纤维的制备和性能[J]. 材料研究学报, 2023, 37(4): 248-256.
[8] 王刚, 杜雷雷, 缪自强, 钱凯成, 杜向博文, 邓泽婷, 李仁宏. 聚多巴胺改性碳纤维增强尼龙6复合材料的界面性能[J]. 材料研究学报, 2023, 37(3): 203-210.
[9] 林师峰, 徐东安, 庄艳歆, 张海峰, 朱正旺. TiZr基非晶/TC21双层复合材料的制备和力学性能[J]. 材料研究学报, 2023, 37(3): 193-202.
[10] 苗琪, 左孝青, 周芸, 王应武, 郭路, 王坦, 黄蓓. 304不锈钢纤维/ZL104铝合金复合泡沫的孔结构、力学、吸声性能及其机理[J]. 材料研究学报, 2023, 37(3): 175-183.
[11] 张开银, 王秋玲, 向军. FeCo/SnO2 复合纳米纤维的制备及其吸波性能[J]. 材料研究学报, 2023, 37(2): 102-110.
[12] 周聪, 昝宇宁, 王东, 王全兆, 肖伯律, 马宗义. (Al11La3+Al2O3)/Al复合材料的高温性能及其强化机制[J]. 材料研究学报, 2023, 37(2): 81-88.
[13] 罗昱, 陈秋云, 薛丽红, 张五星, 严有为. 钠离子电池双层碳包覆Na3V2(PO4)3 正极材料的超声辅助溶液燃烧合成及其电化学性能[J]. 材料研究学报, 2023, 37(2): 129-135.
[14] 刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C3N4/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790.
[15] 谢东航, 潘冉, 朱士泽, 王东, 刘振宇, 昝宇宁, 肖伯律, 马宗义. 增强颗粒尺寸对B4C/Al-Zn-Mg-Cu复合材料微观组织及力学性能的影响[J]. 材料研究学报, 2023, 37(10): 731-738.