La1-<italic></italic>xY<italic></italic>xNi4.8Mn0.2合金的储氢性能*

材料研究学报

2013, Vol. 27

Issue (1): 1-6

研究论文

本期目录 | 过刊浏览

La_1-_xY_xNi_4.8Mn_0.2合金的储氢性能*

陈伟¹ 杨小军² 王培² 罗刚¹ 陈德敏¹ 杨柯¹

1. 中国科学院金属研究所沈阳 110016
2. 中核四0四有限公司兰州 732850

Hydrogen Storage Properties of La_1-_xY_xNi_4.8Mn_0.2 Alloys

CHEN Wei¹ YANG Xiaojun² WANG Pei² LUO Gang¹ CHEN Demin^1** YANG Ke¹

1. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
2. The 404 Ltd., China National Nuclear Corporation, Lanzhou 732850

引用本文:

陈伟, 杨小军, 王培, 罗刚, 陈德敏, 杨柯. La_1-_xY_xNi_4.8Mn_0.2合金的储氢性能*[J]. 材料研究学报, 2013, 27(1): 1-6.
CHEN Wei, YANG Xiaojun, WANG Pei, LUO Gang, CHEN Demin, YANG Ke. Hydrogen Storage Properties of La_1-_xY_xNi_4.8Mn_0.2 Alloys[J]. Chinese Journal of Materials Research, 2013, 27(1): 1-6.

全文: PDF(6379 KB)

摘要: 摘要研究了元素Y(钇)对La_1-_xY_xNi_4.8Mn_0.2(x=0.6, 0.7, 0.8)合金储氢性能的影响, 结果表明: La_1-_xY_xNi_4.8Mn_0.2合金为CaCu₅型六方结构; 随着Y含量的增加, 晶格参数a和晶胞体积V减小, 而c几乎不变, c/a线性增大; 随着Y含量的增加, 合金的吸放氢平台压显著升高, 吸氢量减少, 吸放氢平台斜率S_f和滞后系数H_f略有增加, 滞后系数H_f与XRD(111)峰的半高宽(FWHM)值的变化有着很好的对应关系, 抗粉化性能提高。当Y含量x=0.8时, 合金的吸放氢动力学综合性能最好。

关键词 ：金属材料, 储氢, 金属氢化物, 金属氢化物压缩机

Abstract：The influences of Y content on the crystal structure, hydrogen storage thermodynamics and kinetics, and pulverization resistance of La_1-_xY_xNi_4.8Mn_0.2(x=0.6, 0.7, 0.8) alloys were investigated systematically. The results show that all the alloys have CaCu₅ type hexagonal structure; with increasing Y content, the lattice parameter a, crystal volume V decreased, while the lattice parameter c kept almost unchanged, and c/a increased linearly. With the increase of Y content, the absorption/desorption plateau pressures increased dramatically; however, the hydrogen storage capacity decreased; the slopes of hydrogen absorption/desorption plateau declined, and the hysteresis increased lightly; A similar variation trend was presented between the hysteresis and FWHM (the full width at half maximum) of (111) XRD patterns with increasing Y content; the pulverization resistance improved. When Y content x=0.8, the alloy showed good performance both in the hydrogen absorption and desorption.

ZTFLH:

TG139

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	陈伟
	杨小军
	王培
	罗刚
	陈德敏
	杨柯
44.8K

链接本文:

https://www.cjmr.org/CN/ 或 https://www.cjmr.org/CN/Y2013/V27/I1/1

1 ZHENG Jinyang, KAI Fangming, LIU Zhongqiang, CHEN Rui, CHEN Changpin, Risk assessment and control of high pressure hydrogen equipment, Acta Energiae Solaris Sinica, 27(11), 1168(2006)

(郑津洋, 开方明, 刘仲强, 陈瑞, 陈长聘, 高压氢气储运设备及其风险评价, 太阳能学报, 27(11), 1168(2006))

2 G. Luo, J. P. Chen, S. L. Li, W. Chen, X. B. Han, D. M. Chen, K. Yang, Properties of La_0.2Y_0.8Ni_5-_xMn_x alloys for high-pressure hydrogen compressor, International Journal of Hydrogen Energy, 35(15), 8262(2010)

3 X. H. Wang, R. G. Chen, C. P. Chen, Q. D. Wang, Hydrogen storage properties of TixFe+y wt.% La and its use in metal hydride hydrogen compressor, Journal of Alloys and Compounds, 425(1-2), 291(2006)

4 P. Muthukumar, M. Prakash Maiya, S. Srinivasa Murthy, Performance tests on a thermally operated hydrogen compressor, International Journal of Hydrogen Energy, 33(1), 463(2008)

5 Z. Dehouche, N. Grimard, F. Laurencelle, J. Goyette, T. K. Bose, Hydride alloys properties investigations for hydrogen sorption compressor, Journal of Alloys and Compounds, 399(1-2), 224(2005)

6 ZHANG Yan, WANG Xinhua, FANG Guohua, LI Shouquan, CHEN Lixin, CHEN Changpin, Study on rare earth based hydrogen storage alloy for high-pressure metal hydride hydrogen compressor, Journal of Materials Science and Engineering, 24(1), 97(2006)

(张琰, 王新华, 方国华, 李寿权, 陈立新, 陈长聘, 用于超高压化学热压缩的稀土储氢合金研究, 材料科学与工程学报, 24(1), 97(2006))

7 WANG Xinhua, CHEN Rugan, LI Shouquan, CHEN Lixin, GE Hongwei, FANG Guohua, CHEN Changpin, Study on Ti-Mn/Ti-Cr hydrogen storage alloys for hydride hydrogen compressor, Rare Metal Materials And Engineering, 36(12), 2216(2007)

(王新华, 陈如柑, 李寿权, 陈立新, 葛红卫, 方国华, 陈长聘, 金属氢化物氢压缩器用Ti-Mn/Ti-Cr多元储氢合金, 稀有金属材料与工程, 36(12), 2216(2007))

8 H. Li, X. H. Wang, Z. H. Dong, L. Xu, C. P. Chen, A study on 70 MPa metal hydride hydrogen compressor, Journal of Alloys and Compounds, 502(2), 503(2010)

9 H. Uchida, M. Tada, Y. C. Huang, The influence of cerium, praseodymium, neodymium and samarium on hydrogen absorption in LaNi5 alloys, Journal of the Less Common Metals, 88(1), 81(1982)

10 S. N. Klyamkin, M. T. Hagstr?m, E. V. Mescheryakova, P. D. Lund, Hysteresis in Ce-based AB5-type metal hydrides, Journal of Materials Science, 35(1), 133(2000)

11 HU Zilong, Hydrogen Storage Material (Beijing, Chemical Industrial Press, 2002) p.102

(胡子龙, 贮氢材料 (北京, 化学工业出版社, 2002) p.102)

12 S. Mitrokhin, T. Zotov, E. Movlaev, V. Verbetsky, Synthesis and properties of AB5-type hydrides at elevated pressures, Journal of Alloys and Compounds, 446-447, 603(2007)

13 S. N. Klyamkin, V. N. Verbetsky, Interaction of intermetallic compounds with hydrogen at pressures up to 250 MPa: the LaCo_5-_xMn_x-H₂?and CeNi₅-H₂?systems, Journal of Alloys and Compounds, 194(1), 41(1993)

14 R. H. VanEssen, K. H. J. Buschow, Hydrogen sorption characteristics of Ce-3d and Y-3d intermetallic compounds, Journal of the Less Common Metals, 70(2), 189(1980)

15 E. Anil Kumar, M. Prakash Maiya, S. Srinivasa Murthy, B. Viswanathan, Structural, hydrogen storage and thermodynamic properties of some mischmetal-nickel alloys with partial substitutions for nickel, Journal of Alloys and Compounds, 476(1-2), 92(2009)

16 F. Pourarian, W. E. Wallace, The effect of substitution of Mn or Al on the?hydrogen?sorption characteristics of CeNi₅, International Journal of Hydrogen Energy, 10(1), 49(1985)

17 Y. Osumi, H. Suzuki, A. Kato, K. Oguro, S. Kawai, M. Kaneko, Hydrogen absorption-desorption characteristics of MmNiAlM and MmNiMnM alloys (Mm misch metal), Journal of the Less Common Metals, 89(1), 287(1983)

18 R. K. Singh, M. V. Lototsky, O. N. Srivastava, Thermodynamical, structural, hydrogen storage properties and simulation studies of P-C isotherms of (La, Mm)Ni_5-_yFe_y, International Journal of Hydrogen Energy, 32(14), 2971(2007)

19 D. Endo, K. Sakaki, E. Akiba, Effect of rare earth on lattice size and equilibrium hydrogen pressure for AB₅-type MmNi_3.55Co_0.75-

Al_0.30Mn_0.40, Journal of Alloys Compounds, 459(1-2), 215(2008)

20 K. A. Gschneidner Jr, T. Takeshita, Y. Chung, O. D. McMasters, Influence of electron concentration on the hydrogen absorption by RM₅ Haucke compounds, Journal of Physics F: Metal Physics, 12(1), L1(1982)

21 T. Takeshita, K. A. Gschneidner Jr., J. F. Lakner, High pressure hydrogen absorption study on YNi₅, LaPt₅?and ThNi₅, Journal of the Less Common Metals, 78(2), 43(1981)

22 Y. Xu, H. Ju, The structure, thermodynamic and electrochemical properties of hydrogen-storage alloys: An empirical methodology of average numbers of total electrons, International Journal of Hydrogen Energy, 34(4), 1880(2009)

23 C. E. Lundin, F. E. Lynch, C. B. Magee, A correlation between the interstitial hole sizes in intermetallic compounds and the thermodynamic properties of the hydrides formed from those compounds, Journal of the Less Common Metals, 56(1), 19(1977)

24 C. E. Lundin, Hydrogen storage properties and characteristics of rare earth compounds, Journal of Physics Colloques, 40(C5), 286(1979)

25 D. G. Westlake, Hydrides of intermetallic compounds: A review of stabilities, stoichiometries and preferred hydrogen sites, Journal of the Less Common Metals, 91(1), 1(1983)

26 K. J. Gross, A. Züttel, L. Schlapbach, On the possibility of metal hydride formation: Part II: Geometric considerations, Journal of Alloys and Compounds, 274(1-2), 239(1998)

27 A. Percheron-Guégan, C. Lartigue, J. C. Achard, Correlations between the structural properties, the stability and the hydrogen content of substituted LaNi₅ compounds, Journal of the Less Common Metals, 109(2), 287(1985)

28 S. Luo, C. N. Park, T. B. Flanagana, Analysis of sloping plateaux in alloys and intermetallic hydrides: II. Real systems, Journal of Alloys and Compounds, 384(1-2), 208(2004)

29 Y. Nakamura, H. Nakamura, S. Fujitani, I. Yonezu, Homogenizing behaviour in a hydrogen-absorbing LaNi_4.55Al_0.45alloy through annealing and rapid quenching, Journal of Alloys and Compounds, 210(1-2), 299(1994)

30 C. N. Park, S. Luo, T. B. Flanagan, Analysis of sloping plateaux in alloys and intermetallic hydrides: I. Diagnostic features, Journal of Alloys and Compounds, 384(1-2), 203(2004)

31 Y. Nakamura, K. Sato, S. Fujitani, K. Nishio, K. Oguro, I. Uehara, Lattice expanding behaviour and degradation of LaNi5-based alloys, Journal of Alloys and Compounds, 267(1-2), 205(1998)

32 YU Xuebin, CHEN Jinzhou, WU Zhu, XIA Baojia, Effect of Cr content on the sorption performance of TiMn_1.2-xCr_xV_0.25Fe_0.05 alloys, Acta Metallurgica Sinica, 40(5), 527(2004)

(余学斌, 陈金舟, 吴铸, 夏保佳, Cr含量对TiMn_1.2-xCr_xV_0.25-Fe_0.05合金吸/放氢性能的影响, 金属学报, 40(5), 527(2004))

33 L. OVal?en, A. Zaluska, L. Zaluski, H. Tanaka, N. Kuriyama, J. O. Str?m-Olsen, R.Tunold, Structure and related properties of (La, Ce, Nd, Pr)Ni₅ alloys, Journal of Alloys and Compounds, 306(1-2), 235(2000)

34 W. Zhang, J. Cimato, A. J. Goudy, The hydriding and dehydriding kinetics of some LaNi_5?χAl_χ?alloys, Journal of Alloys and Compounds, 201(1-2), 175(1993)

[1]	毛建军, 富童, 潘虎成, 滕常青, 张伟, 谢东升, 吴璐. AlNbMoZrB系难熔高熵合金的Kr离子辐照损伤行为[J]. 材料研究学报, 2023, 37(9): 641-648.
[2]	宋莉芳, 闫佳豪, 张佃康, 薛程, 夏慧芸, 牛艳辉. 碱金属掺杂MIL125的CO₂ 吸附性能[J]. 材料研究学报, 2023, 37(9): 649-654.
[3]	赵政翔, 廖露海, 徐芳泓, 张威, 李静媛. 超级奥氏体不锈钢24Cr-22Ni-7Mo-0.4N的热变形行为及其组织演变[J]. 材料研究学报, 2023, 37(9): 655-667.
[4]	邵鸿媚, 崔勇, 徐文迪, 张伟, 申晓毅, 翟玉春. 空心球形AlOOH的无模板水热制备和吸附性能[J]. 材料研究学报, 2023, 37(9): 675-684.
[5]	幸定琴, 涂坚, 罗森, 周志明. C含量对VCoNi中熵合金微观组织和性能的影响[J]. 材料研究学报, 2023, 37(9): 685-696.
[6]	欧阳康昕, 周达, 杨宇帆, 张磊. 含LPSO相Mg-Y-Er-Ni合金的组织和拉伸性能[J]. 材料研究学报, 2023, 37(9): 697-705.
[7]	徐利君, 郑策, 冯小辉, 黄秋燕, 李应举, 杨院生. 定向再结晶对热轧态Cu71Al18Mn11合金的组织和超弹性性能的影响[J]. 材料研究学报, 2023, 37(8): 571-580.
[8]	熊诗琪, 刘恩泽, 谭政, 宁礼奎, 佟健, 郑志, 李海英. 固溶处理对一种低偏析高温合金组织的影响[J]. 材料研究学报, 2023, 37(8): 603-613.
[9]	刘继浩, 迟宏宵, 武会宾, 马党参, 周健, 徐辉霞. 喷射成形M3高速钢热处理过程中组织的演变和硬度偏低问题[J]. 材料研究学报, 2023, 37(8): 625-632.
[10]	由宝栋, 朱明伟, 杨鹏举, 何杰. 合金相分离制备多孔金属材料的研究进展[J]. 材料研究学报, 2023, 37(8): 561-570.
[11]	任富彦, 欧阳二明. g-C₃N₄ 改性Bi₂O₃ 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640.
[12]	王昊, 崔君军, 赵明久. 镍基高温合金GH3536带箔材的再结晶与晶粒长大行为[J]. 材料研究学报, 2023, 37(7): 535-542.
[13]	刘明珠, 樊娆, 张萧宇, 马泽元, 梁城洋, 曹颖, 耿仕通, 李玲. SnO₂ 作散射层的光阳极膜厚对量子点染料敏化太阳能电池光电性能的影响[J]. 材料研究学报, 2023, 37(7): 554-560.
[14]	秦鹤勇, 李振团, 赵光普, 张文云, 张晓敏. 固溶温度对GH4742合金力学性能及γ' 相的影响[J]. 材料研究学报, 2023, 37(7): 502-510.
[15]	刘天福, 张滨, 张均锋, 徐强, 宋竹满, 张广平. 缺口应力集中系数对TC4 ELI合金低周疲劳性能的影响[J]. 材料研究学报, 2023, 37(7): 511-522.

Viewed

Full text

Abstract

Cited

Shared

Discussed