Mn掺杂对(Y0.4Er0.6)3Al5O12 热障涂层材料的微观结构和导热性能的影响

doi:10.11901/1005.3093.2023.415

材料研究学报

2024, Vol. 38

Issue (6): 463-470 DOI: 10.11901/1005.3093.2023.415

研究论文

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Mn掺杂对(Y_0.4Er_0.6)₃Al₅O₁₂ 热障涂层材料的微观结构和导热性能的影响

王俊, 王炫力(

), 刘爽, 宋蕊, 宋希文

内蒙古科技大学材料科学与工程学院包头 014010

Effect of Mn Doping on Microstructure and Thermal Conductivity of (Y_0.4Er_0.6)₃Al₅O₁₂ Ceramics Material for Thermal Barrier Coating

WANG Jun, WANG Xuanli(

), LIU Shuang, SONG Rui, SONG Xiwen

School of Materials Science and Engineering, Inner Mongolia University of Science and Technology, Baotou 014010, China

引用本文:

王俊, 王炫力, 刘爽, 宋蕊, 宋希文. Mn掺杂对(Y_0.4Er_0.6)₃Al₅O₁₂ 热障涂层材料的微观结构和导热性能的影响[J]. 材料研究学报, 2024, 38(6): 463-470.
Jun WANG, Xuanli WANG, Shuang LIU, Rui SONG, Xiwen SONG. Effect of Mn Doping on Microstructure and Thermal Conductivity of (Y_0.4Er_0.6)₃Al₅O₁₂ Ceramics Material for Thermal Barrier Coating[J]. Chinese Journal of Materials Research, 2024, 38(6): 463-470.

全文: PDF(11102 KB) HTML

摘要:

采用固相合成法制备(Y_0.4Er_0.6)₃(Al_{1 -}_y Mn _y )₅O₁₂ (y = 0，0.02，0.04，0.06，0.08，0.1)陶瓷材料，使用X射线衍射仪及Rietveld精修、X射线光电子能谱仪、扫描电子显微镜、X射线能谱仪、透射电子显微镜和激光导热仪等手段对其表征，研究了Mn掺杂对其微观结构和导热性能的影响。结果表明：(Y_0.4Er_0.6)₃(Al_{1 -}_y Mn _y )₅O₁₂陶瓷材料均为单一的YAG相，随着Mn掺杂量的提高晶格常数和晶胞体积先减小后增大，Mn²⁺逐渐占据晶胞中的Al³⁺位置但是Y₃Al₅O₁₂的晶体结构不变；Mn掺杂使(Y_0.4Er_0.6)₃(Al_{1 -}_y Mn _y )₅O₁₂陶瓷材料的热导率显著降低，y = 0.06的陶瓷材料热导率最低，在1100℃热导率约为1.38 W/(m·K)，比纯YAG陶瓷的热导率(2.1 W/(m·K))降低了约34.6%。

关键词 ：无机非金属材料, 热障涂层, 钇铝石榴石, 双位掺杂, 微观结构, 热导率

Abstract：

Ceramic materials (Y_0.4Er_0.6)₃(Al_{1 -}_y Mn _y )₅O₁₂ (y = 0, 0.02, 0.04, 0.06, 0.08, 0.1) were prepared by solid phase synthesis method, and their microstructure and thermal conductivity were studied by X-ray diffractometer and Rietveld refinement method, X-ray photoelectron spectroscopy, scanning electron microscopy, X-ray energy spectroscopy, transmission electron microscopy, laser thermal conductivity tester. The results show that the ceramic materials of (Y_0.4Er_0.6)₃(Al_{1 -}_y Mn _y )₅O₁₂ are all single YAG phase, with the increase of Mn doping, the lattice constant and cell volume decrease and then increase, Mn²⁺ gradually occupies the position of Al³⁺ in the cell, keeping the crystal structure of Y₃Al₅O₁₂ unchanged; the thermal conductivity of the ceramic material (Y_0.4Er_0.6)₃(Al_{1 -}_y Mn _y )₅O₁₂ is significantly reduced, with the lowest thermal conductivity at Mn doping y = 0.06, which is about 1.38 W/(m·K) at 1100^oC, and reduced by about 34.6 % compared to that of the pure ceramic material YAG (2.1 W/(m·K)).

Key words： inorganic non-metallic materials thermal barrier coating yttrium aluminum garnet double-site doping microstructure thermal conductivity

收稿日期: 2023-08-23

ZTFLH:

TQ174.1

基金资助:国家自然科学基金(52372062);内蒙古自治区直属高校基本科研业务费项目(2023QNJS016);内蒙古科技大学创新基金项目(2019QDL-B03)

通讯作者: 王炫力，wangxuanli917@163.com，研究方向为高强高韧结构陶瓷材料

Corresponding author: WANG Xuanli, Tel: 15374723217, E-mail: wangxuanli917@163.com

作者简介: 王俊，男，1998年生，硕士生

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图1 (Y0.4Er0.6)3(Al1 - y Mn y )5O12 (y = 0, 0.02, 0.04, 0.06, 0.08, 0.1)陶瓷材料的XRD谱及其局部放大图谱

图2 (Y0.4Er0.6)3(Al1 - y Mn y )5O12陶瓷材料的Rietveld精修

表1 (Y0.4Er0.6)3(Al1 - y Mn y )5O12陶瓷材料经Rietveld精修的晶胞参数和精修数据

表2 (Y0.4Er0.6)3(Al0.94Mn0.06)5O12陶瓷材料的Rietveld全谱拟合结构精修参数

图3 (Y0.4Er0.6)3(Al1 - y Mn y )5O12陶瓷材料的XPS全谱

图4 (Y0.4Er0.6)3(Al1 - y Mn y )5O12陶瓷材料的Mn2p XPS精细谱

图5 (Y0.4Er0.6)3(Al0.94Mn0.06)5O12陶瓷材料的TEM及HRTEM照片

图6 不同掺杂量(Y0.4Er0.6)3(Al1 - y Mn y )5O12陶瓷材料的FESEM照片

图7 (Y0.4Er0.6)3(Al0.94Mn0.06)5O12陶瓷材料的EDS能谱

表3 (Y0.4Er0.6)3(Al1 - y Mn y )5O12陶瓷材料的热扩散系数λ

图8 (Y0.4Er0.6)3(Al1 - y Mn y )5O12 (y = 0，0.02，0.04，0.06，0.08，0.1)陶瓷材料的热导率

1	Padture N P, Gell M, Jordan E H. Thermal barrier coatings for gas-turbine engine applications [J]. Science, 2002, 296(5566): 280 pmid: 11951028
2	Clarke D R, Phillpot S R. Thermal barrier coating materials [J]. Mater. Today, 2005, 8(6): 22
3	Kumar A, Moledina J, Liu Y, et al. Nano-micro-structured 6%~8% YSZ thermal barrier coatings: a comprehensive review of comparative performance analysis [J]. Coatings, 2021, 11(12): 1474
4	Li R Y, Xie M, Zhang Y H, et al. Physical properties of Er₂O₃ Doped Gd₂(Zr_0.8Ti_0.2)₂O₇ ceramic materials [J]. Chin. J. Mater. Res., 2022, 36(1): 49
4	李瑞一, 谢敏, 张永和等. Er₂O₃掺杂Gd₂(Zr_0.8Ti_0.2)₂O₇陶瓷的物理性能 [J]. 材料研究学报, 2022, 36(1): 49 doi: 10.11901/1005.3093.2021.230
5	Jiang T, Xie M, Wang X L, et al. Effects of Nb⁵⁺ doping on thermal properties of Gd₂(Zr_{1 -} _x Nb _x )₂O₇₊ _x ceramics [J]. Adv. Appl. Ceram., 2020, 119(4): 212
6	Yan Z M, Levi A, Zhang Y, et al. A numerical evaluation and guideline for thermal barrier coatings on gasoline compression ignition engines [J]. Int. J. Eng. Res., 2023, 24(5): 2206
7	Xie M, An S L, Song X W, et al. Effects of Er³⁺ doping on structure and thermal properties of (Sm_{1 -} _x Er _x )₂Zr₂O₇ ceramics for thermal barrier coating [J]. J. Rare Earths, 2022, 40(12): 1920
8	Jiang T, Xie M, Guan L L, et al. Effect of Nb⁵⁺ and Cu²⁺ codoping on thermal properties of Gd₂Zr₂O₇ Ceramic [J]. J. Rare Earths, 2021, 39(2): 180
9	An G S, Li W S, Feng L, et al. Isothermal oxidation and TGO growth behaviors of YAG/YSZ double-ceramic-layer thermal barrier coatings [J]. Ceram. Int., 2021, 47(17): 24320
10	Kumar R, Rommel S, Jiang C, et al. Effect of CMAS viscosity on the infiltration depth in thermal barrier coatings of different microstructures [J]. Surf. Coat. Technol., 2022, 432: 128039
11	Sun S Y, Xue Z L, He W T, et al. Corrosion resistant plasma sprayed (Y_0.8Gd_0.2)₃Al₅O₁₂/YSZ thermal barrier coatings towards molten calcium-magnesium-alumina-silicate [J]. Ceram. Int., 2019, 45(7): 8138
12	Li M H, Wang D R, Xue J C, et al. Preparation of Pd-doped Y₃Al₅O₁₂ thermal barrier coatings using cathode plasma electrolytic deposition [J]. Ceram. Int., 2020, 46(6): 7019
13	Owoseni T A, Rincon Romero A, Pala Z, et al. YAG thermal barrier coatings deposited by suspension and solution precursor thermal spray [J]. Ceram. Int., 2021, 47(17): 23803
14	Wang X L, Xing J X, Xie M, et al. Influence of Er³⁺ doping on the mechanical and thermophysical properties of (Er _x Y_{1 -} _x )₃Al₅O₁₂ ceramics [J]. Process. Appl. Ceram., 2023, 17(1): 23
15	Liu Y G, Peng P, Fang M H, et al. Y_{3 -} _x Er _x Al₅O₁₂ aluminate ceramics: preparation, thermal properties and theoretical model of thermal conductivity [J]. Adv. Eng. Mater., 2012, 14(3): 170
16	Wang J, Xu F, Wheatley R J, et al. Yb³⁺ doping effects on thermal conductivity and thermal expansion of yttrium aluminium garnet [J]. Ceram. Int., 2016, 42(12): 14228
17	Xie M, Cui Y, Zhang K, et al. Analysis of thermal conductivity behavior of Yb³⁺ and Er³⁺ Co-doped Sm₂Zr₂O₇ Ceramics [J]. Aeronaut. Manuf. Technol., 2023, 66(suppl.1) : 61
17	谢敏, 崔越, 张凯等. Yb³⁺、Er³⁺共掺杂Sm₂Zr₂O₇陶瓷导热性能研究 [J]. 航空制造技术, 2023, 66(): 61
18	Shu J, Lu M L, Zhang G F, et al. Preparation and redox performance of nanosized Ce_0.92M_0.08O₂ (M = Co, Mn, Fe, La) solid solutions [J]. J. Mater. Eng., 2023, 51(3): 138
18	束俊, 陆旻琳, 张国芳等. 纳米Ce_0.92M_0.08O₂ (M = Co, Mn, Fe, La) 固溶体的制备及其氧化还原性能 [J]. 材料工程, 2023, 51(3): 138
19	Xue Z L, Ma Y, Gong S K, et al. Influence of Yb³⁺ doping on phase stability and thermophysical properties of (Y_{1 -} _x Yb _x )₃Al₅O₁₂ under high temperature [J]. Ceram. Int., 2017, 43(9): 7153
20	Du Z, Zhao Y L, Kuang D H, et al. Preparation and photocatalytic properties of BiFe_{1 -} _x Mn _x O₃ nano-powders [J]. Mater. Rep., 2023, 37(13): 21100037-1
20	杜泽, 赵尉伶, 匡代洪等. BiFe_{1 -} _x Mn _x O₃纳米粉末的制备及光催化性能 [J]. 材料导报, 2023, 37(13): 21100037-1
21	Huang H Y, Xiang W D, Zhang Z M, et al. Preparation and luminescence properties of cerium, manganese Co-doping YAG glass ceramics [J]. J. Chin. Soc. Rare Earths, 2012, 30(6): 726
21	黄海宇, 向卫东, 张志敏等. YAG: Ce, Mn微晶玻璃的制备及光谱性能研究 [J]. 中国稀土学报, 2012, 30(6): 726

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