钠离子电池双层碳包覆Na3V2(PO4)3 正极材料的超声辅助溶液燃烧合成及其电化学性能

doi:10.11901/1005.3093.2021.566

材料研究学报

2023, Vol. 37

Issue (2): 129-135 DOI: 10.11901/1005.3093.2021.566

研究论文

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钠离子电池双层碳包覆Na₃V₂(PO₄)₃ 正极材料的超声辅助溶液燃烧合成及其电化学性能

罗昱, 陈秋云, 薛丽红(

), 张五星, 严有为

华中科技大学材料科学与工程学院材料成形与模具技术国家重点实验室武汉 430074

Preparation of Double-layer Carbon Coated Na₃V₂(PO₄)₃ as Cathode Material for Sodium-ion Batteries by Ultrasonic-assisted Solution Combustion and Its Electrochemical Performance

LUO Yu, CHEN Qiuyun, XUE Lihong(

), ZHANG Wuxing, YAN Youwei

State Key Laboratory of Materials Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong Universtiy of Scienc and Technology, Wuhan 430074, China

引用本文:

罗昱, 陈秋云, 薛丽红, 张五星, 严有为. 钠离子电池双层碳包覆Na₃V₂(PO₄)₃ 正极材料的超声辅助溶液燃烧合成及其电化学性能[J]. 材料研究学报, 2023, 37(2): 129-135.
Yu LUO, Qiuyun CHEN, Lihong XUE, Wuxing ZHANG, Youwei YAN. Preparation of Double-layer Carbon Coated Na₃V₂(PO₄)₃ as Cathode Material for Sodium-ion Batteries by Ultrasonic-assisted Solution Combustion and Its Electrochemical Performance[J]. Chinese Journal of Materials Research, 2023, 37(2): 129-135.

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摘要:

用超声辅助溶液燃烧合成技术制备双层碳包覆的Na₃V₂(PO₄)₃ (NVP)钠离子电池正极材料，并对其电化学性能进行深入的研究。结果表明，双层碳包覆在NVP颗粒表面，由内自外分别为无定形硬碳和石墨烯。石墨烯添加量为5.0%(质量分数)的碳包覆NVP复合材料具有优异的电化学性能，在1 C倍率下充放电其初始比容量为117 mAh·g^–1，循环300圈后容量的保持率为79%，在10 C倍率下其放电比容量高达100 mAh·g^–1。这种正极材料电化学动力学性能的提高，源于均匀的双层碳包覆结构及其构建的三维电子传输通道。

关键词 ：复合材料, C@Na₃V₂（PO₄）₃, 超声辅助溶液燃烧, 钠离子电池

Abstract：

Double-layer carbon coated Na₃V₂(PO₄)₃ (NVP), as cathode material for sodium-ion batteries, was successfully synthesized by ultrasonic-assisted solution combustion synthesis, and its structure, morphology and electrochemical properties were investigated. The results show that the surface of NVP particles is firstly coated with an amorphous hard carbon layer, subsequently with a graphene layer. When the graphene content is 5.0%, the carbon-coated NVP composite exhibits excellent electrochemical properties. It delivers an initial discharge capacity of 117 mAh·g^–1 at 1 C, and retains 79% of the initial capacity after 300 cycles. Even at 10 C, it still maintains a discharge capacity as high as 100 mAh·g^–1. The significant improvement of the sodium storage performance can be ascribed to the special structure of homogeneous double-layer carbon coating, which can act as a 3-dimentional network as electron pathway.

Key words： composite C@Na₃V₂(PO₄)₃ ultrasonic-assisted solution combustion Na-ion battery

收稿日期: 2021-09-28

ZTFLH:

TM911

基金资助:国家重点研发计划(2016YFB0100302)

作者简介: 罗昱，男，1990年生，博士生

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https://www.cjmr.org/CN/10.11901/1005.3093.2021.566 或 https://www.cjmr.org/CN/Y2023/V37/I2/129

图1 碳包覆NVP的XRD谱

图2 碳包覆NVP的拉曼谱

图3 石墨烯纳米片的TEM照片

图4 GO添加量不同的碳包覆NVP的SEM照片

图5 GO添加量不同的NVP的HRTEM图

图6 GO添加量不同的NVP的N2吸/脱附等温曲线(内嵌为孔径分布图)

图7 GO添加量不同的NVP的电化学阻抗奈奎斯特图

图8 GO添加量不同的NVP的电化学性能

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