原位自生法制备石墨烯增强镁基复合材料的工艺和性能

doi:10.11901/1005.3093.2020.385

材料研究学报

2021, Vol. 35

Issue (6): 474-480 DOI: 10.11901/1005.3093.2020.385

研究论文

本期目录 | 过刊浏览

原位自生法制备石墨烯增强镁基复合材料的工艺和性能

王殿君¹(

), 张明秋¹, 吉泽升², 张吉生¹, 魏源¹

^1.黑龙江工业学院现代制造工程学院鸡西 158100
^2.哈尔滨理工大学材料科学与工程学院哈尔滨 151000

Process and Properties of Graphene Reinforced Mg-based Composite Prepared by In-situ Method

WANG Dianjun¹(

), ZHANG Mingqiu¹, JI Zesheng², ZHANG Jisheng¹, WEI Yuan¹

^1.School of Modern Manufacturing Engineering, Heilongjiang Institute of Technology, Jixi 158100, China
^2.School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 151000, China

引用本文:

王殿君, 张明秋, 吉泽升, 张吉生, 魏源. 原位自生法制备石墨烯增强镁基复合材料的工艺和性能[J]. 材料研究学报, 2021, 35(6): 474-480.
Dianjun WANG, Mingqiu ZHANG, Zesheng JI, Jisheng ZHANG, Yuan WEI. Process and Properties of Graphene Reinforced Mg-based Composite Prepared by In-situ Method[J]. Chinese Journal of Materials Research, 2021, 35(6): 474-480.

全文: PDF(12947 KB) HTML

摘要:

采用原位自生法制备石墨烯增强的镁基复合材料，并使用Raman、XPS、XRD、SEM和TEM以及电子万能拉伸试验机等手段表征了原位生成的石墨烯的微观形貌和复合材料的力学性能。结果表明:进行原位反应可制备石墨烯增强的镁基复合材料，反应温度越高原位生成的石墨烯的质量越好，制备出的复合材料的性能越高。反应温度为780℃时复合材料的力学性能达到最大值，其屈服强度、抗拉强度和延伸率分别为245 MPa、340 MPa和6.7%，比基体的力学性能分别提高了40%、21.4%和48.8%。

关键词 ：复合材料, 原位自生法, 石墨烯, 镁基复合材料, 显微组织, 力学性能

Abstract：

The graphene reinforced Mg-based composite material was prepared by in-situ method, and then the in-situ generated graphene and the prepared composite were characterized by means of Raman, XPS, XRD, SEM, TEM and electronic universal tensile testing machine. The results show that graphene-reinforced Mg-based composites can be prepared via in-situ reaction. As the reaction temperature increases the quality of the in-situ generated graphene increases, and the performance of the resulted composites is better. When the reaction temperature is 780℃ the mechanical properties of the composite material reach the maximum, namely, its yield strength, tensile strength and elongation are 245 MPa, 340 MPa and 6.7%, respectively. The yield strength, tensile strength and elongation increased by 40%, 21.4% and 48.8%, respectively, compared with the plain Mg-alloy.

Key words： composite in situ method graphene magnesium matrix composite microstructure mechanical properties

收稿日期: 2020-09-11

ZTFLH:

TB331

基金资助:黑龙江省自然科学基金(LH2019E117)

作者简介: 王殿君，男，1976年生，副教授

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https://www.cjmr.org/CN/10.11901/1005.3093.2020.385 或 https://www.cjmr.org/CN/Y2021/V35/I6/474

表1 AZ31镁合金的化学成分

图1 原位反应制备石墨烯/镁复合材料的流程

图2 在不同反应温度下原位自生的石墨烯的拉曼光谱和ID/IG和I2D/IG比值

图3 在780℃原位自生的石墨烯的XRD谱

图4 在780℃原位自生石墨烯的XPS分析

图5 在780℃原位自生石墨烯的SEM形貌和在镁基体中的分布

图6 在780℃原位自生石墨烯的TEM形貌

图7 原位自生石墨烯增强镁基复合材料的力学性能

图8 在780℃原位自生石墨烯增强镁基复合材料的断口形貌

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