Ni(OH)<sub>2</sub>/RGO复合材料的化学沉淀-回流法制备和放电性能

doi:10.11901/1005.3093.2016.322

材料研究学报

2017, Vol. 31

Issue (3): 226-232 DOI: 10.11901/1005.3093.2016.322

研究论文

本期目录 | 过刊浏览

Ni(OH)₂/RGO复合材料的化学沉淀-回流法制备和放电性能

于慧颖¹,赫文秀¹(

),张永强¹,安胜利¹,刘君红²

1 内蒙古科技大学化学与化工学院包头 014010
2 包头职业技术学院包头 014010

Chemical Precipitation-reflux Synthesis and Discharge Performance of Composite of Nickel Hydroxide /Reduced Graphene Oxide

Huiying YU¹,Wenxiu HE¹(

),Yongqiang ZHANG¹,Shengli AN¹,Junhong LIU²

1 School of Chemistry and Chemistry Engineering, Inner Mongolia University of Science & Technology, Baotou 014010, China
2 Baotou Professional Technology College, Baotou 014010, China

引用本文:

于慧颖,赫文秀,张永强,安胜利,刘君红. Ni(OH)₂/RGO复合材料的化学沉淀-回流法制备和放电性能[J]. 材料研究学报, 2017, 31(3): 226-232.
Huiying YU, Wenxiu HE, Yongqiang ZHANG, Shengli AN, Junhong LIU. Chemical Precipitation-reflux Synthesis and Discharge Performance of Composite of Nickel Hydroxide /Reduced Graphene Oxide[J]. Chinese Journal of Materials Research, 2017, 31(3): 226-232.

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摘要:

以氧化石墨(GO)和NiSO₄6H₂O为前驱体,氨水为沉淀剂,用化学沉淀-回流法制备Ni(OH)₂/还原氧化石墨烯(RGO)复合材料,用XRD、SEM表征材料的结构和表面微观形貌,用循环伏安(CV)、恒电流充放电和电化学阻抗(EIS)测试电极材料的电化学性能,研究了GO:Ni(OH)₂质量比和氨水浓度对复合材料结构、形貌和电化学性能的影响。结果表明：所制备的β-Ni(OH)₂/RGO复合材料为Ni(OH)₂纳米片与RGO片相互插层的结构,当氨水的浓度为3 mol/L,GO:Ni(OH)₂=1:8(质量比)时复合电极材料在0.2C的放电比容量高达334.9 mAh/g,5C的放电比容量为260.2 mAh/g,保持在β-Ni(OH)₂理论比容量的90%,表现出良好的倍率性能和循环性能。

关键词 ：复合材料, 化学沉淀-回流法, β-Ni(OH)₂, 还原氧化石墨烯, 电化学性能

Abstract：

Composite of nickel hydroxide/reduced graphene oxide (Ni(OH)₂/RGO) was synthesized by facile chemical precipitation-reflux method with graphite oxide and nickel sulfate hexahydrate as precursors and ammonium hydroxide as the precipitator. The surface morphology and microscopic structures of the composite were characterized by X-ray diffraction (XRD) and scan electron microscopy (SEM). The electrochemical performance of the composite was assessed by cyclic voltammetry (CV), galvanostatic charge/discharge and electrochemical impedance spectroscopy (EIS). The influence of different mass ratio of graphite oxide to nickel hydroxide (GO: Ni(OH)₂) and the concentration of ammonium hydroxide on structures, morphologies, and electrochemical properties of the composite was investigated. The results show that the synthesized composite of β-Ni(OH)₂/RGO has mutually inserted structure. The composite of β-Ni(OH)₂/RGO exhibits high electrochemical performance of 334.9 mAh/g at 0.2C rate and 260.2 mAh/g at 5C rate when the concentration of ammonium hydroxide is 3 mol/L and the mass ratio of GO:Ni(OH)₂ is 1:8, while the product can still maintain 90% of the theoretical specific capacity of β-Ni(OH)₂. It displays that this electrode material has excellent electrochemical performance with excellent rate capability.

Key words： composite chemical precipitation-reflux method β-Ni(OH)₂ reduced graphene oxide electrochemical performance

收稿日期: 2016-06-12

基金资助:内蒙古自然科学基金(2014MS0523、2015MS0208),内蒙古自治区高等学校青年科技英才计划-青年科技领军人才A类项目(NJYT-14-A08)和包头市科技计划(2015C2004-1)资助项目

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https://www.cjmr.org/CN/10.11901/1005.3093.2016.322 或 https://www.cjmr.org/CN/Y2017/V31/I3/226

图1 GN8(5M)、GN10(3M)和GN8(3M)复合材料的XRD图谱

图2 Ni(OH)2、 GN8(5M)、 GN10(3M)和GN8(3M)复合材料的FE-SEM图

图3 Ni(OH)2、GN8(5M)、GN10(3M)和GN8(3M)电极材料在不同扫描速率下的CV曲线

图4 Ni(OH)2和Ni(OH)2/RGO电极材料在0.2C倍率下的充放电曲线

图5 Ni(OH)2和Ni(OH)2/RGO电极材料在不同倍率下的放电比容量曲线

图6 Ni(OH)2和Ni(OH)2/RGO电极材料在不同倍率下的循环稳定性曲线

图7 Ni(OH)2和Ni(OH)2/RGO电极材料的电化学阻抗图谱及其高频区的放大图

[1]	Fang Q, Xie S Y, Cheng Y, et al.Effects of nanoscale conductive additives on high temperature and high power performance of nickel electrodes[J]. Chin. J. Rare Metals, 2009, 33: 376
[1]	(方庆, 谢守韫, 成艳等. 纳米导电剂对镍电极高温/高功率性能的影响[J]. 稀有金属, 2009, 33: 376)
[2]	Tang Y G.Ni/MH Batteries[M]. Beijing: Chemical Industry Press, 2007: 100
[2]	(唐有根. 镍氢电池[M]. 北京: 化学工业出版社, 2007: 100)
[3]	Liang Y Y, Wu D Q, Feng X L, et al.Dispersion of graphene sheets in organic solvent supported by ionic interactions[J]. Adv. Mater., 2009, 21: 1679
[4]	Wu Z, Huang X L, Wang Z L, et al.Electrostatic induced stretch growth of homogeneous β-Ni(OH)2 on Graphene with enhanced high-rate cycling for Supercapacitors[J]. Sci. Rep., 2014, 4: 3669
[5]	Wang L N, Chen H Y, Cai F, et al.Hierarchical carbon nanotube/α-Ni(OH)2 nanosheet composite paper with enhanced electrochemical capacitance[J]. Mater. Let., 2014, 115: 168
[6]	Zhang J L, Liu H D, Shi P, et al.Growth of nickel (111) plane: The key role in nickel for further improving the electrochemical property of hexagonal nickel hydroxide-nickel & reduced graphene oxide composite[J]. J. Power Sour., 2014, 267: 356
[7]	Ji J Y, Zhang L L, Ji H X, et al.Nanoporous Ni(OH)2 thin film on 3D ultrathin-graphite foam for asymmetric supercapacitor[J]. ACS Nano, 2013, 7: 6237
[8]	Yan J, Fan Z J, Sun W, et al.Advanced asymmetric Supercapacitors based on Ni(OH)2 /Graphene and porous Graphene electrodes with high energy density[J]. Adv. Funct. Mater., 2012, 22: 2632
[9]	Kim Y, Cho E S, Park S J, et al.One-pot microwave-assisted synthesis of reduced graphene oxide/nickel cobalt double hydroxide composites and their electrochemical behavior[J]. J. Ind. Eng. Chem., 2016, 33: 110
[10]	Zhu J W, Chen S, Zhou H, et al.Fabrication of a low defect density graphene-nickel hydroxide nanosheet hybrid with enhanced electrochemical performance[J]. Nano Res., 2012, 5: 11
[11]	Xie J F, Sun X, Zhang N, et al.Layer-by-layer β-Ni(OH)2/graphene nanohybrids for ultraflexible all-solid-state thin-film Supercapacitors with high electrochemical performance[J]. Nano Energy, 2013, 2: 65
[12]	Huang Z N, Kou S Z, Jin D D, et al.Performance of Ni(OH)2/reduced graphene oxides composites for supercapacitors[J]. J. Funct. Mater., 2015, 46: 5084
[12]	(黄振楠, 寇生中, 金东东等. 氢氧化镍/还原氧化石墨烯复合物的超级电容性能[J]. 功能材料, 2015, 46: 5084)
[13]	Fang D L, Chen Z D, Liu X, et al.Homogeneous growth of nano-sized β-Ni(OH)2 on reduced graphene oxide for high-performance supercapacitors[J]. Electrochim. Acta, 2012, 81: 321
[14]	Fu W D, Gong Y C, Wang M, et al.β-Ni(OH)2 nanosheets grown on graphene as advanced electrochemical pseudocapacitor materials with improved rate capability and cycle performance[J]. Mater. Let., 2014, 134: 107
[15]	HummersJr W S, Offeman R E. Preparation of graphitic oxide[J]. J. Am. Chem. Soc., 1958, 80: 1339
[16]	Sheng K X, Xu Y X, Li C, et al.High-performance self-assembled graphene hydrogels prepared by chemical reduction of graphene oxide[J]. New Carbon Mater., 2011, 26: 9
[17]	Li Z Q, Lu C J, Xia Z P, et al.X-ray diffraction patterns of graphite and turbostratic carbon[J]. Carbon, 2007, 45: 1686
[18]	Kim J, Kim Y, Park S J, et al.Preparation and electrochemical analysis of graphene nanosheets/nickel hydroxide composite electrodes containing carbon nanotubes[J]. J. Ind. Eng. Chem., 2016, 36: 139
[19]	Watanabe K, Kikuoka T, Kumagai N.Physical and electrochemical characteristics of nickel hydroxide as a positive material for rechargeable alkaline batteries[J]. J. Appl. Electrochem., 1995, 25: 219
[20]	Nan J M, Tang Z Y, Liu J H, et al.XRD and Raman spectrometric characterization on Ni(OH)2 electrode materials[J]. Chin. J. Appl. Chem., 2001, 18: 108
[20]	(南俊民, 唐致远, 刘建华等. Ni(OH)2电极材料的XRD和Raman光谱表征[J]. 应用化学, 2001, 18: 108)
[21]	Xu M W, Bao S J, Li H L.Synthesis and characterization of mesoporous nickel oxide for electrochemical capacitor[J]. J. Solid State Electrochem., 2007, 11: 372
[22]	Chen X A, Chen X H, Zhang F Q, et al.One-pot hydrothermal synthesis of reduced graphene oxide/carbon nanotube/α-Ni(OH)2 composites for high performance electrochemical supercapacitor[J]. J. Power Sour., 2013, 243: 555
[23]	Lei H.Synthesis and property studies of high-capacity Ni-MH battery cathode materials [D]. Beijing: Beijing Nonferrous Metal Research Institute, 2014
[23]	(雷浩. 高容量镍氢电池正极合成与性能研究 [D]. 北京: 北京有色金属研究总院, 2014)
[24]	Yang Y.The preparation of Ni(OH)2 mixing with graphene oxide and studying the electrical performance [D]. Xinxiang: Henan Normal University, 2012
[24]	(杨祎. 氢氧化镍掺杂氧化石墨烯的制备以及电性能的研究 [D]. 新乡: 河南师范大学, 2012)
[25]	Yang W L, Gao Z, Wang J, et al.Synthesis of reduced graphene nanosheet/urchin-like manganese dioxide composite and high performance as supercapacitor electrode[J]. Electrochim. Acta, 2012, 69: 112

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