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材料研究学报  2012, Vol. 26 Issue (6): 621-626    
  研究论文 本期目录 | 过刊浏览 |
磁性羟基磷灰石的制备及其Pb(II)吸附性能
杨慧慧1,2, 张浩1, 黄传军1, 黄荣进1, 李来风1
1.中国科学院低温工程学重点实验室(中国科学院理化技术研究所) 北京 100190
2.中国科学院大学 北京 100049
Fabrication and Pb(II) Adsorptive Properties of Magnetic Hydroxyapatite
YANG Huihui1,2,  ZHANG Hao1,  HUANG Chuanjun1,  HUANG Rongjin1,  LI Laifeng1
1.Key Laboratory of Cryogenics, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190
2.University of Chinese Academy of Sciences, Beijing 100049
引用本文:

杨慧慧 张浩 黄传军 黄荣进 李来风. 磁性羟基磷灰石的制备及其Pb(II)吸附性能[J]. 材料研究学报, 2012, 26(6): 621-626.
YANG Huihui ZHANG Hao HUANG Chuanjun HUANG Rongjin LI Laifeng. Fabrication and Pb(II) Adsorptive Properties of Magnetic Hydroxyapatite[J]. Chinese Journal of Materials Research, 2012, 26(6): 621-626.

全文: PDF(1037 KB)  
摘要: 

以Ca(OH)2、NH4H2PO4为原料, 在25℃恒温条件下用共沉淀法制备磁性羟基磷灰石(HAp)复合材料。利用X射线衍射(XRD)、场发射扫描电镜(FEG--SEM)、高分辨透射电子显微镜(HR--TEM)和氮气吸附--脱吸附(BET)对其化学组成、形貌结构和性能进行表征, 并对其Pb(II)性能进行了研究。结果表明, 复合材料的均一性、分散性良好, 多数Fe3O4纳米颗粒沉积在HAp材料表面, 部分生长在HAp结构内部, 结合牢固;Fe3O4减轻了HAp的团聚, 使材料的比表面积增大, 并使其对Pb(II)的吸附性能显著提高。

关键词 复合材料纳米Fe3O4羟基磷灰石Pb(II)吸附    
Abstract

Magnetic hydroxyapatite composite was prepared by coprecipitation method with Fe3O4 particles and Ca(OH)2, and NH4H2PO4 as its raw material. The crystal structure and surface morphology of the composite were characterized by means of X-ray diffractometer (XRD), the field emission scanning electron microscopy (FEG-SEM), high--resolution transmission electron microscope (HR-TEM) and Brunauer-Emmett-Teller (BET), respectively. The results show that the composite is homogenous. Fe3O4 particles mostly deposite well on the surface of HAp and sometimes incorporated into the HAp material, which leads to the higher specific surface area and better Pb(II) adsorption of the HAp material.

Key wordscomposite material    nano Fe3O4    hydroxyapatite    Pb(II) adsorption
收稿日期: 2012-09-10     
ZTFLH:  TB332  
基金资助:

国家自然科学基金51107139资助项目。

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