透明MSe2@氮掺杂碳膜对电极用于钴电解质双面DSSC

doi:10.11901/1005.3093.2020.044

材料研究学报

2020, Vol. 34

Issue (9): 683-690 DOI: 10.11901/1005.3093.2020.044

研究论文

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透明MSe₂@氮掺杂碳膜对电极用于钴电解质双面DSSC

欧金花¹, 胡波年¹, 王薇¹, 韩瑜²^,³(

)

1.湖南工学院材料与化学工程学院衡阳 421002
2.大连理工大学建设工程学部大连 116024
3.辽宁省建设科学研究院有限责任公司沈阳 110005

Transparent MSe₂@N-doped Carbon Film as a Cathode for Co(Ⅲ/Ⅱ)-mediated Bifacial Dye-sensitized Solar Cells

OU Jinhua¹, HU Bonian¹, WANG Wei¹, HAN Yu²^,³(

)

1. Department of Material and Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China
2. Faculty of Infrastructure Engineering, Dalian University of Technology, Dalian 116024, China
3. Liaoning Province Building Science Research Institute Co. Ltd., Shenyang 110005, China

引用本文:

欧金花, 胡波年, 王薇, 韩瑜. 透明MSe₂@氮掺杂碳膜对电极用于钴电解质双面DSSC[J]. 材料研究学报, 2020, 34(9): 683-690.
Jinhua OU, Bonian HU, Wei WANG, Yu HAN. Transparent MSe₂@N-doped Carbon Film as a Cathode for Co(Ⅲ/Ⅱ)-mediated Bifacial Dye-sensitized Solar Cells[J]. Chinese Journal of Materials Research, 2020, 34(9): 683-690.

全文: PDF(8931 KB) HTML

摘要:

用层层自组装法制备一种M-TCPP(M=Ni、Fe)薄膜，然后原位硒化制备出MSe₂和氮掺杂碳的复合透明膜(MSe₂@NCF)，将其用作对电极并结合钴电解质的特点制备了双面DSSC。对MSe₂@NCF的形貌、结构和电化学性能进行表征，并探讨了从正面和背面辐射DSSC时电池的电荷传输路线和光伏性能的区别。结果表明，NiSe₂@NCF具有可与Pt相媲美的催化活性，用其组装的双面DSSC从正面辐射和背面辐射其PCE分别为8.19%和6.02%，与用Pt电极组装DSSC的PCE(8.46%和6.23%)接近。

关键词 ：复合材料, 染料敏化太阳能电池, 层层自组装, 对电极, NiSe₂, FeSe₂

Abstract：

Transparent MSe₂@N-doped carbon film was synthesized using a metal metalloporphyrin (M-TCPP, M=Ni,Fe) thin film as a template in the presence of selenium powder in nitrogen atmosphere, and the MSe₂@N-doped carbon film was used as the counter electrode (CE) in Co-mediated bifacial dye-sensitized solar cells (DSSCs). The morphology, structure and electrochemical performance of MSe₂@NCF were characterized, while the difference of charge transfer process and photovoltaic performance of the cells was discussed when irradiated at the front and rear of the DSSC. The NiSe₂@N-doped carbon film achieves admirable PCEs of 8.19% and 6.02% when irradiated at the front and rear of the device, respectively, which is comparable performance to that of a cell with a Pt CE (PCEs of 8.46% and 6.23%).

Key words： composite dye-sensitized dolar cells layer-by-layer self-assembly method counter electrode NiSe₂ FeSe₂

收稿日期: 2020-02-13

ZTFLH:

TK513.5

基金资助:国家自然科学基金(51974115);湖南省教育厅项目(19B143)

作者简介: 欧金花，女，1987年生，博士

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https://www.cjmr.org/CN/10.11901/1005.3093.2020.044 或 https://www.cjmr.org/CN/Y2020/V34/I9/683

图1 MSe2@NCF的XRD谱

图2 FTO、NiSe2@NCF、FeSe2@NCF的SEM照片和NiSe2@NCF、FeSe2@NCF的TEM照片

图3 NiSe2@NCF 和FeSe2@NCF的 XPS谱

图4 MSe2@NCF的J-V曲线

表1 MSe2@NCF对电极DSSC的光伏参数

图5 用不同对电极组装的对称电池的交流阻抗谱

表2 不同对电极的EIS参数

图6 用不同对电极组装的对称电池的塔菲尔极化曲线

[1]	Ahmad M S, Pandey A K, Rahim N A. Advancements in the development of TiO₂ photoanodes and its fabrication methods for dye sensitized solar cell (DSSC) applications. A review [J]. Renew. Sust. Energ. Rev., 2017, 77: 89
[2]	Sugathan V, John E, Sudhakar K. Recent improvements in dye sensitized solar cells: A review [J]. Renew. Sust. Energ. Rev., 2015, 52: 54
[3]	Chen M, Shao L L. Review on the recent progress of carbon counter electrodes for dye-sensitized solar cells [J]. Chem. Eng. J., 2016, 304: 629
[4]	Meyer E, Bede A, Zingwe N, et al. Metal sulphides and their carbon supported composites as Platinum-free counter electrodes in dye-sensitized solar cells: a review [J]. Materials, 2019, 12: 1980
[5]	Ponken T, Tagsin K, Suwannakhun C, et al. Preparation of platinum (Pt) Counter electrode coated by electrochemical technique at high temperature for dye-sensitized solar cell (DSSC) application [J]. J. Phys., 2017, 901: 012084
[6]	Ou J H, Xiang J, Liu J X, et al. Surface-supported metal-organic framework thin-film-derived transparent CoS_1.097@ N-doped carbon film as an efficient counter electrode for bifacial dye-sensitized solar cells [J]. ACS Appl. Mater. Interfaces, 2019, 11: 14862
[7]	Duan Y Y, Tang Q W, He B L, et al. Transparent nickel selenide alloy counter electrodes for bifacial dye-sensitized solar cells exceeding 10% efficiency [J]. Nanoscale, 2014, 6: 12601 doi: 10.1039/c4nr03900a pmid: 25185939
[8]	Ito S, Zakeeruddin S M, Comte P, et al. Bifacial dye-sensitized solar cells based on an ionic liquid electrolyte [J]. Nat. Photon., 2008, 2: 693
[9]	Bisquert J. Photovoltaics: the two sides of solar energy [J]. Nat. Photon., 2008, 2: 648
[10]	Fu Y P, Lv Z B, Hou S C, et al. TCO‐free, flexible, and bifacial dye‐sensitized solar cell based on low‐cost metal wires [J]. Adv. Energy Mater., 2012, 2: 37
[11]	Duan Y Y, Tang Q W, He B L, et al. Bifacial dye-sensitized solar cells with transparent cobalt selenide alloy counter electrodes [J]. J. Power Sour., 2015, 284: 349
[12]	Ou J H, Liang J, Xiang J, et al. Highly transparent nickel and iron sulfide on nitrogen-doped carbon films as counter electrodes for bifacial quantum dot sensitized solar cells [J]. Sol. Energy, 2019, 193: 766
[13]	Wu J H, Li Y, Tang Q W, et al. Bifacial dye-sensitized solar cells: A strategy to enhance overall efficiency based on transparent polyaniline electrode [J]. Sci. Rep., 2014, 4: 4028 doi: 10.1038/srep04028 pmid: 24504117
[14]	Xu S J, Luo Y F, Liu G W, et al. Bifacial dye-sensitized solar cells using highly transparent PEDOT: PSS films as counter electrodes [J]. Electrochim. Acta, 2015, 156: 20
[15]	Kim C K, Ji J M, Zhou H R, et al. Tellurium-doped, mesoporous carbon nanomaterials as transparent metal-free counter electrodes for high-performance bifacial dye-sensitized solar cells [J]. Nanomaterials, 2020, 10: 29
[16]	Yun S N, Liu Y F, Zhang T H, et al. Recent advances in alternative counter electrode materials for Co-mediated dye-sensitized solar cells [J]. Nanoscale, 2015, 7: 11877 pmid: 26132719
[17]	Kavan L, Yum J H, Graetzel M. Optically transparent cathode for Co(III/II) mediated dye-sensitized solar cells based on graphene oxide [J]. ACS Appl. Mater. Interfaces, 2012, 4: 6999 doi: 10.1021/am302253e pmid: 23182034
[18]	Gao C J, Han Q J, Wu M X. Review on transition metal compounds based counter electrode for dye-sensitized solar cells [J]. J. Energy Chem., 2018, 27: 703
[19]	Ou J H, Gong C H, Wang M, et al. Highly efficient ZIF-8/graphene oxide derived N-doped carbon sheets as counter electrode for dye-sensitized solar cells [J]. Electrochim. Acta, 2018, 286: 212
[20]	Gong F, Wang H, Xu X, et al. In situ growth of Co_0.85Se and Ni_0.85Se on conductive substrates as high-performance counter electrodes for dye-sensitized solar cells [J]. J. Am. Chem. Soc., 2012, 134: 10953 doi: 10.1021/ja303034w pmid: 22713119
[21]	Hezam A, Namratha K, Drmosh Q A, et al. Electronically semitransparent ZnO nanorods with superior electron transport ability for DSSCs and solar photocatalysis [J]. Ceram. Int., 2018, 44: 7202
[22]	Han C L, Wang J, Gong Y T, et al. Nitrogen-doped hollow carbon hemispheres as efficient metal-free electrocatalysts for oxygen reduction reaction in alkaline medium [J]. J. Mater. Chem., 2014, 2A: 605
[23]	Ma X, Zhang L, Xu G C, et al. Facile synthesis of NiS hierarchical hollow cubes via Ni formate frameworks for high performance supercapacitors [J]. Chem. Eng. J., 2017, 320: 22
[24]	Du Y S, Cheng G Z, Luo W. NiSe₂/FeSe₂ nanodendrites: a highly efficient electrocatalyst for oxygen evolution reaction [J]. Catal. Sci. Technol., 2017, 7: 4604
[25]	Xu H J, Wang B K, Shan C F, et al. Ce-doped NiFe-layered double hydroxide ultrathin nanosheets/nanocarbon hierarchical nanocomposite as an efficient oxygen evolution catalyst [J]. ACS Appl. Mater. Interfaces, 2018, 10: 6336 doi: 10.1021/acsami.7b17939 pmid: 29384365
[26]	Chen T, Li S Z, Wen J, et al. Rational construction of hollow core‐branch CoSe₂ nanoarrays for high‐performance asymmetric supercapacitor and efficient oxygen evolution [J]. Small, 2018, 14: 1700979 doi: 10.1002/smll.v14.5
[27]	Liu T T, Asiri A M, Sun X P. Electrodeposited Co-doped NiSe₂ nanoparticles film: a good electrocatalyst for efficient water splitting [J]. Nanoscale, 2016, 8: 3911 doi: 10.1039/c5nr07170d pmid: 26866797
[28]	Li D J, Maiti U N, Lim J, et al. Molybdenum sulfide/N-doped CNT forest hybrid catalysts for high-performance hydrogen evolution reaction [J]. Nano Lett., 2014, 14: 1228 doi: 10.1021/nl404108a pmid: 24502837
[29]	Gong J W, Sumathy K, Qiao Q Q, et al. Review on dye-sensitized solar cells (DSSCs): Advanced techniques and research trends [J]. Renew. Sust. Energ. Rev., 2017, 68: 234
[30]	Gunasekera S S B, Perera I R, Gunathilaka S S. Conducting polymers as cost effective counter electrode material in dye-sensitized solar cells [A]. Solar Energy [C]. Singapore: Springe, 2020: 345
[31]	Silambarasan K, Archana J, Athithya S, et al. Hierarchical NiO@NiS@ graphene nanocomposite as a sustainable counter electrode for Pt free dye-sensitized solar cell [J]. Appl. Surf. Sci., 2020, 501: 144010
[32]	Ou J H, Gong C H, Xiang J, et al. Noble metal-free Co@N-doped carbon nanotubes as efficient counter electrode in dye-sensitized solar cells [J]. Sol. Energy, 2018, 174: 225
[33]	Makhlouf M M, Abdulkarim S, Adam M S S, et al. Unraveling urea pre-treatment correlated to activate Er₂(WO₄)₃ as an efficient and stable counter electrode for dye-sensitized solar cells [J]. Electrochim. Acta, 2020, 333: 135540

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