材料研究学报  2010, Vol. 24 Issue (5): 540-546

研究论文 本期目录 | 过刊浏览 |

细菌纤维素负载稀土掺杂二氧化钛复合膜的制备和光催化性能

张秀菊, 陈文彬, 林志丹, 姚佳

暨南大学理工学院材料系 广州 510632

Preparation and Photocatalysis Performances of Bacterial Cellulose/TiO2 Composite Membranes Doped by Rare Earth Elements

ZHANG Xiuju, CHEN Wenbin, LIN Zhidan, YAO Jia

Preparation and Photocatalysis Performances of Bacterial Cellulose/TiO2 Composite Membranes Doped by Rare Earth Elements

张秀菊 陈文彬 林志丹 姚佳. 细菌纤维素负载稀土掺杂二氧化钛复合膜的制备和光催化性能[J]. 材料研究学报, 2010, 24(5): 540-546.
. Preparation and Photocatalysis Performances of Bacterial Cellulose/TiO2 Composite Membranes Doped by Rare Earth Elements[J]. Chin J Mater Res, 2010, 24(5): 540-546.

摘要 参考文献 相关文章 Metrics 全文: PDF(1344 KB)   摘要: 以细菌纤维素(BC)为载体, 用溶胶－凝胶法原位生成稀土镧和铈元素(La, Ce)掺杂的二氧化钛复合膜, 以甲基橙为目标降解物, 考察了复合膜的光催化活性。结果表明: 稀土元素已引入TiO2/BC复合膜中; 掺杂TiO2的晶型为锐钛矿型; 掺杂稀土的TiO2/BC复合膜的光催化活性比未掺杂的有较大提高;铈掺杂的TiO2/BC复合膜的光催化性能优于镧掺杂的; Ce4+掺杂的最适浓度为2 mmol/L, 而La3+掺杂的最适浓度为5 mmol/L; 稀土掺杂的TiO2/BC复合膜对甲基橙溶液重复降解5次的降解率仍高于70%。 关键词 ： 复合材料 ,   细菌纤维素 ,   稀土 ,  二氧化钛 ,  光催化 ,  甲基橙     Abstract：The composite membrane of TiO2/BC(bacterial cellulose) doped with rare earth elements was prepared by a sol-gel method using tetraisopropyl titanate as starting materials and BC as the support. Photocatalysis performances of the membrane were estimated by using methyl orange as a degradation agent. The results show that rare earth ions are incorporated into TiO2/BC membrane; the resulting titanium dioxide is anatase type. Compared with a pure TiO2/BC membrane, photocatalysis efficiency of the doped one is significantly enhanced. The degradation rate of methyl orange solution for the composite membrane doped with Ce4+ is higher than that of membrane doped with La3+. The optimal dosage of Ce4+ is 2 mmol/L, while the most suitable concentration of La3+ is 5 mmol/L. The degradation rate of methyl orange solution is above 70% after degradation for five times. Key words： composites    bacterial cellulose    rare earth    titanium dioxide    photocatalysis    methylene orange 收稿日期: 2010-07-07      ZTFLH:  O643   基金资助: 广东省科技攻关项目2010B080701060和广东省自然科学基金项目8451063201000041资助。 服务 把本文推荐给朋友 加入引用管理器 E-mail Alert RSS 作者相关文章 张秀菊 44.8K 链接本文: https://www.cjmr.org/CN/      或      https://www.cjmr.org/CN/Y2010/V24/I5/540 1 S.Yamanaka, K.Watanabe, N.Kitamura, M. Iguchi, S. Mitsvhashi, Y. Nishi, M.Uryu, Production of Bacterial Cellulose by Acetobacter xylinum from watermelon peel juice, J Mater. Sci., 24,3141(1989) 2 Y.Z.Wan, L. Hong, S.R.Jia, Y.Huang, Y.Zhu, Y.L.Wang, H.J. Jiang, Synthesis and characterization of hydroxyapatite-bacterial cellulose nanocomposites, Composites Science and Technology, 66(11-12),1825(2006) 3 H. S. Barud, R. M. N. Assun??o, M. A. U. Martines, J. Dexpert-Ghys, R. F. C. Marques, Y. Messaddeq, S. J. L. Ribeiro, Bacterial cellulose-silica organic-inorganic hybrids, Journal of Sol-Gel Science Technology, 46(3),363(2008) 4 C. Zollfrank, H.Scheel, P.Greil, Regioselectively ordered silica nanobubes by molecular templating, Advanced Materials, 19(7), 984(2007) 5 S. H.Yoon, H. J. Jin, M. C. Kook, Y. R. Pyun, Electrically conductive bacterial cellulose by incorporation of carbon nanotubes, Biomacromolecules，7(4)，1280(2006) 6 D.Y. Zhang, L.M. Qi, Synthesis of mesoporous titania networks consisting of anatase nanowires by templating of bacterial cellulose membranes, Chem. Comm., 2735(2005) 7 D. Dana, B. Vlasta, M. Milan, A. M. Mounir, Investigations of metal-doped titanium dioxide photocatalysts, Appl. Catal.B: Environ., 37(2), 91(2002) 8 H. Lachheb, E. Puzenat, A. Houas, M. Ksibi, E. Elaloui, C. Guillard, J. M. Herrmann, Photocatalytic degradation of various types of dyes (Alizarin S, Crocein Orange G, Methyl Red, Congo Red, Methylene Blue in water by UV-irradiated titania, Applied Catalysis B: Environmental, 39(1), 75(2002) 9 S. F. Li, G. L. Ye, G. Q. Chen, Low-Temperature Preparation and Characterization of Nanocrystalline Anatase TiO2, J. Phys. Chem. C, 113(10), 4031(2009) 10 Y. H. Zhang, H. X. Zhang, Y. X. Xu, Y. G. Wang, Significant effect of lanthanide doping on the texture and properties of nanocrystalline mesoporous TiO2, Journal of Solid State Chemistry, 177(10), 3490(2004) 11 K.T.Ranjit, I.Willne, S.H.Bossmann, A.M.Braun, Lanthanide oxide doped Titanium dioxide Photocatalysts: effective Photocatalysts for the enhanced degradation of salieylic acid and t-cinnamic acid, Journal of Catalysis, 204(2), 305(2001) [1] 潘新元, 蒋津, 任云飞, 刘莉, 李景辉, 张明亚. 热挤压钛/钢复合管的微观组织和性能[J]. 材料研究学报, 2023, 37(9): 713-720. [2] 刘瑞峰, 仙运昌, 赵瑞, 周印梅, 王文先. 钛合金/不锈钢复合板的放电等离子烧结技术制备及其性能[J]. 材料研究学报, 2023, 37(8): 581-589. [3] 任富彦, 欧阳二明. g-C3N4 改性Bi2O3 对盐酸四环素的光催化降解[J]. 材料研究学报, 2023, 37(8): 633-640. [4] 季雨辰, 刘树和, 张天宇, 查成. MXene在锂硫电池中应用的研究进展[J]. 材料研究学报, 2023, 37(7): 481-494. [5] 王伟, 解泽磊, 屈怡珅, 常文娟, 彭怡晴, 金杰, 王快社. Graphene/SiO2 纳米复合材料作为水基润滑添加剂的摩擦学性能[J]. 材料研究学报, 2023, 37(7): 543-553. [6] 张藤心, 王函, 郝亚斌, 张建岗, 孙新阳, 曾尤. 基于界面氢键结构的石墨烯/聚合物复合材料的阻尼性能[J]. 材料研究学报, 2023, 37(6): 401-407. [7] 邵萌萌, 陈招科, 熊翔, 曾毅, 王铎, 王徐辉. C/C-ZrC-SiC复合材料的Si2+ 离子辐照行为[J]. 材料研究学报, 2023, 37(6): 472-480. [8] 张锦中, 刘晓云, 杨健茂, 周剑锋, 查刘生. 温度响应性双面纳米纤维的制备和性能[J]. 材料研究学报, 2023, 37(4): 248-256. [9] 王刚, 杜雷雷, 缪自强, 钱凯成, 杜向博文, 邓泽婷, 李仁宏. 聚多巴胺改性碳纤维增强尼龙6复合材料的界面性能[J]. 材料研究学报, 2023, 37(3): 203-210. [10] 林师峰, 徐东安, 庄艳歆, 张海峰, 朱正旺. TiZr基非晶/TC21双层复合材料的制备和力学性能[J]. 材料研究学报, 2023, 37(3): 193-202. [11] 苗琪, 左孝青, 周芸, 王应武, 郭路, 王坦, 黄蓓. 304不锈钢纤维/ZL104铝合金复合泡沫的孔结构、力学、吸声性能及其机理[J]. 材料研究学报, 2023, 37(3): 175-183. [12] 张开银, 王秋玲, 向军. FeCo/SnO2 复合纳米纤维的制备及其吸波性能[J]. 材料研究学报, 2023, 37(2): 102-110. [13] 周聪, 昝宇宁, 王东, 王全兆, 肖伯律, 马宗义. (Al11La3+Al2O3)/Al复合材料的高温性能及其强化机制[J]. 材料研究学报, 2023, 37(2): 81-88. [14] 罗昱, 陈秋云, 薛丽红, 张五星, 严有为. 钠离子电池双层碳包覆Na3V2(PO4)3 正极材料的超声辅助溶液燃烧合成及其电化学性能[J]. 材料研究学报, 2023, 37(2): 129-135. [15] 刘志华, 岳远超, 丘一帆, 卜湘, 阳涛. g-C3N4/Ag/BiOBr复合材料的制备及其光催化还原硝酸盐氮[J]. 材料研究学报, 2023, 37(10): 781-790. Viewed Full text Abstract Cited   Shared      Discussed