Carbon Dioxide Adsorption Capacity of Alkali-metal Cation Dopped MIL125

doi:10.11901/1005.3093.2022.504

Chinese Journal of Materials Research

2023, Vol. 37

Issue (9): 649-654 DOI: 10.11901/1005.3093.2022.504

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Carbon Dioxide Adsorption Capacity of Alkali-metal Cation Dopped MIL125

SONG Lifang, YAN Jiahao, ZHANG Diankang, XUE Cheng, XIA Huiyun, NIU Yanhui(

)

Engineering Research Center of Transportation Materials, Ministry of Education, School of Materials Science and Engineering, Chang'an University, Xi'an 710064, China

Cite this article:

SONG Lifang, YAN Jiahao, ZHANG Diankang, XUE Cheng, XIA Huiyun, NIU Yanhui. Carbon Dioxide Adsorption Capacity of Alkali-metal Cation Dopped MIL125. Chinese Journal of Materials Research, 2023, 37(9): 649-654.

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Abstract

The metal-organic skeleton compound MIL125 was prepared with terephthalic acid and isopropyl titanate as raw materials, afterwards by post impregnating in alkaline metal chloride solution, a series of alkali metal cation-doped M@MIL125-t (M: Li⁺, Na⁺, K⁺; t: 6 h, 9 h, 12 h) were obtained. They were characterized by X-ray diffractometer, Fourier transform infrared spectroscopy and field emission scanning electron microscopy. Their specific surface area and CO₂ adsorption capacity were assessed by nitrogen isothermal adsorption-desorption curve and CO₂ adsorption curve measurements. The results showed that being impregnated with alkali metal chloride solution, the structure and crystal form of MIL125 has not changed significantly. The surface and pores of MIL125 grain was corroded by the impregnation solution, and the specific surface area increased first and then decreased. The optimum impregnation time of MIL125 in the three alkali metal chloride solutions was 9 h. When doped with Na⁺ by impregnating for 9 h, the maximum specific surface area is up to 2497 m²/g, which is 81.5% higher than that of blank MIL125, and the CO₂ adsorption amount is 1.41 mmol/g, which is 72.0% higher than that of blank MIL125.

Key words: inorganic non-metallic materials metal organic frameworks MIL125 alkali metal CO₂ adsorption

Received: 19 September 2022

ZTFLH:

TB333

Fund: National Natural Science Foundation of China(51502021);National Training Programs of Innovation and Entrepreneurship for Undergraduates(X202210710585)

Corresponding Authors: NIU Yanhui, Tel: 18913730031, E-mail: niuyh@chd.edu.cn

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	SONG Lifang
	YAN Jiahao
	ZHANG Diankang
	XUE Cheng
	XIA Huiyun
	NIU Yanhui

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https://www.cjmr.org/EN/10.11901/1005.3093.2022.504 OR https://www.cjmr.org/EN/Y2023/V37/I9/649

Fig.1 FT-IR spectra of MIL125 and M@MIL125-t

Fig.2 XRD patterns of MIL125 and M@MIL125-t

Fig.3 TG curves of MIL125 and M@MIL125-t

Fig.4 SEM images of MIL125, Li@MIL125-9 and K@MIL125-9

Fig.5 SEM images of Na@MIL125-t

Fig.6 SEM-EDS mapping of K@MIL125-9

Fig.7 N₂ adsorption isotherms of MIL125 and M@MIL125-t at 77 K

Fig.8 BET surface area of MIL125 and M@MIL125-t

Fig.9 CO₂ adsorption isotherms of MIL125 and M@MIL125-t (293 K, 101.325 kPa)

Fig.10 Relationship between CO₂ uptake and S_BET in M@MIL125-t(293 K and 101.325 kPa)

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