Effect of Photoanode Film Thickness of SnO2 as Scattering Layer on the Photovoltaic Performance of Quantum Dot Dye-sensitized Solar Cells

doi:10.11901/1005.3093.2022.445

Chinese Journal of Materials Research

2023, Vol. 37

Issue (7): 554-560 DOI: 10.11901/1005.3093.2022.445

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Effect of Photoanode Film Thickness of SnO₂ as Scattering Layer on the Photovoltaic Performance of Quantum Dot Dye-sensitized Solar Cells

LIU Mingzhu, FAN Rao, ZHANG Xiaoyu, MA Zeyuan, LIANG Chengyang, CAO Ying, GENG Shitong, LI Ling(

)

School of Physical Sciences and Technology, Hebei University, Baoding 071002, China

Cite this article:

LIU Mingzhu, FAN Rao, ZHANG Xiaoyu, MA Zeyuan, LIANG Chengyang, CAO Ying, GENG Shitong, LI Ling. Effect of Photoanode Film Thickness of SnO₂ as Scattering Layer on the Photovoltaic Performance of Quantum Dot Dye-sensitized Solar Cells. Chinese Journal of Materials Research, 2023, 37(7): 554-560.

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Abstract

To search superior photoanode materials for further enhancing the cell performance of quantum dot-sensitized solar cells (QDSSCs), the zero-dimensional SnO₂ may be a good option for its excellent cycling stability, high mobility and bandgap tunability. For this purpose, hollow nanospheres of SnO₂, as the candidate material for scattering layer of the photoanode were synthesized by a simple one-step hydrothermal method, and then screen-printed on the TiO₂ substrate to produce a photoanode for quantum dot sensitized solar cells (QDSSCs), which showed excellent electrochemical performance. It is demonstrated that the hollow sphere structure of SnO₂ facilitates the storage of electrolytes and improves its chemical stability while ensuring an efficient electron transfer rate, allowing the cyclic reaction to proceed more efficiently. ZnCuInSe quantum dots were used as sensitizers for the preparation of QDSSCs. Thus it is meaningfull to investigate the effect of photoanodes with different thickness of TiO₂ films printed with quantum dots on the photovoltaic performance of solar cells. Several sets of test results show that when the thickness of the SnO₂ scattering layer is 9 μm, the photoelectric conversion efficiency reaches a maximum value of 7.31%. This opens up the possibility of using SnO₂ in QDSSCs.

Key words: inorganic non-metallic materials quantum dot-sensitized solar cells screen printing techniques SnO₂ scattering layer film thickness of the photoanode electrochemical characteristics

Received: 18 August 2022

ZTFLH:

TQ152

Fund: National Natural Science Foundation of China(51772073);Key Project of the Natural Science Foundation of Hebei Province(E2020201030);Beijing-Tianjin-Hebei Collaborative Innovation Community Construction Project(21344301D);Hebei University 2022 College Student Innovation and Entrepreneurship Program Training Funding Project(2022169);Hebei University 2022 College Student Innovation and Entrepreneurship Program Training Funding Project(2022165);Hebei University 2022 College Student Innovation and Entrepreneurship Program Training Funding Project(2022170)

Corresponding Authors: LI Ling, Tel: 18733255796, E-mail: lilinghbu@163.com

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	LIU Mingzhu
	FAN Rao
	ZHANG Xiaoyu
	MA Zeyuan
	LIANG Chengyang
	CAO Ying
	GENG Shitong
	LI Ling

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https://www.cjmr.org/EN/10.11901/1005.3093.2022.445 OR https://www.cjmr.org/EN/Y2023/V37/I7/554

Fig.1 Flow chart of preparation for SnO₂ nanosphere

Fig.2 SEM images of SnO₂(a), TEM image of SnO₂(b,d) and schematic model of SnO₂ (c)

Fig.3 XRD patterns of SnO₂ material

Fig.4 UV-Vis curves of TiO₂film without scattering layer and TiO₂-SnO₂ scattering layer

Table 1 Photovoltaic performance parameters of light anode scattering layers with different film thicknesses

Fig.5 J-V curves based on photoanodic scattering layers with different film thicknesses (a), IPCE spectra and J_sc curves (b) and Nyquist curves (c)

Table 2 EIS performance parameter table of photoanode scattering layer with different film thicknesses

1	Zaban A, MićićO I, Gregg B A, et al. Photosensitization of nanoporous TiO₂ electrodes with InP quantum dots [J]. Langmuir, 1998, 14: 3153 doi: 10.1021/la9713863
2	Zhou B, Li Y Y, Zou Y Q, et al. Platinum modulates redox properties and 5-hydroxymethylfurfural adsorption kinetics of Ni(OH)₂ for biomass upgrading [J]. Angew. Chem. Int. Ed., 2021, 60: 22908 doi: 10.1002/anie.v60.42
3	Ramya M, Nideep T K, Nampoori V P N, et al. The impact of ZnO nanoparticle size on the performance of photoanodes in DSSC and QDSSC: a comparative study [J]. J. Mater. Sci: Mater. Electron., 2021, 32: 3167 doi: 10.1007/s10854-020-05065-0
4	Peng Y C, Fu G S. Approach to quantum dot solar cells [J]. Chin. J. Mater. Res., 2009, 23: 449
	彭英才, 傅广生. 量子点太阳电池的探索 [J]. 材料研究学报, 2009, 23: 449
5	Xiong T H, Cai W H, Miao Y, et al. Simultaneous epitaxy growth and photoelectrochemical performance of ZnO nanorod arrays and films [J]. Chin. J. Mater. Res., 2022, 36: 481 doi: 10.11901/1005.3093.2021.149
	熊庭辉, 蔡文汉, 苗雨等. ZnO纳米棒阵列和薄膜的同步外延生长及其光电化学性能 [J]. 材料研究学报, 2022, 36: 481 doi: 10.11901/1005.3093.2021.149
6	Song B, Cheng K, Wu C, et al. Synthesis and their optical characterizations of CdS quantum dots [J]. Chin. J. Mater. Res., 2009, 23: 89
	宋冰, 程珂, 武超等. CdS量子点的制备和光学性质 [J]. 材料研究学报, 2009, 23: 89
7	Chen G Z, Chen P, Xu D W, et al. Preparation and microwave absorbtion performance of composite hollow carbon/Fe₃O₄ magnetic quantum dots [J]. Chin. J. Mater. Res., 2022, 36: 29
	陈冠震, 陈平, 徐东卫等. 中空碳/Fe₃O₄磁性量子点复合材料的制备及其吸波性能 [J]. 材料研究学报, 2022, 36: 29 doi: 10.11901/1005.3093.2021.334
8	Archana T, Sreelekshmi S, Subashini G, et al. The effect of graphene quantum dots/ZnS co-passivation on enhancing the photovoltaic performance of CdS quantum dot sensitized solar cells [J]. Int. J. Energy Res., 2021, 45: 15879 doi: 10.1002/er.v45.11
9	Du Z L, Pan Z X, Fabregat-Santiago F, et al. Carbon counter-electrode-based quantum-dot-sensitized solar cells with certified efficiency exceeding 11% [J]. J. Phys. Chem. Lett., 2016, 7: 3103 doi: 10.1021/acs.jpclett.6b01356 pmid: 27455143
10	Elibol E. Design of CdSe _x S_1- _x /ZnS quantum dot sensitized solar cell [J]. AIP Conf. Proc., 2022, 2440: 030007
11	Zhang J J, Wang L X, Jiang C H, et al. CsPbBr₃ nanocrystal induced bilateral interface modification for efficient planar perovskite solar cells [J]. Adv. Sci., 2021, 8: 2102648 doi: 10.1002/advs.v8.21
12	Ou J H, Hu B N, Wang W, et al. Transparent MSe₂@N-doped carbon film as a cathode for Co(Ⅲ/Ⅱ)-mediated bifacial dye-sensitized solar cells [J]. Chin. J. Mater. Res., 2020, 34: 683
	欧金花, 胡波年, 王薇等. 透明MSe2@氮掺杂碳膜对电极用于钴电解质双面DSSC [J]. 材料研究学报, 2020, 34: 683 doi: 10.11901/1005.3093.2020.044
13	Chang J F, Xiao Y, Luo Z Y, et al. Recent progress of non-noble metal catalysts in water electrolysis for hydrogen production [J]. Acta Phys.-Chim. Sin., 2016, 32: 1556 doi: 10.3866/PKU.WHXB201604291
	常进法, 肖瑶, 罗兆艳等. 水电解制氢非贵金属催化剂的研究进展 [J]. 物理化学学报, 2016, 32: 1556
14	Wang W, Feng W L, Du J, et al. Cosensitized quantum dot solar cells with conversion efficiency over 12% [J]. Adv. Mater., 2018, 30: 1705746 doi: 10.1002/adma.201705746
15	Carey G H, Abdelhady A L, Ning Z J, et al. Colloidal quantum dot solar cells [J]. Chem. Rev., 2015, 115: 12732 doi: 10.1021/acs.chemrev.5b00063 pmid: 26106908
16	Tian J J, Cao G Z. Design, fabrication and modification of metal oxide semiconductor for improving conversion efficiency of excitonic solar cells [J]. Coord. Chem. Rev., 2016, 320-321: 193 doi: 10.1016/j.ccr.2016.02.016
17	Wu C P, Xie K X, He J P, et al. SnO₂ quantum dots modified N-doped carbon as high-performance anode for lithium ion batteries by enhanced pseudocapacitance [J]. Rare Met., 2021, 40: 48 doi: 10.1007/s12598-020-01623-x
18	Wei Z P, Liu M N, Li H G, et al. SnO₂ quantum dots decorated reduced graphene oxide nanosheets composites for electrochemical supercapacitor applications [J]. Int. J. Electrochem. Sci., 2020, 15: 6257 doi: 10.20964/2020.07.18
19	Xu Z M, Guan P Y, Younis A, et al. Manipulating resistive states in oxide based resistive memories through defective layers design [J]. RSC Adv., 2017, 7: 56390 doi: 10.1039/C7RA11681K
20	Yan X B, Pei Y F, Chen H W, et al. Self-assembled networked PbS distribution quantum dots for resistive switching and artificial synapse performance boost of memristors [J]. Adv. Mater., 2019, 31: 1805284 doi: 10.1002/adma.201805284
21	Ren Z W, Wang J, Pan Z X, et al. Amorphous TiO₂ buffer layer boosts efficiency of quantum dot sensitized solar cells to over 9% [J]. Chem. Mater., 2015, 27: 8398 doi: 10.1021/acs.chemmater.5b03864
22	Hossain A, Koh Z Y, Wang Q. PbS/CdS-sensitized mesoscopic SnO₂ solar cells for enhanced infrared light harnessing [J]. Phys. Chem. Chem. Phys., 2012, 14: 7367 doi: 10.1039/c2cp40551b pmid: 22531753
23	Lin Y B, Lin Y, Meng Y M, et al. CdS/CdSe co-sensitized SnO₂ photoelectrodes for quantum dots sensitized solar cells [J]. Opt. Commun., 2015, 346: 64 doi: 10.1016/j.optcom.2015.02.031
24	Liu D, Li Y, Zhang X L, et al. Heterostructured perylene diimide (PDI) supramolecular nanorods with SnO₂ quantum dots for enhanced visible-light photocatalytic activity and stability [J]. Chem. Cat. Chem., 2022, 14: e202200087
25	Gao S, Yi X H, Shang J, et al. Organic and hybrid resistive switching materials and devices [J]. Chem. Soc. Rev., 2019, 48: 1531 doi: 10.1039/c8cs00614h pmid: 30398508
26	Kim E K, Bui H T, Shrestha N K, et al. An enhanced electrochemical energy conversion behavior of thermally treated thin film of 1-dimensional CoTe synthesized from aqueous solution at room temperature [J]. Electrochim. Acta, 2018, 260: 365 doi: 10.1016/j.electacta.2017.12.072
27	Pan Z X, Zhao K, Wang J, et al. Near infrared absorption of CdSe _x Te_1- _x alloyed quantum dot sensitized solar cells with more than 6% efficiency and high stability [J]. ACS Nano, 2013, 7: 5215 doi: 10.1021/nn400947e
28	Hossain A, Yang G W, Parameswaran M, et al. Mesoporous SnO₂ spheres synthesized by electrochemical anodization and their application in CdSe-sensitized solar cells [J]. J. Phys. Chem. C, 2010, 114: 21878 doi: 10.1021/jp109083k
29	Hossain A, Jennings J R, Koh Z Y, et al. Carrier generation and collection in CdS/CdSe-sensitized SnO₂ solar cells Exhibiting unprecedented photocurrent densities [J]. ACS Nano, 2011, 5: 3172 doi: 10.1021/nn200315b pmid: 21384799
30	Latif H, Ashraf S, Rafique M S, et al. A novel, PbS quantum dot-Sensitized solar cell structure with TiO₂-fMWCNTS nano-composite filled meso-porous anatase TiO₂ photoanode [J]. Sol. Energy, 2020, 204: 617 doi: 10.1016/j.solener.2020.03.114
31	Wang H, Li B, Gao J, et al. SnO₂ hollow nanospheres enclosed by single crystalline nanoparticles for highly efficient dye-sensitized solar cells [J]. Cryst. Eng. Comm., 2012, 14: 5177 doi: 10.1039/c2ce06531b
32	Du J, Du Z L, Hu J S, et al. Zn-Cu-In-Se quantum dot solar cells with a certified power conversion efficiency of 11.6% [J]. J. Am. Chem. Soc., 2016, 138: 4201 doi: 10.1021/jacs.6b00615 pmid: 26962680
33	Wang W R, Jiang G C, Yu J, et al. High efficiency quantum dot sensitized solar cells based on direct adsorption of quantum dots on photoanodes [J]. ACS Appl. Mater. Interfaces, 2017, 9: 22549 doi: 10.1021/acsami.7b05598
34	Peng W X, Du J, Pan Z X, et al. Alloying strategy in Cu-In-Ga-Se quantum dots for high efficiency quantum dot sensitized solar cells [J]. ACS Appl. Mater. Interfaces, 2017, 9: 5328 doi: 10.1021/acsami.6b14649
35	Liu Z Q, Cheng D F, Zhu Y L, et al. Robust bifunctional phosphorus-doped perovskite oxygen electrode for reversible proton ceramic electrochemical cells [J]. Chem. Eng. J., 2022, 450: 137787 doi: 10.1016/j.cej.2022.137787
36	Tachibana Y, Hara K, Sayama K, et al. Quantitative analysis of light-harvesting efficiency and electron-transfer yield in ruthenium-dye-sensitized nanocrystalline TiO₂ solar cells [J]. Chem. Mater., 2002, 14: 2527 doi: 10.1021/cm011563s
37	Sacco A. Electrochemical impedance spectroscopy: fundamentals and application in dye-sensitized solar cells [J]. Renewable Sustainable Energy Rev., 2017, 79: 814 doi: 10.1016/j.rser.2017.05.159

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