Electrosorption Characteristics of NF/PDMA /MnO2-Co Capacitor Electrode for Pb2+ in a Dilute Solution of Lead Ions

doi:10.11901/1005.3093.2020.193

Chinese Journal of Materials Research

2021, Vol. 35

Issue (2): 115-127 DOI: 10.11901/1005.3093.2020.193

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Electrosorption Characteristics of NF/PDMA /MnO₂-Co Capacitor Electrode for Pb²⁺in a Dilute Solution of Lead Ions

TANG Changbin¹(

), NIU Hao², HUANG Ping¹, WANG Fei², ZHANG Yujie¹, XUE Juanqin¹

^1.School of Chemistry and Chemical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
^2.School of Metallurgical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China

Cite this article:

TANG Changbin, NIU Hao, HUANG Ping, WANG Fei, ZHANG Yujie, XUE Juanqin. Electrosorption Characteristics of NF/PDMA /MnO₂-Co Capacitor Electrode for Pb²⁺in a Dilute Solution of Lead Ions. Chinese Journal of Materials Research, 2021, 35(2): 115-127.

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Abstract

NF/PDMA/MnO₂-Co electrode was prepared by anodic electrodeposition on the foam nickel substrate, and which then was characterized by FESEM-EDS, XPS and Raman spectroscopy. The capacitance characteristics and Pb²⁺ adsorption behavior of the composite electrode were evaluated by cyclic voltammetry and capacitance adsorption desorption tests. The results show that the NF/PDMA/MnO₂-Co composite electrode prepared by applied current density of 1 mA/cm² at 30 ℃ for 3min has a higher adsorption capacity (59.9 mg/g) and specific capacitance (208.8 F/g) for the simulated wastewater of 20 mg/L Pb²⁺. The synergistic effect of the bottom layer of PDMA and the top layer of Co doped MnO₂ can effectively improve the capacitance and adsorption performance of the MnO₂ electrode. The adsorption kinetics fitting shows that the adsorption process is controlled by the mixture of physical and chemical adsorption, and is limited by the mass transfer of ions and the diffusion in pores. The stability of the electrode is higher, and its adsorption capacity is 51.7 mg/g after four cycles of adsorption.

Key words: surface and interface in the materials MnO₂ electrode electrodeposition Pb²⁺ capacitive deionization

Received: 28 May 2020

ZTFLH:

TQ174

Fund: National Natural Science Foundation(51874227);Natural Science Foundation of Shaanxi Province(2018JM5131)

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	Changbin TANG
	Hao NIU
	Ping HUANG
	Fei WANG
	Yujie ZHANG
	Juanqin XUE

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.193 OR https://www.cjmr.org/EN/Y2021/V35/I2/115

Fig.1 Sketch of adsorption experiment equipment

Fig.2 Surface morphologies of PDMA electrode (a) and MnO₂-Co-3 min electrode (b)

Fig.3 Surface morphology (a) collector; (b~e) electrodes and EDS analysis of the NF/PDMA/MnO₂-Co electrode

Fig.4 XPS spectrum of PDMA coating

Fig.5 XPS spectrum of NF/PDMA/MnO₂-Co

Fig.6 Raman spectra of PDMA sublayer and NF/PDMA/MnO₂-Co electrode surface

Fig.7 CV results of PDMA sublayers (a) and MnO₂-Co surface coatings (b) with different deposition time

Fig.8 CV curves of electrodes

Fig.9 Electroadsorption behavior of Pb^{2 +} on three kinds of electrodes

Fig.10 Pb²⁺ adsorption kinetics fitting (a) quasi-first-order model; (b) quasi-second-order model; (c) simplified Elovich model; (d) Weber-Morris model; (e) Boyd model

Table 1 Pb²⁺ adsorption parameters in according to pseudo first-order and pseudo second-order kinetics fitting for Pb²⁺ adsorption

Table 2 Elovich kinetic parameters of Pb²⁺ adsorption via three electrodes

Table 3 Weber-Morris parameters of three electrode for Pb²⁺ adsorption

Fig.11 cycle stability of three electrodes

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