Effect of Rhenium Addition on Isothermal Oxidation Behavior of a Nickel-base Single Crystal Superalloy

doi:10.11901/1005.3093.2016.575

Chinese Journal of Materials Research

2017, Vol. 31

Issue (9): 695-702 DOI: 10.11901/1005.3093.2016.575

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Effect of Rhenium Addition on Isothermal Oxidation Behavior of a Nickel-base Single Crystal Superalloy

Jianxiu CHANG¹, Dong WANG²(

), Jiasheng DONG², Di WANG², Hanchang WU³, Gong ZHANG², Langhong LOU²

1 College of Materials Science and Engineering, Xi?an Shiyou University, Xi?an 710065, China
2 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3 Guiyang AECC Power Investment Casting Ltd. Co., Guiyang 550014, China

Cite this article:

Jianxiu CHANG, Dong WANG, Jiasheng DONG, Di WANG, Hanchang WU, Gong ZHANG, Langhong LOU. Effect of Rhenium Addition on Isothermal Oxidation Behavior of a Nickel-base Single Crystal Superalloy. Chinese Journal of Materials Research, 2017, 31(9): 695-702.

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Abstract

Effect of rhenium (Re) addition on isothermal oxidation behavior of a nickel-base single crystal superalloy was investigated by means of intermittent measurement of weight change as well as scanning electron microscope (SEM) and X-ray diffractometer (XRD). It was shown that, a scale composed of a (Cr, Ti)-enriched outer oxide layer, an inner Al₂O₃ layer and an inner TiN layer was formed for both the Re-containing and Re-free alloys, however, the Al₂O₃ layer was much more complete and the amount of TiN was much less on the Re-containing alloy rather than those on the Re-free alloy. Re was found to lower the oxidation rate of the alloy and improve the stability of the entire oxide scale during long-term oxidation by increasing the activity of Cr and thus increasing the content of Cr₂O₃ in the scale. Enhancement of Cr₂O₃formation may then accelerate the selective oxidation of Al and thus promote the formation of a continuous Al₂O₃ layer beneath the outer oxide scale, as a result, which inhibited the formation of the inner nitride.

Key words: metallic materials nickel-base single crystal superalloy high temperature oxidation rhenium (Re) activity selective oxidation

Received: 30 September 2016

ZTFLH:

TG172.3

Fund: Supported by National Natural Science Foundation of China (No.51631008) and National Key Research and Development Program of China (No.2016YFB0701403)

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	Jianxiu CHANG
	Dong WANG
	Jiasheng DONG
	Di WANG
	Hanchang WU
	Gong ZHANG
	Langhong LOU

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https://www.cjmr.org/EN/10.11901/1005.3093.2016.575 OR https://www.cjmr.org/EN/Y2017/V31/I9/695

Table 1 Nominal and measured compositions of the experimental alloys (%, mass fraction)

Fig.1 SEM micrographs of the single crystal superalloys E1 and E7 after standard heat treatment (a, c) E1, (b, d) E7

Fig.2 Oxidation kinetic curves of the E1 and E7 alloys oxidized at 1000℃

Fig.3 Macroscopic morphologies of the E1 and E7 alloys after isothermal oxidation at 1000℃ (a) E1-4 h, (b) E7-4 h, (c) E1-500 h, (d) E7-500 h

Table 2 XRD results of the E1 and E7 alloys after isothermal oxidation at 1000℃

Fig.4 Morphologies and EDS analyses of the oxide scales formed on E1 and E7 alloys after isothermal oxidation at 1000℃ (a) E1-100 h, (b) E7-100 h, (c) E1-500 h, (d) E7-500 h

Table 3 EDS results of the regions “A” and “B” in Fig.4 (%, atomic fraction)

Fig.5 Cross-section morphologies of the oxide scales formed on E1 alloy after isothermal oxidation at 1000℃ (a) flat surface region at 100h, (b) oxides cluster at 100 h, (c) flat surface region at 500 h, (d) oxides cluster at 500 h

Table 4 EDS results of the regions “A”, “B”, “C”, “D” and “E” in Fig.5 (%,atomic fraction)

Fig.6 Cross-section morphologies of the oxide scales formed on E7 alloy after isothermal oxidation at 1000℃ (a) flat surface region at 100 h, (b) oxides cluster at 100 h, (c) flat surface region at 500 h, (d) oxides cluster at 500 h

Table 5 EDS results of the regions “A”, “B”, “C” and “D” in Fig.6 (%,atomic fraction)

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