Property of Composite with Coarse Grain WC Prepared by Plasma In-situ Metallurgy of Ni/W/C Powder

doi:10.11901/1005.3093.2015.497

Chinese Journal of Materials Research

2017, Vol. 31

Issue (2): 117-122 DOI: 10.11901/1005.3093.2015.497

Orginal Article

Current Issue | Archive | Adv Search

Property of Composite with Coarse Grain WC Prepared by Plasma In-situ Metallurgy of Ni/W/C Powder

Jian ZHAO^1,²(

),Ning LIU²,Chenghai TIAN³,Qiang JI³,Huiqi LI¹,Shufeng WANG¹,Jing CHI¹,Jiannan LI¹

1 College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China
2 College of Electrical Engineering and Automation, Shandong University of Science and Technology, Qingdao 266590, China
3 Qingdao Haina Plasma Technology Co., Ltd, Qingdao 266590, China

Cite this article:

Jian ZHAO,Ning LIU,Chenghai TIAN,Qiang JI,Huiqi LI,Shufeng WANG,Jing CHI,Jiannan LI. Property of Composite with Coarse Grain WC Prepared by Plasma In-situ Metallurgy of Ni/W/C Powder. Chinese Journal of Materials Research, 2017, 31(2): 117-122.

Download:

HTML

PDF(3861KB)
Export: BibTeX | EndNote (RIS)

Abstract

Ball-studs with coarse grained WC were prepared on Q345 steel plateby in-situ plasma metallurgy method with powder mixtures of Ni/W/C as raw material on. The microstructure, composition, phase constituent and microhardness of the ball-studs were characterized by means of SEM, EMPA, XRD and microhardness tester. The results show that among others, the powder mixture with 40% Ni could produce the most desirable ball-studs with brighter surface, higher compactness and stronger adhe sive to the substrate; coarse granules of WC with an average size ca 80μm evenly distributed in the inner portion of the ball-stud matrix of (Fe,Ni); meanwhile, the network-pattern eutectic structure of Ni₁₇W₃ and (Fe, Ni) can be detected. The average microhardness of ball-stud is 1183.517HV_0.1, while the microhardness of the coarse grain of WC is 2078HV_0.1.

Key words: metallic materials plasma in-situ metallurgy coarse grain WC microhardness metallographic structure

Received: 28 January 2016

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Jian ZHAO
	Ning LIU
	Chenghai TIAN
	Qiang JI
	Huiqi LI
	Shufeng WANG
	Jing CHI
	Jiannan LI

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2015.497 OR https://www.cjmr.org/EN/Y2017/V31/I2/117

Fig.1 Sample of Ni/W/C powder

Table 1 Content ratio of Ni/W/C powder (%,mass fraction)

Table 2 Test parameters of plasma in-situ metallurgy

Fig.2 Sketch map of plasma in-situ metallurgy

Fig.3 Macroscopic morphologies of Ni/W/C powder samples with different Ni content after plasma in-situ metallurgical treatment (a) Ni50%, (b) Ni40%, (c) Ni30%

Fig.4 Microstructure of sample nearby bonding zone (Ni40%,200 magnification times)

Fig.5 Microstructure of Ni/W/C powder samples with different Ni content after plasma in-situ metallurgical treatment (a) 50%Ni, (b) 40%Ni, (c) 30%Ni

Fig.6 XRD spectrum of Ni/W/C powder samples with different Ni content after plasma in-situ metallurgical treatment

Fig.7 Liquidus projection of the W-Fe-C ternary phase diagram

Table 3 Atomic number percentage according to the EDS analysis results for different phases (%)

Table 4 Mean value of different phases' microhardness

Fig.8 Microhardness value of the samples

[1]	Zhao M H, Liu A G, Guo M H.Research on WC reinforced metal matrix composite[J].Welding, 2006, (11): 27
[1]	(赵敏海, 刘爱国, 郭面焕. WC颗粒增强耐磨材料的研究现状[J]. 焊接, 2006, (11): 27)
[2]	Zhang D, Zhang G D, Li Z Q.The current state and trend of metal matrix composities[J]. Materials China, 2010, 29(4): 2
[2]	(张荻, 张国定, 李志强. 金属基复合材料的现状与发展趋势[J]. 中国材料进展, 2010, 29(4): 2)
[3]	Wang S F.Study of tungsten carbide composite produced by in-situ metallurgy[D]. Qingdao:Shandong University of Science and Technology, 2011
[3]	(王淑峰. 原位冶金碳化钨复合材料研究[D]. 青岛: 山东科技大学, 2011)
[4]	Yu J M, Xiao Y Z, Wang Q J, et al.New development of technology of clad metal[J]. Chinese Journal of Materials Research, 2000, 14(1): 12
[4]	(于九明, 孝云祯, 王群骄等. 金属层状复合技术及其新进展[J]. 材料研究学报, 2000, 14(1): 12)
[5]	Huang H K, Li Z L, Shan Q, et al.Interface remelting of tungsten carbide particles reinforced steel composite[J]. Chinese Journal of Materials Research, 2014, 28(3): 191
[5]	(黄浩科, 李祖来, 山泉等. 碳化钨/钢基复合材料的界面重熔[J]. 材料研究学报, 2014, 28(3): 191)
[6]	Wang L, Hu S B, Shan W T, et al.Microstructure and wear resistance of laser cladding NiCrMn-WC composite coatings[J]. The Chinese Journal of Nonferrous Metals, 2014, 24(1): 149
[6]	(王璐, 胡树兵, 单炜涛等. 激光熔覆NiCrMn-WC 复合涂层的组织与耐磨性[J]. 中国有色金属学报, 2014, 24(1): 149)
[7]	Li Z L, Jiang Y H, Zhou R, et al.Thermo-physical characteristics of WC particle-reinforced steel substrate surface composites[J]. Chinese Journal of Materials Research, 2014, 28(8): 622
[7]	(李祖来, 蒋业华, 周荣等. 碳化钨颗粒增强钢基表层复合材料的热物理特性[J]. 材料研究学报, 2014, 28(8): 622)
[8]	Wang W G, Zhang H J, Wang Q Z, et al.Effects of carbide inhibitor on microstructures and mechanical properties of ultrafine grained carbide cement WC-2.5TiC-10Co[J]. Chinese Journal of Materials Research, 2015, 29(12): 883
[8]	(王文广, 张贺佳, 王全兆等. 碳化物抑制剂对WC-2.5TiC-10Co超细晶硬质合金微观组织及力学性能的影响[J]. 材料研究学报, 2015, 29(12): 883)
[9]	R. Furushima, K. Katou, K. Shimojima, et al.Control of WC grain sizes and mechanical properties in WC-FeAl composite fabricated from vacuum sintering technique[J]. International Journal of Refractory Metals and Hard Materials, 2015, (50): 17
[10]	Bai Y L, Wu C H, Yang X, et al.Coarsen grain WC-Co cemented carbide fabricated by nanometer powder dissolution method[J].Materials Science and Engineering of Powder Metallurgy, 2012, 17(4): 502
[10]	(白英龙, 吴冲浒, 杨霞等. 纳米粉末溶解法制备粗晶WC-Co硬质合金[J]. 粉末冶金材料科学与工程, 2012, 17(4): 502)
[11]	Wang Q.Microstructure performance and abrasive wear behaviour of metal tungsten carbide coatings deposited by HVOF and oxygen-acetylene flame spray and fuse[D]. Changsha: Hunan University, 2011
[11]	(王群. 热喷涂(焊)金属WC涂层组织、性能及抗磨粒磨损行为研究[D]. 长沙: 湖南大学, 2011)
[12]	Lu J B, Wang Z X, Xi Y J.Study on NiCrBSi steel PWC composite coating prepared by plasma cladding on Q235 steel[J]. Transactions of Materials and Heat Treatment, 2009, 30(4): 142
[12]	(卢金斌, 王志新, 席艳君. Q235钢等离子熔覆添加碳化钨铁基合金涂层的研究[J]. 材料热处理学报, 2009, 30(4): 142)
[13]	Li F Q, Chen Y B, Li L Q.Microstructure and wear property of surface modification layer produced by laser melt injection WC on Q235 steel[J]. Transactions of the China Welding Institution, 2010, 31(4): 32
[13]	(李福泉, 陈彦宾, 李俐群. Q235钢表面激光熔注WC涂层的微观组织及耐磨性[J]. 焊接学报, 2010, 31(4): 32)
[14]	Chi J, Li H Q, Wang S F, et al.Coarse-grain bulk WC composites prepared by direct current arc in-situ metallurgy[J]. The Chinese Journal of Nonferrous Metals, 2013, 23(5): 1263
[14]	(迟静, 李惠琪, 王淑峰等. 直流电弧原位冶金制备粗晶碳化钨块体复合材料[J]. 中国有色金属学报, 2013, 23(5): 1263)
[15]	D. V. Suetin, I. R. Shein, A. L.Ivanovskii.Structure electronic and magnetic properties of η carbides (Fe3W3C, Fe6W6C, Co3W3C, Co6W6C) from first principles calculations[J]. Physica B, 2009, 404: 3545

[1]	MAO Jianjun, FU Tong, PAN Hucheng, TENG Changqing, ZHANG Wei, XIE Dongsheng, WU Lu. Kr Ions Irradiation Damage Behavior of AlNbMoZrB Refractory High-entropy Alloy[J]. 材料研究学报, 2023, 37(9): 641-648.
[2]	SONG Lifang, YAN Jiahao, ZHANG Diankang, XUE Cheng, XIA Huiyun, NIU Yanhui. Carbon Dioxide Adsorption Capacity of Alkali-metal Cation Dopped MIL125[J]. 材料研究学报, 2023, 37(9): 649-654.
[3]	ZHAO Zhengxiang, LIAO Luhai, XU Fanghong, ZHANG Wei, LI Jingyuan. Hot Deformation Behavior and Microstructue Evolution of Super Austenitic Stainless Steel 24Cr-22Ni-7Mo-0.4N[J]. 材料研究学报, 2023, 37(9): 655-667.
[4]	SHAO Hongmei, CUI Yong, XU Wendi, ZHANG Wei, SHEN Xiaoyi, ZHAI Yuchun. Template-free Hydrothermal Preparation and Adsorption Capacity of Hollow Spherical AlOOH[J]. 材料研究学报, 2023, 37(9): 675-684.
[5]	XING Dingqin, TU Jian, LUO Sen, ZHOU Zhiming. Effect of Different C Contents on Microstructure and Properties of VCoNi Medium-entropy Alloys[J]. 材料研究学报, 2023, 37(9): 685-696.
[6]	OUYANG Kangxin, ZHOU Da, YANG Yufan, ZHANG Lei. Microstructure and Tensile Properties of Mg-Y-Er-Ni Alloy with Long Period Stacking Ordered Phases[J]. 材料研究学报, 2023, 37(9): 697-705.
[7]	XU Lijun, ZHENG Ce, FENG Xiaohui, HUANG Qiuyan, LI Yingju, YANG Yuansheng. Effects of Directional Recrystallization on Microstructure and Superelastic Property of Hot-rolled Cu71Al18Mn11 Alloy[J]. 材料研究学报, 2023, 37(8): 571-580.
[8]	XIONG Shiqi, LIU Enze, TAN Zheng, NING Likui, TONG Jian, ZHENG Zhi, LI Haiying. Effect of Solution Heat Treatment on Microstructure of DZ125L Superalloy with Low Segregation[J]. 材料研究学报, 2023, 37(8): 603-613.
[9]	LIU Jihao, CHI Hongxiao, WU Huibin, MA Dangshen, ZHOU Jian, XU Huixia. Heat Treatment Related Microstructure Evolution and Low Hardness Issue of Spray Forming M3 High Speed Steel[J]. 材料研究学报, 2023, 37(8): 625-632.
[10]	YOU Baodong, ZHU Mingwei, YANG Pengju, HE Jie. Research Progress in Preparation of Porous Metal Materials by Alloy Phase Separation[J]. 材料研究学报, 2023, 37(8): 561-570.
[11]	REN Fuyan, OUYANG Erming. Photocatalytic Degradation of Tetracycline Hydrochloride by g-C₃N₄ Modified Bi₂O₃[J]. 材料研究学报, 2023, 37(8): 633-640.
[12]	WANG Hao, CUI Junjun, ZHAO Mingjiu. Recrystallization and Grain Growth Behavior for Strip and Foil of Ni-based Superalloy GH3536[J]. 材料研究学报, 2023, 37(7): 535-542.
[13]	LIU Mingzhu, FAN Rao, ZHANG Xiaoyu, MA Zeyuan, LIANG Chengyang, CAO Ying, GENG Shitong, LI Ling. Effect of Photoanode Film Thickness of SnO₂ as Scattering Layer on the Photovoltaic Performance of Quantum Dot Dye-sensitized Solar Cells[J]. 材料研究学报, 2023, 37(7): 554-560.
[14]	QIN Heyong, LI Zhentuan, ZHAO Guangpu, ZHANG Wenyun, ZHANG Xiaomin. Effect of Solution Temperature on Mechanical Properties and γ' Phase of GH4742 Superalloy[J]. 材料研究学报, 2023, 37(7): 502-510.
[15]	GUO Fei, ZHENG Chengwu, WANG Pei, LI Dianzhong. Effect of Rare Earth Elements on Austenite-Ferrite Phase Transformation Kinetics of Low Carbon Steels[J]. 材料研究学报, 2023, 37(7): 495-501.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed