Influence of Anodic Oxidation on Hydroxyapatite-TiO2 Coating Deposited on Ti6Al4V Alloy

doi:10.11901/1005.3093.2014.336

Chinese Journal of Materials Research

2014, Vol. 28

Issue (12): 887-894 DOI: 10.11901/1005.3093.2014.336

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Influence of Anodic Oxidation on Hydroxyapatite-TiO₂ Coating Deposited on Ti6Al4V Alloy

Pu WANG¹,Daihua HE^2,^**(

),Ping LIU²,Xinkuan LIU²,Jun ZHAO³,Bingyu CHEN²

1. School of Mechanical Engineering, University of Shanghai for Science and Technology, Shanghai 200093
2. School of Materials Science and Engineering, University of Shanghai for Science and Technology, Shanghai 200093
3. Key Laboratory of Inorganic Coating Materials, Chinese Academy of Sciences, Shanghai 200050

Cite this article:

Pu WANG,Daihua HE,Ping LIU,Xinkuan LIU,Jun ZHAO,Bingyu CHEN. Influence of Anodic Oxidation on Hydroxyapatite-TiO₂ Coating Deposited on Ti6Al4V Alloy. Chinese Journal of Materials Research, 2014, 28(12): 887-894.

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Abstract

Ti6Al4V substrate was pretreated by anodic oxidation and then hydroxyapatite coatings were deposited on the oxidized titanium surface by hydrothermal-electrochemical method. The effect of oxidation voltage on the phase composition, surface morphology, wettability and roughness of anodic films, as well as on the phase composition, micro-morphology and bioactivity of HA coatings were investigated. The results show that: after anodic oxidation the titanium alloy is covered by TiO₂ porous oxide film consisted of rutile and anatase when the voltage is higher than 110 V. The pore size of the titania layer increases with the increase of the anodic voltage and the alloy after anodic oxidation by 120 V has good wettability and the roughness is about R_a=0.56 μm. The HA coatings formed by hydrothermal-electrochemical deposition exhibits a layered structure with a preferential orientation (002) for several of oxidation voltage. The crystallinity of HA increases with anodic oxidation voltage up to 120 V and then decreases. The hydroxyapatite-TiO₂ coating deposited on the alloy which had been anodic-oxidized by 120 V has better bioactivity.

Key words: inorganic non-metallic materials Ti6Al4V anodic oxidation hydrothermal-electrochemical HA-TiO₂ coating

Received: 11 July 2014

Fund: *Supported by Key Laboratory of Inorganic Coating Materials, Chinese Academy of Sciences No. KLICM-2014-11, and Shanghai Mumicipal Natural Science Foundation No. 15ZR1428300.

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	Pu WANG
	Daihua HE
	Ping LIU
	Xinkuan LIU
	Jun ZHAO
	Bingyu CHEN

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.336 OR https://www.cjmr.org/EN/Y2014/V28/I12/887

Fig 1 XRD patterns of Ti6Al4V substrates subjected to anodic oxidation for 10 min at 90 V (a), 100 V(b), 110 V (c), 120 V (d), 130 V (e) and 140 V (f)

Fig.2 SEM micrographs of Ti6Al4V substrates subjected to anodic oxidation for 10 min at 90 V (a), 100 V (b), 110 V (c), 120 V (d), 130 V (e) and 140 V (f)

Fig.3 Roughness of Ti6Al4V substrates subjected to anodic oxidation for 10 min at different voltages

Fig.4 Wettability of Ti6Al4V substrates subjected to anodic oxidation for 10 min at different voltages

Fig.5 XRD patterns of HA-TiO₂-coated substrates after anodic oxidation treatment at 90 V (a), 100 V (b), 110 V (c), 120 V (d), 130 V (e) and 140 V (f), and hydrothermal-electrochemical depositions

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