Oxidation Behavior of GH3535 Superalloy at 700℃ and 900℃

doi:10.11901/1005.3093.2014.308

Chinese Journal of Materials Research

2014, Vol. 28

Issue (12): 895-900 DOI: 10.11901/1005.3093.2014.308

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Oxidation Behavior of GH3535 Superalloy at 700℃ and 900℃

Tao LIU^1,²,Jiasheng DONG^2,^**(

),Hui LI²,Zhijun LI³,Xingtai ZHOU³,Langhong LOU²

1. Dalian University of Technology, Dalian 116024
2. Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
3. Shanghai Institute of Applied Physics, Chinese Academy of Sciences 201800

Cite this article:

Tao LIU,Jiasheng DONG,Hui LI,Zhijun LI,Xingtai ZHOU,Langhong LOU. Oxidation Behavior of GH3535 Superalloy at 700℃ and 900℃. Chinese Journal of Materials Research, 2014, 28(12): 895-900.

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Abstract

The isothermal and cyclic oxidation behavior of GH3535 superalloy in air at 700^oC and 900^oC were investigated by using TGA method. The results show that GH3535 alloy has a good oxidation resistance to isothermal oxidation at 700℃and 900℃. But the alloy shows a worse resistance to cyclic oxidization, especially when cyclic oxidation at 900^oC the alloy suffered from accelerated oxidation with rather severe spallation of oxide scales. The X-ray and EDS analysis show that the formed oxide scale consists mainly of Cr₂O₃, NiMn₂O₄ and FeCr₂O₄ during isothermal oxidation. However, oxide products such as MoO₂, NiFe₂O₄, NiCr₂O₄, NiMn₂O₄, and NiMoO₄ can be detected after cyclic oxidation. The oxidation resistance of the alloy decrease noticeably because of the cracking and spallation of the protective oxide scale as well as the continuous participant of Mo in the oxidation process.

Key words: metallic materials GH3535 nickel-based superalloy high temperature oxidation oxidation kinetics

Received: 29 June 2014

Fund: *Supported by the Strategic Priority Research Program of the Chinese Academy of Sciences No. XDA020404040.

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	Tao LIU
	Jiasheng DONG
	Hui LI
	Zhijun LI
	Xingtai ZHOU
	Langhong LOU

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https://www.cjmr.org/EN/10.11901/1005.3093.2014.308 OR https://www.cjmr.org/EN/Y2014/V28/I12/895

Table 1 Nominal composition of the experimental alloy (%, mass fraction)

Fig.1 Isothermal and cyclic oxidation kinetics curves of GH3535 at 700℃ and 900℃: (a) oxidation velocity curve and (b) oxidation mass gain curve

Fig.2 X-ray diffraction spectrum obtained from the alloy surface after isothermal and cyclic oxidation of 500 h at 700℃ and 900℃ (a) isothermal oxidization at 700℃, (b) isothermal oxidization at 900℃, (c) cyclic oxidation at 700℃, (d) cyclic oxidation at 900℃, (e) peeling scale of cyclic oxidation at 900℃

Fig.3 Cross-section morphology and element distribution of the specimen after isothermal oxidation at 700℃ for 500 h

Fig.4 Cross-section morphology and element distribution of the specimen after isothermal oxidation at 900℃ for 500 h

Fig.5 Cross-section morphologies and element distribution of the specimen after cyclic oxidation at 700℃ for 500 h

Fig.6 Cross-section morphology and element distribution of the specimen after cyclic oxidation at 900℃ for 500 h

1	M. W. Rosenthal, P. R. Kasten, R. B. Briggs,Molten-salt reactors-history, status, and potential, Nuclear Applications and Technology, 8, 107(1970)
2	U. S. DOE Nuclear Energy Research Advisory Committeethe Generation IV International Forum: Molten Salt Reactor System R&D,GIF-002-00, 33(2002)
3	R. C. Robertson,Description of reactor design, ORNL-TM-0728, 9 (1965)
4	H. E. McCoy, J. R. Weir,Materials development for molten-salt breeder reactors, ORNL-TM-1854, 3(1967)
5	H. E. McCoy, J. R. Weir,Materials development for molten-salt breeder reactors, ORNL-TM-1854, 31(1967)
6	J. W. Koger,Evaluation of hastelloy N alloys after nine years exposure to both a molten fluoride salt and air at temperatures from 700 to 560℃, ORNL-TM-4189, 19(1972)
7	E. L. Youngblood, R. P. Milford, R.G. Nicol, J. B. Ruch,Corrosion of the volatility pilot plant INOR-8 hydrofluorinator and nickel 201 fluorinator during forty fuel-processing runs with zirconium-uranium alloy, ORNL-3623, 20(1965)
8	H. E. McCoy, B. McNabb,Intergranular cracking of INOR-8 in the MSRE, ORNL-4829, 79(1972)
9	T. K. Roche,The influence of composition upon the 1500oF creep-rupture strength and microstructure of molybdenum-chromium-iron-nickel base alloys, ORNL-2524, 1(1958)
10	R. E. Gehlbach, H. E. McCoy,Phase instability in Hastelloy N, International Symposium on Structural Stability in Superalloys, 2, 346(1968)
11	LI Meishuan, High Temperature Corrosion of Metal, 1st Edition, (Beijing, Metallurgy Industry Press, 2001)p.42
11	( 42)
12	GUO Jianting, Materials Science and Engineering for Superalloys, 1st Edition, (Beijing, Science Press, 2008) p. 582
12	(582)

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