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Chin J Mater Res  2012, Vol. 26 Issue (4): 431-436    DOI:
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Preparation and Properties of Ambient Crosslinking Porous Molecularly Imprinted Latex Membranes
ZHANG Weiying1,2,  LIN Meina1,  LI Xiao1,  YING Xiaoguang1,  CHENG Xiansu2
1.College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108
2.College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108
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Abstract  A porous molecular imprinted latex membrane (MILM) with L-Tryptophan as template molecule, adipic acid dihydrazide (ADH) as cross-linker and glucose as porogen was prepared at ambient temperature from polyacrylate core-shell emulsion incorporated with diacetone acrylamide (DAAM) and acrylic acid (AA). The strength of interaction of functional monomers with L-Tryptophan was compared. The effects of functional monomers on the separation properties of MILM were investigated. The results show that the MILM with developed void structures can be obtained by the method proposed in this paper. The strength of interaction between the three functional monomers and L-Tryptophan is in the following order: L-Trp/ADH>L-Trp/DAAM>L-Trp/AA. ADH, AA and DAAM have considerable influence on crosslinking degree and consequently the permeation properties of MILM. Compared with non-imprinted membrane, the acquired MILM exhibits selective recognition behavior towards template with separation factor reaching over 2.0.
Key words:  organic polymer materials      molecularly imprinted membrane      emulsion film forming      ambient crosslinking      selectivity     
Received:  14 January 2012     
ZTFLH: 

TB324

 
Fund: 

Supported by the Fujian Provincial Natural Science Foundation of China No.2010J01037 and the Program for New Century Excellent Talents in Fujian Province University No.HX2006-102.

Cite this article: 

ZHANG Weiying LIN Meina LI Xiao YING Xiaoguang CHENG Xiansu. Preparation and Properties of Ambient Crosslinking Porous Molecularly Imprinted Latex Membranes. Chin J Mater Res, 2012, 26(4): 431-436.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2012/V26/I4/431

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