Please wait a minute...
Chin J Mater Res  2012, Vol. 26 Issue (4): 431-436    DOI:
论文 Current Issue | Archive | Adv Search |
Preparation and Properties of Ambient Crosslinking Porous Molecularly Imprinted Latex Membranes
ZHANG Weiying1,2,  LIN Meina1,  LI Xiao1,  YING Xiaoguang1,  CHENG Xiansu2
1.College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350108
2.College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108
Download:  PDF(859KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  A porous molecular imprinted latex membrane (MILM) with L-Tryptophan as template molecule, adipic acid dihydrazide (ADH) as cross-linker and glucose as porogen was prepared at ambient temperature from polyacrylate core-shell emulsion incorporated with diacetone acrylamide (DAAM) and acrylic acid (AA). The strength of interaction of functional monomers with L-Tryptophan was compared. The effects of functional monomers on the separation properties of MILM were investigated. The results show that the MILM with developed void structures can be obtained by the method proposed in this paper. The strength of interaction between the three functional monomers and L-Tryptophan is in the following order: L-Trp/ADH>L-Trp/DAAM>L-Trp/AA. ADH, AA and DAAM have considerable influence on crosslinking degree and consequently the permeation properties of MILM. Compared with non-imprinted membrane, the acquired MILM exhibits selective recognition behavior towards template with separation factor reaching over 2.0.
Key words:  organic polymer materials      molecularly imprinted membrane      emulsion film forming      ambient crosslinking      selectivity     
Received:  14 January 2012     
ZTFLH: 

TB324

 
Fund: 

Supported by the Fujian Provincial Natural Science Foundation of China No.2010J01037 and the Program for New Century Excellent Talents in Fujian Province University No.HX2006-102.

Cite this article: 

ZHANG Weiying LIN Meina LI Xiao YING Xiaoguang CHENG Xiansu. Preparation and Properties of Ambient Crosslinking Porous Molecularly Imprinted Latex Membranes. Chin J Mater Res, 2012, 26(4): 431-436.

URL: 

https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2012/V26/I4/431

1 S.A.Piletsky, I.Y.Dubey, D.M.Fedoryak, V.P.Kukhar, Substrate–selective polymeric membranes: selective transfer of nucleic acid components, Biopolym. Kletka, 6, 55(1990)

2 M.Yoshikawa, K.Koso, K.Yonetani, S.Kitamura, S.Kimura, Optical resolution of racemic amino acid derivatives with molecularly imprinted membranes bearing oligopeptide tweezers, J. Polym. Sci., Part A: Polym. Chem., 43, 385(2005)

3 M.Petcu, P.N.Schaare, C.J.Cook, Propofol–imprinted membranes with potential applications in biosensors, Anal. Chim. Acta, 504(1), 73(2004)

4 T.A.Sergeyeva, O.O.Brovko, E.V.Piletska, S.A.Piletsky, L.A.Goncharova, L.V. Karabanova, L.M. Sergeyeva, A.V. El’skaya, Porous molecularly imprinted polymer membranes and polymeric particles, Anal. Chim. Acta, 582(2), 311(2007)

5 T.Panasyuk–Delaney, V.M.Mirsky, M.Ulbricht,  O.S.Wolfbeis, Impedometric herbicide chemosensors based on molecularly imprinted polymers, Anal. Chim. Acta, 435(1), 157(2001)

6 T.A.Sergeyeva, S.A.Piletsky, E.V.Piletska, O.O.Brovko, L.V.Karabanova, L.M.Sergeeva, A.V.El’skaya, A.P.F.Turner, In situ formation of porous molecularly imprinted polymer membranes, Macromolecules, 36(19), 7352(2003)

7 R. Malaisamy, M. Ulbricht, Evaluation of molecularly imprinted polymer blend filtration membranes under solid phase extraction conditions, Sep. Purif. Technol., 39, 211(2004)

8 K.Araki, T.Maruyama, N.Kamiya, M.Goto, Metal ion–selective membrane prepared by surface molecular imprinting, J. Chromatogr. B, 818, 141(2005)

9 P.A.Steward, J.Hearn, M.C.Wilkinson, An overview of polymer latex film formation and properties, Adv. Colloid Interface Sci., 86, 195(2000)

10 A.Fogden, Porous polymer films cast from latex–glucose dispersions, Colloids Surf., A, 349, 102(2009)

11 CUI Yuezhi, DUAN Hongdong, ZHANG Qingsi, WANG Shitai, ZHAO Chuanshan, Preparation and application of polyacrylate emulsion incorporated with DAAM, Chinese Journal of Applied Chemistry, 18(2), 131(2001)

(崔月芝, 段洪东, 张庆思, 王世泰, 赵传山, 双丙酮丙烯酰胺参与共聚的聚丙烯酸酯乳液的制备及其应用, 应用化学, 18(2), 131(2001))

12 SHI Jun, YUAN Quan, GAO Congjie, Handbook of Membrane Technology (Beijing, Chemical Industry Press, 2001) p.65

(时 均, 袁 权, 高从堦,  膜技术手册  (北京, 化学工业出版社, 2001) p.65)

13 QU Lingbo, WANG Ling, CHEN Xiaolan, YUAN Jinwei, YANG Ran, LI Ping, Study on the interaction of bovine serum albumin with puerarin and its derivatives, Acta Chimica Sinica, 65(21), 2417(2007)

(屈凌波, 王 玲, 陈晓岚, 袁金伟, 杨 冉, 李 萍, 葛根素及其衍生物与牛血清白蛋白相互作用研究, 化学学报,  65(21), 2417(2007))

14 Y.Wei, R.Y.M.Huang, Pervaporation with latex membranes: A study on membrane and pervaporation effects, Sep. Sci. Technol., 30(5), 697(1995)
[1] HUANG Jian, LIN Chunxiang, CHEN Ruiying, XIONG Wanyong, WEN Xiaole, LUO Xin. Ionic Liquid-assisted Synthesis of Nanocellulose Adsorbent and Its Adsorption Properties[J]. 材料研究学报, 2020, 34(9): 674-682.
[2] XIONG Xiaoqin, ZHANG Hongquan, FANG Chanyu. Synthesis and Self-assembly Behavior of Amylose-chenodeoxycholic Acid Conjugates[J]. 材料研究学报, 2020, 34(8): 569-574.
[3] ZHENG Xie, ZHA Liusheng. Preparation of Ultra-fast Temperature Responsive Nanofibrous Hydrogel and Application in Controllable Drug Release[J]. 材料研究学报, 2020, 34(6): 452-458.
[4] CHEN Bin,PEI Xinpeng,XU Yang,ZHANG Ying. Effect of Reactive Organic Modifiers on Thermal/Mechanical Properties of Epoxy/Clay Nanocomposites[J]. 材料研究学报, 2020, 34(3): 161-168.
[5] GONG Guifen,LI Ze,WANG Lei,CUI Weiwei. Electrospinning TiO2 Modified Biphenyl Polyimide Lithium Ion Battery Separator[J]. 材料研究学报, 2020, 34(3): 169-175.
[6] DING Renhao, CAO Dan, XU Lu, WANG Ziqiang, LI Jianxi, MA Hongjuan. Effect of Electron-beam Radiation on Properties of Oriented Poly (ether-ether-ketone)[J]. 材料研究学报, 2020, 34(11): 822-828.
[7] CHEN Bin, ZHANG Jialu, ZHANG Yan, ZHAO Haichao, ZHU Lijing. Carbon Dots Incorporated Polysulfone Nanocomposite Membranes with High Water Fux and Fouling Resistance[J]. 材料研究学报, 2020, 34(10): 761-769.
[8] ZHANG Mingyan,LIU Ju,YANG Zhenhua,WANG Denghui,WU Zijian. Effect of Copolymer Chain Structure on Properties of Fluorinated Copolyimide Film[J]. 材料研究学报, 2020, 34(1): 43-49.
[9] Xia HE, Fei WANG, Hanwen ZHAO, Yanping WANG, Libang FENG. Preparation and Healing Behavior of Self-healing Epoxy Resins Based on Diels-Alder Reaction[J]. 材料研究学报, 2019, 33(8): 635-640.
[10] Yunhua LU,Guoyong XIAO,Lin LI,Yan DONG,Haijun CHI,Zhizhi HU,Tonghua WANG. Thermal Rearrangement of Acetate-functionalized Polyimides and Adsorption Properties for CO2[J]. 材料研究学报, 2019, 33(3): 209-217.
[11] LIAO Mingyi,XU Xiaochuan. Anionic Synthesis and Dynamic Mechanical Poperties of Styrene/Isoprene Copolymers with Gradient Blocks[J]. 材料研究学报, 2019, 33(11): 831-836.
[12] ZHU Yongfei,LI Peilin,SU Junming,YU Shujuan. Effect of Polyamide 650 on Ring-opening Polymerization of Benzoxazine and Performance of Polybenzoxazine[J]. 材料研究学报, 2019, 33(11): 857-864.
[13] Zhengzhou WANG, Ting YANG, Lifei HU. Preparation and Application for EPS Foam of Melamine-Bis[Tetrakis (Hydroxymethyl) Phosphonium] Sulfate Flame Retardant[J]. 材料研究学报, 2018, 32(8): 584-590.
[14] Hegang REN, Zhenyou LI, Yibin YAN, Sihan WANG, Xiaopeng CUI, Binyuan LIU. Preparation and Properties of Spherical Particles of Polymer Alloy Polypropylene/Polybutene-1[J]. 材料研究学报, 2018, 32(7): 518-524.
[15] Dayong ZHU, Ting GU, Jie YU, Shengjun LU. Dynamic Rheological Characterization of PLA/PBS Blends Compatibilized by Epoxy Furan Resin[J]. 材料研究学报, 2018, 32(7): 547-554.
No Suggested Reading articles found!