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Preparation and Performance of AgNWs -TPU/PVDF Flexible Film Capacitance Sensors |
SUN Liying, QIAN Jianhua(), ZHAO Yongfang |
School of Textile Science and Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China |
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Cite this article:
SUN Liying, QIAN Jianhua, ZHAO Yongfang. Preparation and Performance of AgNWs -TPU/PVDF Flexible Film Capacitance Sensors. Chinese Journal of Materials Research, 2021, 35(6): 441-448.
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Abstract Silver nanowires (AgNWs) with length-to-diameter ratio of about 800 were prepared by alcohol reduction method, next a network-like structure of AgNWs was constructed via dispersion method. Then PVDF film is prepared by solution casting method, and different mass fraction of polyurethane (TPU) is added to improve the flexibility of the film to form a PVDF/TPU composite film. The AgNWs mesh is fixed on both sides of the PVDF/TPU flexible film to form a capacitive electrode plate, and the AgNWs were used to form a variable-pitch flexible film capacitive sensor. The structure of AgNWs was characterized by scanning electron microscope(SEM), ultraviolet-visible spectroscopy, and XRD; the performance of the flexible thin film capacitive sensor was tested by electronic tensile tester, square resistance meter, three-electrode test system, LCR digital bridge, etc. The results show that: the square resistance of the single-sided polar plate of the capacitor formed by network-like AgNWs is 15.635 mΩ/sq; when the mass ratio of TPU to PVDF is 2:8 the elongation at break of the film is 91.2%, the toughness is the best, The specific capacitance was 375 μF/g; as the bending angle of the sensor increased, the output capacitance also continued to increase. The bending angle and the output capacitance value showed a linear relationship within a certain range. When the bending angle reached 180° the maximum capacitance is 436 μF.
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Received: 17 June 2020
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Fund: National Natural Science Foundation Youth Science Foundation of China(21706238) |
About author: QIAN Jianhua, Tel: 13989856975, E-mail: qianjianhua@zstu.edu.cn
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1 |
Zhu J H. Preparation and performance study of PVDF piezoelectric film and sensor [D]. Harbin: Harbin Institute of Technology, 2011
|
|
朱金海. PVDF压电薄膜及其传感器的制备与性能研究 [D]. 哈尔滨: 哈尔滨工业大学, 2011
|
2 |
Banea M D, Da Silva L F M, Campilho R D S G. The effect of adhesive thickness on the mechanical behavior of a structural polyurethane adhesive [J]. J. Adh., 2015, 91: 331
|
3 |
Bae S, Kim S J, Shin D, et al. Towards industrial applications of graphene electrodes [J]. Phys. Scr., 2012, 2012: 014024
|
4 |
Yu X, Di T T, Shen H Y. Synthesis of nano-snagcu solder by microemulsion method [J]. Chin. J. Mater. Res., 2020, 34: 299
|
|
俞鑫, 邸彤彤, 沈杭燕. 微乳法制备参数对纳米锡银铜焊粉熔点的影响 [J]. 材料研究学报, 2020, 34: 299
|
5 |
Lee T W, Lee S E, Jeong Y G. Highly effective electromagnetic interference shielding materials based on silver nanowire/cellulose papers [J]. ACS Appl. Mater. Interfaces, 2016, 8: 13123
|
6 |
Król P. Synthesis methods, chemical structures and phase structures of linear polyurethanes. Properties and applications of linear polyurethanes in polyurethane elastomers, copolymers and ionomers [J]. Prog. Mater. Sci., 2007, 52: 915
|
7 |
Zhao H L. Research on PVDF piezoelectric film sensor and its application in PCBA modal analysis [D]. Zhenjiang: Jiangsu University, 2009
|
|
赵洪利. PVDF 压电薄膜传感器的研究及其在 PCBA 模态分析中的应用 [D]. 镇江: 江苏大学, 2009
|
8 |
Tang N, Peng Y, Jia Z L, et al. Pyp vacuum distilled simulation of the on using polypropylene hydrophobic micro micropys [J]. J. Appl. Polym. Sci., 2015, 132: 41632
|
9 |
Piana F, Pionteck J. Exploitation of the hard/soft segments ratio in thermoplastic polyurethane (TPU) for the tuning of electrical and mechanical properties of expanded graphite (EG) based composites [J]. SN Appl. Sci., 2019, 1: 878
|
10 |
He X J, Yao K. Crystallization mechanism and piezoelectric properties of solution-derived ferroelectric poly(vinylidene fluoride) thin films [J]. Appl. Phys. Lett., 2006, 89: 112909
|
11 |
Meng X W, Mao Y Y, Yang Y W, et al. Synthesis of ultra-long silver nanowires by SNS-directed method and their characterization [J]. Precious Met., 2017, 38: 19
|
12 |
Chen D P, Qiao X L, Qiu X L, et al. Convenient synthesis of silver nanowires with adjustable diameters via a solvothermal method [J]. J. Colloid Interface Sci., 2010, 344: 286
|
13 |
Li H X, Wu T, Xie M H, et al. Enhancing the tactile and near-infrared sensing capabilities of electrospun PVDF nanofibers with the use of gold nanocages [J]. J. Mater. Chem. C. Mater., 2018, 6: 10263
|
14 |
Yang X F, Wang Y S, Qing X L. A flexible capacitive sensor based on the electrospun PVDF nanofiber membrane with carbon nanotubes [J]. Sens. Actuators A, 2019, 299: 111579
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