Preparation and Properties of Aqueous Phenolic Resin Modified by Organosilicone Oil

doi:10.11901/1005.3093.2020.420

Chinese Journal of Materials Research

2021, Vol. 35

Issue (9): 651-656 DOI: 10.11901/1005.3093.2020.420

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Preparation and Properties of Aqueous Phenolic Resin Modified by Organosilicone Oil

YAN Jun¹^,², YANG Jin¹^,²(

), WANG Tao¹^,², XU Guilong¹^,², LI Zhaohui³

^1.School of Light Industry and Engineer, State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
^2.National Engineering Research Center of Papermaking and Pollution Control, South China University of Technology, Guangzhou 510640, China
^3.Guangdong Laboratory of South Ocean Science and Engineering (Zhuhai), Zhuhai 519082, China

Cite this article:

YAN Jun, YANG Jin, WANG Tao, XU Guilong, LI Zhaohui. Preparation and Properties of Aqueous Phenolic Resin Modified by Organosilicone Oil. Chinese Journal of Materials Research, 2021, 35(9): 651-656.

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Abstract

Silicone oil was grafted and modified with allyl polyoxyethylene ether (PEO) and allyl glycidyl ether (AGE) via hydrosilylation reactions to enhance the dispersibility in water of the silicone oil, while proper amount of reactive epoxy groups were introduced in order to prepare aqueous phenolic resin. The structures, as well as the stability and heat resistance of the blends of modified silicone oil and aqueous phenolic resin were characterized by FT-IR, ¹H-NMR, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) respectively. In addition, silicone-modified phenolic resin was applied to oil filter paper, of which the micro-morphology, mechanical properties, oil resistance and high temperature resistance were examined. The results show that after being co-grafted with PEO and AGE (3:1 in molar ratio) the silicone has good dispersibility in water, and then, the bland complex of aqueous phenolic resin with 5% (mass fraction) of the co-grafted silicone can forms a three-dimensional network structure with good stability. After being reinforced through impregnation of the above bland complex, the oil filter paper presents greatly enhanced mechanical properties. What is more, the reinforced oil filter paper shows high retention rate of mechanical properties even after soaking in high temperature oil, namely, retention rate of 55%, 63%, and 87% for stiffness, burst strength and tensile strength respectively.

Key words: organic polymer materials oil filter paper hydrosilylation graft modification phenolic silicone oil blending

Received: 10 October 2020

ZTFLH:

TB332

Fund: the Program of Marine Economy Development Special Fund (Six Marine Industries) under Department of Natural Resources of Guangdong Province(GDNRC 2021-33)

About author: YANG Jin, Tel: 13580467907, E-mial: yangjin@scut.edu.cn

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.420 OR https://www.cjmr.org/EN/Y2021/V35/I9/651

Fig.1 Hydrosilylation of silicone oil

Fig.2 ¹H-NMR spectra of g-PHMS

Table 1 Stability of g-PHMS

Table 2 Stability of PF/g-PHMS

Fig.3 FT-IR spectra of PF、g-PHMS and g-PHMS

Fig.4 DSC spectra of PF、g-PHMS and PF/g-PHMS

Fig.5 TGA diagram of phenolic and reinforced resins

Fig.6 SEM images of oil filter paper (a) origin filter paper, (b) pure phenolic impregnated paper, (c) silicone modified phenolic impregnated paper

Table 3 Mechanical properties of oil filter paper

Table 4 Oil resistance of oil filter paper

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