The Component and Structure of Thermally Poled and Corona Charged PVDF Films

Chin J Mater Res

2011, Vol. 25

Issue (4): 403-407 DOI:

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The Component and Structure of Thermally Poled and Corona Charged PVDF Films

YE Yun¹, GUO Tailiang¹, JIANG Yadong², LI Weizhi²

1.College of Physics and Telecommunication Engineering, Fuzhou University, Fuzhou 350002
2.State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu, 610054

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YE Yun GUO Tailiang JIANG Yadong LI Weizhi. The Component and Structure of Thermally Poled and Corona Charged PVDF Films. Chin J Mater Res, 2011, 25(4): 403-407.

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Abstract The component and structure of thermally poled and corona charged PVDF films were investigated by the aid of high-resolution X-ray photoelectron spectroscopy (XPS). The results of XPS and ferroelectric properties show that the reaction and mechanism of thermally poling and corona charging for PVDF films was distinct. With the effect of high electric field at high temperature in thermally poling, a new carbon couple bond was created through the action of HF which was produced by F− radicals. However, the H+ radicals engendered due to bombardment of particles during corona charging. And the remanent polarization of thermally poled PVDF film is about 3.5 μC/cm2, while that of corona charged PVDF film is about 3.0 μC/cm2.

Key words: inorganic non-metallic materials thermally poling corona charging PVDF films XPS

Received: 03 September 2010

ZTFLH:

TQ342

Fund:

Supported by the National Science Foundation for Distinguished Young Scholars of China No. 60425101, the Foundation of State Key Laboratory of Electronic Thin Films and Integrated Devices No.KFJJ200916 and Science and Technology Department of Fujian Province No.2009J05145.

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https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2011/V25/I4/403

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