Chin J Mater Res  2011, Vol. 25 Issue (3): 327-332    DOI:

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Effect of Long–term Thermal Cycling Absorption Process (TCAP) on Hydrogen Storage Performance of a Palladium/Kieselguhr Composite

CHEN Wei1,2,  LUO Gang1,2,  XIONG Liangyin1,  CHEN Demin1,  LIU Shi1,  YANG Ke1

1.Institute of Metal Research, Chinese Academy of Science, Shenyang 110016 2.Graduate School of Chinese Academy of Sciences, Beijing 100049

CHEN Wei LUO Gang XIONG Liangyin CHEN Demin LIU Shi1 YANG Ke. Effect of Long–term Thermal Cycling Absorption Process (TCAP) on Hydrogen Storage Performance of a Palladium/Kieselguhr Composite. Chin J Mater Res, 2011, 25(3): 327-332.

Abstract References Related Articles Recommended Metrics Download:  PDF(1165KB)  Export:  BibTeX | EndNote (RIS)       Abstract  A palladium–kieselguhr composite (Pd/K) was prepared by the PdCl2 dipping–calcinating–reducing method. Hydrogen storage performances of the Pd/K before and after subjecting to 1000 and 2000 cycles of hydriding–dehydriding test using the TCAP method were investigated, including phase analysis, morphology observation, pressure–composition isotherm (P − C − T curve) and hydrogen absorption kinetics of the Pd/K composite. Comparing to the initial status, it was found that the absorption rate of the thermally cycled Pd/K greatly enhanced, the P − C − T curve almost retained the same, while the hydrogen uptake capacity decreased slightly. Pulverization of the palladium particles was found on the thermally cycled Pd/K, and the pulverization rates of the Pd/K after 1000 and 2000 cycles were 0.21% and 3.98%, respectively. Key words:  metallic materials      palladium      kieselguhr      hydrogen storage performance      thermal cycling absorption process (TCAP)      Received:  14 March 2011      ZTFLH:  TG139   Service E-mail this article Add to citation manager E-mail Alert RSS （） Articles by authors CHEN Wei LUO Gang XIONG Liang-Yin CHEN De-Min LIU Shi YANG Ke URL:  https://www.cjmr.org/EN/     OR     https://www.cjmr.org/EN/Y2011/V25/I3/327 1 C.P.Chang, J.K.Wu, Y.D.Yao, C.W.Wang, E.K.Lin, Hydrogen and deuterium in palladium, International Journal of Hydrogen Energy, 16(7), 491(1991) 2 P.D.Encinias, D.H.W.Carstens, Hydrogen isotopic exchange in palladium hydride, Journal of the Less Common Metals, 172–174, 1331(1991) 3 K.Aoki, Y.Ogata, K.Kusakabe, S.Morooka, Applicability of palladium membrane for the separation of protium and deuterium, International Journal of Hydrogen Energy, 23(5), 325(1998) 4 J.Evans, I.R.Harris, D.K.Ross, A proposed method of hydrogen isotope separation using palladium alloy membranes, Journal of the Less Common Metals, 89(2), 407(1983) 5 A.N.Golubkov, A.I.Vedeneev, B.N.Tenyaev, B.M.Andreev, I.N.Selivanenko, Counterflow hydrogen isotope separation facility–data on tritium activities, Fusion Engineering and Design, 29-50，825（2000） 6 H.Fujiwara, S.Fukada, Y.Yamaguchi, Hydrogenating rates of twin columns packed with Pd and molecular sieve with an alternately counter–current flow for hydrogen isotope separation, International Journal of Hydrogen Energy, 25(2), 127(2000) 7 LEI Qianghua, LUO Deli, XIONG Yifu, Hydrogen adsorption dynamics analysis of palladium supported on kieselguhr(Pd/K), Rare Metal Materials and Engineering, 34(11), 1690(2005) (雷强华, 罗德礼, 熊义富, 涂钯硅藻土(Pd/k)吸氢动力学分析, 稀有金属材料与工程,  34(11), 1690(2005)) 8 CHEN Wei, LI Shenlan, LUO Gang, HAN Xingbo, CHEN Demin, LIU Shi, YANG Ke, Preparation and hydrogen absorption/desorption properties of palladium/kieselguhr composite, Atomic Energy Science and Technology, 44(8), 920(2010) (陈伟, 李慎兰, 罗刚, 韩兴博, 陈德敏, 刘实, 杨柯, 载钯硅藻土的制备及其吸放氢性能研究, 原子能科学与技术,  44(8), 920(2010)) 9 H.H.Cheng, X.X.Deng, S.L.Li, W.Chen, D.M.Chen, K.Yang, Design of PC based high pressure hydrogen absorption/ desorption apparatus, International Journal of Hydrogen Energy, 32(14), 3046(2007) 10 R.L¨asser, K.H.Klatt, Solubility of hydrogen isotopes in palladium, Phys. 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