Fabrication of Composite Material Based on MOFs and its Adsorption Properties for Methylene Blue Dyes

doi:10.11901/1005.3093.2021.002

Chinese Journal of Materials Research

2021, Vol. 35

Issue (11): 866-872 DOI: 10.11901/1005.3093.2021.002

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Fabrication of Composite Material Based on MOFs and its Adsorption Properties for Methylene Blue Dyes

ZHANG Xiangyang¹, ZHANG Qiyang³, ZHENG Tao¹, TANG Tao¹, LIU Hao¹, LIU Guojin¹, ZHU Hailin¹, ZHU Haifeng²(

)

^1.Zhejiang Provincial Key Laboratory of Fiber Materials and Manufacturing Technology, Zhejiang Sci-Tech University, Hangzhou 310018, China
^2.School of Fashion Design & Engineering, Zhejiang Sci-Tech University, Hangzhou 310018, China
^3.Shaoxing Eco-Environmental Education and Aircraft Platoon Center, Shaoxing 312000, China

Cite this article:

ZHANG Xiangyang, ZHANG Qiyang, ZHENG Tao, TANG Tao, LIU Hao, LIU Guojin, ZHU Hailin, ZHU Haifeng. Fabrication of Composite Material Based on MOFs and its Adsorption Properties for Methylene Blue Dyes. Chinese Journal of Materials Research, 2021, 35(11): 866-872.

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Abstract

Zr-based metal-organic frameworks (MOFs) UIO-66-NH₂ was modified with methacrylate anhydride, and then the modified MOFs were deposited onto polypropylene (PP) nonwoven fabric while real-time curing assisted by UV irradiation to prepare composite of MOFS/nonwoven fabric (PSP). The changes of crystal form and morphology of UIO-66-NH₂ before and after modification were analyzed, and the binding fastness of MOFs (UIO-66-NH2-MET) to PP nonwovens was examined, and the effect of adsorption conditions on the adsorption properties of PSP composite was investigated. The results show that UIO-66-NH2-MET could be prepared through modifying the UIO-66-NH2 structure with methacrylate anhydride group. After modification, the crystal structure of MOFs remained unchanged and the original frame structure was retained. UIO-66-NH2-MET has good fastness on PP nonwovens. No mass loss occurred after repeated washing, and the PSP composite retained good adsorption effect. The optimum conditions for PSP composites to adsorb methylene blue (MB) are as follows: The initial concentration of the dye was 50 mg/L, the adsorption time was 300 min, and the pH value was 9.

Key words: organic polymer materials PSP composite adsorption dyes nonwovens

Received: 11 January 2021

ZTFLH:

TS179

Fund: Natural Science Foundation of Zhejiang Province(LQ19E030022)

About author: ZHU Haifeng, Tel: 13958086618, E-mail: zzspeak@163.com

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	Xiangyang ZHANG
	Qiyang ZHANG
	Tao ZHENG
	Tao TANG
	Hao LIU
	Guojin LIU
	Hailin ZHU
	Haifeng ZHU

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https://www.cjmr.org/EN/10.11901/1005.3093.2021.002 OR https://www.cjmr.org/EN/Y2021/V35/I11/866

Fig.1 standard adsorption curve of MB

Fig.2 Infrared spectrum before and after modification (a) and nuclear magnetic spectrum (b) after modification of UiO-66-NH₂

Fig.3 TEM morphology (a, b) TG curve (c) XRD diagram (d) of UiO-66-NH₂ before and after modification

Fig.4 Element distribution curve of PSP cloth

Fig.5 FESEM image of PP nonwovens and PSP composites

Fig.6 Relationship between adsorption capacity and mass fraction of PSP and adsorption time

Fig.7 Relationship between adsorption capacity of PSP composite and adsorption time

Fig.8 Relationship between adsorption capacity of PSP composite and pH values

Fig.9 Relationship between adsorption capacity of PSP composite and temperatures

Fig.10 Linear fitting equation of quasi first order dynamics (a) and quasi second order dynamics (b) of MB for PSP composite

Table 1 quasi first order and quasi second order kinetic constants

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