Preparation of Hollow Magnetic Graphene Oxide and Its Adsorption Performance for Methylene Blue

doi:10.11901/1005.3093.2020.579

Chinese Journal of Materials Research

2021, Vol. 35

Issue (7): 517-525 DOI: 10.11901/1005.3093.2020.579

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Preparation of Hollow Magnetic Graphene Oxide and Its Adsorption Performance for Methylene Blue

QUE Aizhen, ZHU Taoyu, ZHENG Yuying(

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Department of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China

Cite this article:

QUE Aizhen, ZHU Taoyu, ZHENG Yuying. Preparation of Hollow Magnetic Graphene Oxide and Its Adsorption Performance for Methylene Blue. Chinese Journal of Materials Research, 2021, 35(7): 517-525.

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Abstract

The Fe₃O₄ coated polystyrene microsphere (PS), namely Fe₃O₄@PS_{was firstly fabricated by co-precipitation method with FeCl₂·6H₂O and FeCl₃ as raw material, and PS microsphere as tempelate. Then Fe₃O₄@PS was immersed in toluene solution for removing the PS template. Next, the hollow Fe₃O₄ microsphere was coated with graphene oxide sheets under sonication to produce the hollow magnetic graphene oxide (HMGO). Subsequently, the absorption performance of the HMGO for methylene blue (MB) was assessed in an artificial waste MB solution. Results verified that the adsorption process reach to equilibrium at 55℃ after 60 min. The maximum adsorption capacity of MB on HMGO is 349.85 mg·g^-1. The adsorbent shows good stability and reusability, after 8 times recycling the adsorption rate is still higher than 80%. The adsorption process of MB on HMGO can be well fitted by Pseudo-second-order kinetic model and the adsorption rate is sensitive to the initial concentration. The adsorption isotherm conforms to the Langmuir isotherm model, and the adsorption process is a single-layer surface adsorption.}

Key words: composite adsorption hollow graphene oxide magnetic methylene blue

Received: 04 January 2021

ZTFLH:

X703.5

Fund: the Scientific and Technological Innovation Project of Fujian Province(2012H6008);Scientific and Technological Innovation Project of Fuzhou City(2013-G-92)

About author: ZHENG Yuying, Tel: 18959111811, E-mail: yyzheng@fzu.edu.cn

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	Aizhen QUE
	Taoyu ZHU
	Yuying ZHENG

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.579 OR https://www.cjmr.org/EN/Y2021/V35/I7/517

Fig.1 effect ofBefore HMGO adsorbs MB (a), After HMGO adsorbs MB (b) and Magnet separation HMGO (c)

Fig.2 Infrared spectrum of Fe₃O₄, GO and HMGO

Fig.3 X-ray diffraction patterns of GO, Fe₃O₄ and HMGO

Fig.4 Scanning electron micrographs of PS microspheres、Fe₃O₄、Fe₃O₄@PS、HMGO (a~d), and EDS images of HMGO (e~g)

Fig.5 particle size distribution of PS microspheres (a), Fe₃O₄ (b) and HMGO (c)

Fig.6 Effects of Adsorption time on methylene blue removal

Fig.7 Adsorption kinetic curve fitting (a) pseudo-first-order kinetics (b) pseudo-second-order kinetics

Table 1 Parameters of pseudo first-order and second-order kinetics equations of HMGO

Fig.8 Effects of initial concentrations on methylene blue removal

Fig.9 Curve fitting of adsorption isotherm (a) Langmuir adsorption isotherm equation (b) Freundlich adsorption isotherm equation

Table 2 Langmuir and Freundlich models parameters of HMGO

Fig.10 Effects of adsorption temperature on methylene blue removal

Fig.11 Adsorption thermodynamic curve fitting

Table 3 Thermodynamic parameters of HMGO

Fig.12 Effect of cycle time on the adsorption capacity of MB

1	Rafatullah M, Sulaiman O, Hashim R, et al. Adsorption of methylene blue on low-cost adsorbents: A review [J]. J. Hazard. Mater., 2010, 177(1-3): 70
2	Guo J Y,Gan P F,Chen C,et al. Preparation of magnetic chitosan and its application in the treatment of methylene blue wastewater [J]. Chin. Environ. Science., 2019, 39(6): 2422
	郭俊元, 甘鹏飞, 陈诚等. 磁性壳聚糖的制备及处理亚甲基蓝废水 [J]. 中国环境科学, 2019, 39(6): 2422
3	Crini G, Lichtfouse E, Wilson L D, et al. Conventional and non-conventional adsorbents for wastewater treatment [J]. Environ. Chem. Lett., 2019, 17:195
4	Yao Y J, Xu F F, Chen M, et al. Adsorption behavior of methylene blue on carbon nanotubes [J]. Bioresource Technol., 2010,101(9): 3040
5	Zhou L, Gao C, Xu W J. Magnetic dendritic materials for highly efficient adsorption of dyes and drugs [J]. Acs. Appl. Mater. Inter., 2010, 2(5): 1483
6	Altenor S, Carene B, Emmanuel E, et al. Adsorption studies of methylene blue and phenol onto vetiver roots activated carbon prepared by chemical activation [J]. J. Hazard. Mater., 2009, 165(1-3): 1029
7	Mak S Y, Chen D H. Fast adsorption of methylene blue on polyacrylic acid-bound iron oxide magnetic nanoparticles [J]. Dyes. Pigments., 2004, 61(1): 93
8	Gupta V K, Suhas. Application of low-cost adsorbents for dye removal-A review [J]. J. Environ. Manage., 2009, 90(8): 2313
9	Lu N, He G, Liu J X, et al. Combustion synthesis of graphene for water treatment [J]. Ceram. Int., 2018, 44(2): 2463
10	Xiao W Q,Huang H,Chen L, et al. Preparation and heat treatment of nanocomposites of PBT/graphene oxide [J]. Chin. J. Mater. Res., 2019, 33(02): 95
	肖文强, 黄欢, 陈林等. PBT/氧化石墨烯纳米复合材料的制备及热处理 [J]. 材料研究学报, 2019, 33(02): 95
11	Zhao W Y, Wang Z X,Zheng Y Y, et al. Electrochemical performance of NiS₂/3D porous reduce graphene oxide composite as electrode material for supercapacitors [J]. Acta Mater. Compositae Sin. [J]., 2020, 37(2): 422
	赵文誉, 王振祥, 郑玉婴等. NiS/三维多孔石墨烯复合材料作为超级电容器电极材料的电化学性能 [J]. 复合材料学报, 2020, 37(2): 422
12	Li Y H, Du Q J, Liu T H, et al. Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes [J]. Chem. Eng. Res. Des., 2013, 91(2): 361
13	Wu Y, Luo H J, Wang H, et al. Adsorption properties of modified graphene for methylene blue removal from wastewater [J]. Environ. Sci., 2013, 34(11): 4333
	吴艳, 罗汉金, 王侯等. 改性石墨烯对水中亚甲基蓝的吸附性能研究 [J]. 环境科学, 2013, 34(11): 4333
14	Yang S T, Chen S, Chang Y, et al. Removal of methylene blue from aqueous solution by graphene oxide [J]. J. Colloid. Interf. Sci., 2011, 359(1): 24
15	Balkız G, Pingo E, Kahya N, et al. Graphene oxide/alginate quasi-cryogels for removal of methylene blue [J]. Water. Air. Soil. Pollut., 2018, 229: 131
16	Li R R, Huang H, Dong X L,et al. Adsorption performance of methylene blue onto nanoparticles of carbon-encapsulated magnetic nickel [J]. Chin. J. Mater. Res., 2015, 29(09): 663
	李冉冉, 黄昊, 董星龙等. 碳包覆磁性镍纳米粒子对亚甲基蓝的吸附性能 [J]. 材料研究学报, 2015, 29(09): 663
17	Adel M, Ahmed M A, Mohamed A A. Synthesis and characterization of magnetically separable and recyclable crumbled MgFe₂O₄/reduced graphene oxide nanoparticles for removal of methylene blue dye from aqueous solutions [J]. J. Phys. Chem. Solids., 2021, 149: 109760
18	Othman N H, Alias N H, Shahruddin M Z, et al. Adsorption kinetics of methylene blue dyes onto magnetic graphene oxide [J]. J. Environ. Chem. Eng., 2018, 6(2): 2803
19	Gu F B, Liang M, Dong M H, et al. Multifunctional sandwich-like mesoporous silica-Fe₃O₄-graphene oxide nanocomposites for removal of methylene blue from water [J]. Rsc. Adv., 2015, 5(50): 39964
20	Hosseinzadeh H, Hosseinzadeh S, Pashaei S. Fabrication of novel magnetic graphene oxide nanocomposites for selective adsorption of mercury from aqueous solutions [J]. Environ. Sci. Pollut. Res., 2019, 26: 26807
21	Sun Z W, Srinivasakannan C, Liang J S, et al. Preparation of hierarchical magnesium silicate with excellent adsorption capacity [J]. Ceram. Int., 2019, 45(4): 4590
22	Chen P, Cao Z F, Wen X, et al. In situ nano-silicate functionalized graphene oxide composites to improve MB removal [J]. J. Taiwan. Inst. Chem. Eng., 2017, 81: 87
23	Dai H J, Huang Y, Huang H H,et al. Eco-friendly polyvinyl alcohol/carboxymethyl cellulose hydrogels reinforced with graphene oxide and bentonite for enhanced adsorption of methylene blue [J]. Carbohyd. Polym., 2018, 185: 1
24	Pan Y Y. The modification of magnetic chitosan and the research on simulated wastewater [D]. Taiyuan:North University of China, 2013
	潘媛媛.磁性壳聚糖的改性及其对模拟废水的处理研究 [D]. 太原: 中北大学, 2013
25	Xu J, Li S S, Wang F, et al. Efficient and enhanced adsorption of methylene blue on triethanolamine-modified graphene oxide [J]. J. Chem. Eng. Data., 2019, 64(4): 1816
26	Sarkar C, Basu J K, Samanta A N. Removal of Ni²⁺ ion from waste water by geopolymeric adsorbent derived from LD slag [J]. J. Water. Process. Eng., 2017, 17: 237

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