Preparation and Electrochemical Properties of B-doped MnO2

doi:10.11901/1005.3093.2020.149

Chinese Journal of Materials Research

2021, Vol. 35

Issue (1): 36-44 DOI: 10.11901/1005.3093.2020.149

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Preparation and Electrochemical Properties of B-doped MnO₂

XIA Ao(

), ZHAO Chenpeng, ZENG Xiaoxiong, HAN Yuepeng, TAN Guoqiang

Shaanxi Key Laboratory of Green Preparation and Functionalization for Inorganic Materials, Shaanxi University of Science & Technology, Xi'an 710021, China

Cite this article:

XIA Ao, ZHAO Chenpeng, ZENG Xiaoxiong, HAN Yuepeng, TAN Guoqiang. Preparation and Electrochemical Properties of B-doped MnO₂. Chinese Journal of Materials Research, 2021, 35(1): 36-44.

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Abstract

B³⁺ doped birnessite-MnO₂ anode materials were successfully prepared by one-step hydrothermal method, and then characterized by XRD, Raman, SEM, TEM, XPS and electrochemical performance tests. The pure- and doped-MnO₂ particles were globular nano-flowers composed of two-dimensional nano flakes . The thickness of nano flakes decreased after B³⁺ doping, thus the transmission path of Li-ions and electrons in the bulk material was shortened. The charge transfer resistance of birnessite-MnO₂ decreased obviously after a proper amount of B³⁺ ions doping. The B-MnO₂ doped with 9% B³⁺showed the optimal electrochemical performance. In conditions of the current density of 100 mA·g^-1 and 1000 mA·g^-1, the initial charging specific capacities were 855.1 mAh·g^-1 and 599 mAh·g^-1, respectively. After 100 cycles the corresponding reversible capacities still remained 805 mAh·g^-1 and 510.3 mAh·g^-1, and the respective retention rates were 94.1% and 85.2% respectively.

Key words: synthesizing and processing technics for materials lithium-ion battery hydrothermal method MnO₂ electrochemical performance

Received: 03 May 2020

ZTFLH:

TM912.9

Fund: China Postdoctoral Science Foundation(2016M592746);Doctor Initiation Funding Scheme of the Shaanxi University of Science & Technology(BJ15-04)

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	Ao XIA
	Chenpeng ZHAO
	Xiaoxiong ZENG
	Yuepeng HAN
	Guoqiang TAN

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https://www.cjmr.org/EN/10.11901/1005.3093.2020.149 OR https://www.cjmr.org/EN/Y2021/V35/I1/36

Fig.1 XRD patterns of B-doped MnO₂samples

Table 1 Lattice parameters of all samples obtained from XRD patterns

Fig.2 Raman spectra of B-doped MnO₂ samples

Fig.3 SEM images of B0M (a, e), B3M (b, f), B9M (c, g), B15M (d, h) samples

Fig.4 TEM images of B9M

Fig.5 XPS survey spectra of B0M and B9M (a), B1s spectra of B9M (b), Mn2p spectra of B0M (c), Mn2p spectra of B9M (d), O1s spectra of B0M (e) and O1s spectra of B9M (f)

Table 2 Element state analysis calculated through XPS results

Fig.6 Crystal structure diagram of pure MnO₂ (a) and B³⁺ doped MnO₂ (b)

Fig.7 Cycle voltammetry (CV) curves (a) and first charge/discharge curves of samples (b)

Fig.8 Cycling performance of samples at 100 mA·g^-1 (a); Cycling performance of samples at 1000 mA·g^-1 (b); Rate performance of samples (c) and EIS of samples after three cycles at 100 mA·g^-1 (d)

Table 3 EIS model parameters for the synthesized samples

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