Preparation of Foam Structured Catalyst ZnFe2O4-α-Fe2O3/SiC and its Performance in Oxidative Dehydrogenation of Butene

doi:10.11901/1005.3093.2017.320

Chinese Journal of Materials Research

2018, Vol. 32

Issue (3): 225-232 DOI: 10.11901/1005.3093.2017.320

ARTICLES

Current Issue | Archive | Adv Search

Preparation of Foam Structured Catalyst ZnFe₂O₄-α-Fe₂O₃/SiC and its Performance in Oxidative Dehydrogenation of Butene

Renzheng JIANG^1,², Yilai JIAO¹, Bo SUN¹, Xiaodan YANG¹, Zhenming YANG¹, Jinsong ZHANG¹(

)

1 Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;
2 University of Chinese Academy of Sciences, Beijing 100049, China;

Cite this article:

Renzheng JIANG, Yilai JIAO, Bo SUN, Xiaodan YANG, Zhenming YANG, Jinsong ZHANG. Preparation of Foam Structured Catalyst ZnFe₂O₄-α-Fe₂O₃/SiC and its Performance in Oxidative Dehydrogenation of Butene. Chinese Journal of Materials Research, 2018, 32(3): 225-232.

Download:

HTML

PDF(11081KB)
Export: BibTeX | EndNote (RIS)

Abstract

A foam structured catalyst of ZnFe₂O₄-α-Fe₂O₃/SiC was prepared by a slurry-coating method with citric acid-nitrates as binder. Its phase composition, morphology and pore structure were characterized by XRD, SEM and BET. The influence of the concentration of citric acid-nitrates and the deposited amount of slurry on the morphology, pore structure and catalytic performance in the oxidative dehydrogenation of 1-butene of the prepared catalyst were investigated. The result show that the concentration of citric acid-nitrates hardly changed the phase composition; the as-prepared structured catalyst has a compact and neat coating with a wide range distribution of pore size; the concentration of citric acid-nitrates of the slurry or the most probable pore size of the as-prepared catalyst has a little influence on the peformance of the structured catalyst. The BET surface area and the catalytic performance of the structured catalyst gradually increased with the incresing the deposited amount of slurry. In case of gas firing hourly space velocity of bntene of 300 h^-1, the conversion rate of 1-butene and selectivity of butadiene reache ca. 86% and 91%, respectively for the prepared structured catalyst with a deposited amount of 0.2 g/mL slurry, which are much higher than that for particulate catalysts, indicating superior oxidative dehydrogenation performance.

Key words: inorganic non-metallic materials ZnFe₂O₄-α-Fe₂O₃; foam SiC structured catalyst 1-butene oxidative dehydrogenation slurry-coating

Received: 17 May 2017

ZTFLH:

TQ031

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Renzheng JIANG
	Yilai JIAO
	Bo SUN
	Xiaodan YANG
	Zhenming YANG
	Jinsong ZHANG

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2017.320 OR https://www.cjmr.org/EN/Y2018/V32/I3/225

Fig.1 XRD patterns of ZF-0 particles, ZF-0.11 particles, ZFS-0.2 structured catalyst and foam SiC

Fig.2 SEM images of foam SiC and ZFS-0.2 structured catalyst (a) Foam SiC, (b) strut surface with Si, (c) strut surface without Si and (d) cross section of ZFS-0.2 structured catalyst

Fig.3 High (a, b, c, d) and low (a1, b1, c1, d1) magnification images of ZFS-0.2 structured catalysts CNS concentration of a, b, c and d is 0.11, 0.44, 0.88 and 1.32 mol/L, respectively

Table 1 BET surface areas and total pore volumes of ZF-c coating particles

Fig.4 Pore diameter size distribution of ZF-c coating particles

Fig.5 Images of ZFS-w structured catalyst with coating loading amount 0.064, 0.082, 0.128, 0.164, 0.2 and 0.223

Table 2 BET surface areas and total pore volumes of ZFS-w structured catalysts

Fig.6 Pore diameter distribution of ZFS-w structured catalyst

Fig.7 Influence of citric acid-nitrates concentration on theperformanceof ZFS-0.2 structured catalyst reaction condition: 1-butene: oxygen: steam=1:0.85:12, 1-butene GHSV=300 h^-1

Fig.8 Influence of coating loading on the performance of ZFS structured catalyst reaction condition: 1-butene: oxygen: steam=1:0.85:12, 1-butene GHSV=300 h^-1

Fig.9 Performance of ZFS-0.2 structured catalyst, ZF-0.11 particulate catalyst and ZF-0 co-precipitated particulate catalyst reaction condition: 1-butene:oxygen:steam=1:0.85:12, 1-butene GHSV=300 h^-1

[1]	Makshina E V, Dusselier M, Janssens W, et al.Review of old chemistry and new catalytic advances in the on-purpose synthesis of butadiene[J]. Chem. Soc. Rev., 2014, 43(22): 7917
[2]	Kim T W, Kim J W, Kim S Y, et al.Butadiene production from bioethanol and acetaldehyde over tantalum oxide-supported spherical silica catalysts for circulating fluidized bed[J]. Chem. Eng. J., 2015, 278: 217
[3]	Sterrett J S, Mcllvried H G.Kinetics of the oxidative dehydrogenation of butene to butadiene over a ferrite catalyst[J]. Ind. Eng. Chem. Process Des. Dev., 1974, 13(1): 54
[4]	Tronconi E, Groppi G, Visconti C G.Structured catalysts for non-adiabatic applications[J]. Curr. Opin. Chem. Eng., 2014, 5: 55
[5]	Liu Y, Edouard D, Nguyen L D, et al.High performance structured platelet milli-reactor filled with supported cobalt open cell SiC foam catalyst for the Fischer-Tropsch synthesis[J]. Chem. Eng. J., 2013, 222(8): 265
[6]	Keller N, Pham-Huu C, Ledoux M J.Continuous process for selective oxidation of H2S over SiC-supported iron catalysts into elemental sulfur above its dewpoint[J]. Appl. Catal. A Gen., 2001, 217(1-2): 205
[7]	Li C, Xu H, Hou S, et al.SiC foam monolith catalyst for pressurized adiabatic methane reforming[J]. Appl. Energ., 2013, (107): 297
[8]	Liu H, Yang D, Gao R., et al.A novel Na2WO4-Mn/SiC monolithic foam catalyst with improved thermal properties for the oxidative coupling of methane[J]. Catal. Commun., 2008, 9(6): 1302
[9]	Yuan H, Sun Z, Liu H, et al.Immobilizing Carbon Nanotubes on SiC Foam as a Monolith Catalyst for Oxidative Dehydrogenation Reactions[J]. Chemcatchem, 2013, 5(7): 1713
[10]	Wei W, Cao X M, Tian C, et al.The influence of Si distribution and content on the thermoelectric properties of SiC foam ceramics[J]. Micropor. Mesopor.Mater., 2008, 112(1-3): 521
[11]	Jiao Y L, Jiang C H, Yang Z M, et al.Controllable synthesis of ZSM-5 coatings on SiC foam support for MTP application[J]. Micropor. Mesopor. Mater., 2012, 162(6): 152
[12]	Zheng C W.High temperature oxidation behaviour of several silicon carbide ceramics processed by reaction bonding method [D]. Shenyang: Chinese Academy of Sciences, 2010(郑传伟. 几种反应烧结碳化硅陶瓷材料的高温氧化行为研究[D]. 沈阳: 中国科学院金属研究所, 2010)
[13]	Fang J Z, Xu C F.Study of three kinds of XRD quantitative analysis methods[J]. Coal conversion. 2010, 33(2): 88(房俊卓, 徐崇福. 三种X射线物相定量分析方法对比研究[J]. 煤炭转化, 2010, 33(2): 88)
[14]	Park J H, Noh H, Ji W P, et al. Effects of iron content on bismuth molybdate for the oxidative dehydrogenation of n-butenes to 1, 3-butadiene[J]. Appl. Catal. A Gen., 2012, s 431-432(29): 137

[1]	SONG Lifang, YAN Jiahao, ZHANG Diankang, XUE Cheng, XIA Huiyun, NIU Yanhui. Carbon Dioxide Adsorption Capacity of Alkali-metal Cation Dopped MIL125[J]. 材料研究学报, 2023, 37(9): 649-654.
[2]	SHAO Hongmei, CUI Yong, XU Wendi, ZHANG Wei, SHEN Xiaoyi, ZHAI Yuchun. Template-free Hydrothermal Preparation and Adsorption Capacity of Hollow Spherical AlOOH[J]. 材料研究学报, 2023, 37(9): 675-684.
[3]	REN Fuyan, OUYANG Erming. Photocatalytic Degradation of Tetracycline Hydrochloride by g-C₃N₄ Modified Bi₂O₃[J]. 材料研究学报, 2023, 37(8): 633-640.
[4]	LIU Mingzhu, FAN Rao, ZHANG Xiaoyu, MA Zeyuan, LIANG Chengyang, CAO Ying, GENG Shitong, LI Ling. Effect of Photoanode Film Thickness of SnO₂ as Scattering Layer on the Photovoltaic Performance of Quantum Dot Dye-sensitized Solar Cells[J]. 材料研究学报, 2023, 37(7): 554-560.
[5]	LI Yanwei, LUO Kang, YAO Jinhuan. Lithium Ions Storage Properties of Ni(OH)₂ Anode Materials Prepared with Sodium Dodecyl Sulfate as Accessory Ingredient[J]. 材料研究学报, 2023, 37(6): 453-462.
[6]	YU Moxin, ZHANG Shuhai, ZHU Bowen, ZHANG Chen, WANG Xiaoting, BAO Jiamin, WU Xiang. Preparation of Nitrogen-doped Biochar and its Adsorption Capacity for Co²⁺[J]. 材料研究学报, 2023, 37(4): 291-300.
[7]	ZHU Mingxing, DAI Zhonghua. Study on Energy Storage Properties of SrSC_0.5Nb_0.5O₃ Modified BNT-based Lead-free Ceramics[J]. 材料研究学报, 2023, 37(3): 228-234.
[8]	LIU Zhihua, YUE Yuanchao, QIU Yifan, BU Xiang, YANG Tao. Preparation of g-C₃N₄/Ag/BiOBr Composite and Photocatalytic Reduction of Nitrate[J]. 材料研究学报, 2023, 37(10): 781-790.
[9]	ZHOU Yi, TU Qiang, MI Zhonghua. Effect of Preparing Methods on Structure and Properties of Phosphate Glass-ceramics[J]. 材料研究学报, 2023, 37(10): 739-746.
[10]	XIE Feng, GUO Jianfeng, WANG Haitao, CHANG Na. Construction of ZnO/CdS/Ag Composite Photocatalyst and Its Catalytic and Antibacterial Performance[J]. 材料研究学报, 2023, 37(1): 10-20.
[11]	FANG Xiangming, REN Shuai, RONG Ping, LIU Shuo, GAO Shiyong. Fabrication and Infrared Detection Performance of Ag-modified SnSe Nanotubes[J]. 材料研究学报, 2022, 36(8): 591-596.
[12]	LI Fulu, HAN Chunmiao, GAO Jiawang, JIANG Jian, XU Hui, LI Bing. Temperature Dependent Luminescence Properties of Graphene Oxide[J]. 材料研究学报, 2022, 36(8): 597-601.
[13]	ZHU Xiaodong, XIA Yangwen, YU Qiang, Yang Daixiong, HE Lili, FENG Wei. Preparation and Characterization of Cu Doped Rutile TiO₂ and Photocatalytic Property[J]. 材料研究学报, 2022, 36(8): 635-640.
[14]	XIONG Tinghui, CAI Wenhan, MIAO Yu, CHEN Chenlong. Simultaneous Epitaxy Growth and Photoelectrochemical Performance of ZnO Nanorod Arrays and Films[J]. 材料研究学报, 2022, 36(7): 481-488.
[15]	MENG Xiangdong, ZHEN Chao, LIU Gang, CHENG Huiming. Controlled Synthesis of CuO Nanoarrays as Efficient Photocathodes for Photoelectrochemical (PEC) for Water Splitting[J]. 材料研究学报, 2022, 36(4): 241-249.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed