Preparation and Property of a Hierarchical Porous Carbon Material

doi:10.11901/1005.3093.2017.106

Chinese Journal of Materials Research

2017, Vol. 31

Issue (12): 881-886 DOI: 10.11901/1005.3093.2017.106

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Preparation and Property of a Hierarchical Porous Carbon Material

Yuan JIAO^1,², Lili SUN^1,², Peng GUO¹, Aiying WANG¹(

)

1 Key Laboratory of Marine Materials and Related Technologies, Zhejiang Key Laboratory of Marine Materials and Protective Technologies, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
2 University of Chinese Academy of Sciences, Beijing 100049, China

Cite this article:

Yuan JIAO, Lili SUN, Peng GUO, Aiying WANG. Preparation and Property of a Hierarchical Porous Carbon Material. Chinese Journal of Materials Research, 2017, 31(12): 881-886.

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Abstract

Porous carbon materials were fabricated by a dual-templating method, using non-woven polyethylene terephthalate (PET) fabrics as the hard template and Pluronic F127 as the soft template, with soluble phenolic resol as the carbon precursor. There exists meso pores of 4~6 nm resulted from decomposition of F127 and macro pores of 10~15 μm resulted from decomposition of PET fabric in the prepared hierarchical porous materials. The conductivity can be reduced from 1.63×10⁴ Ωm to 3.13×10^-3 Ωm by properly adjusting the carbonization process parameter. This porous carbon sheet can be directly used as an electrode for Li-ion battery without any conductive additive or binder, and has very stable capacity.

Key words: inorganic non-metallic materials dual-templating porous carbon material Li-ion battery

Received: 24 January 2017

ZTFLH:

TB321

Fund: Supported by National Natural Science Foundation of China (No. 51522106), Key Research and Development Program of Zhejiang Province (No. 2017C01001)

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https://www.cjmr.org/EN/10.11901/1005.3093.2017.106 OR https://www.cjmr.org/EN/Y2017/V31/I12/881

Table 1 Parameters of different porous carbon materials

Fig.1 SEM and optical (insert) images of pristine PET sheet (a), SEM and TEM images of porous carbon materials numbered (b)(d) #1, (c) (e) #2, and (f) #3; (g) and (h) show local profiles of (d, e)

Fig.2 Resistivity of porous carbon materials made from different carbonization processes

Fig.3 Raman spectra (a),G peak position and I_D/I_G changes (b) of porous carbon materials prepared by using different carbonization process

Fig.4 C-V curves for the first 5 cycles at 0.1C (a) and C-C curve for 300 cycles (b)

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