Influence of Synergistic Effect of Carbon Nanotubes/Carbon Black on Properties of Natural Rubber/Butadiene Rubber Composites

doi:10.11901/1005.3093.2016.444

Chinese Journal of Materials Research

2017, Vol. 31

Issue (10): 758-764 DOI: 10.11901/1005.3093.2016.444

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Influence of Synergistic Effect of Carbon Nanotubes/Carbon Black on Properties of Natural Rubber/Butadiene Rubber Composites

Jiangshan GAO, Yan HE(

), Jin XU, Chang GUO

Qingdao University of Science and Technology, Qingdao 266061, China

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Jiangshan GAO, Yan HE, Jin XU, Chang GUO. Influence of Synergistic Effect of Carbon Nanotubes/Carbon Black on Properties of Natural Rubber/Butadiene Rubber Composites. Chinese Journal of Materials Research, 2017, 31(10): 758-764.

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Abstract

Carbon nanotubes (CNTs) and carbon black (CB) were used as the hybrid reinforcing fillers, the coordinated effect of different fillers on the properties of composites was investigated. The filling content of CNTs increases as the decrease of CB content, and the mass ratio of CNTs increase to CB decrease is fixed to m (CNTs):m(decreasing amount of CB)=1:2.5.The dispersion of CNTs at the brittle fracture surface was gottenby the scanning electron microscopy (SEM). The flatness and height difference of the tensile fracture-surface were observed by 3D measuring laser microscope. The tensile strength was the best when 4 phr CNTs was filled, that was 11.41% higher than that of composites with 0 phr CNTs. The processability was worse and the modulus was enhanced, abrasion property increased with the increase of CNTs and composites with 8 phr CNTs was 21.14% more wearable than 0 phr CNTs. According to the loss factor of dynamic mechanical analysis (DMA), rolling resistance of composites was reductive but wet-skid resistance decreased with the increase of CNTs.

Key words: composite synergistic effect carbon nanotubes carbon black mechanical properties DIN abrasion DMA

Received: 27 July 2016

ZTFLH:

TB332

Fund: Supported by National Natural Science Foundation of China (Nos.51276091 & 51676103) and Independent Innovation and Achievement Transformation Projects of Shandong (No.2014ZZCX01503)

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https://www.cjmr.org/EN/10.11901/1005.3093.2016.444 OR https://www.cjmr.org/EN/Y2017/V31/I10/758

Table 1 Experimental formula

Table 2 Mass of CNTs and carbon black

Fig.1 SEM surface appearance images of different ratio of composites (a) 1#,(b) 3#,(c) 6#,(d) 9#

Fig.2 3D measuring laser microscope images of the tensile fracture-surface of composites (a) 1#,(b) 3#,(c) 6#,(d) 9#

Fig.3 3D measuring laser microscope images of the tensile fracture-surface of composites (The left is colorized image and the right is altitude intercept 3D image of each group) (a) 1#,(b) 3#,(c) 6#,(d) 9#

Fig.4 Tensile strength and modulus of different ratio of composites

Fig.5 Processability of the composites

Fig.6 Modulus and DIN abrasion of the composites

Fig.7 Loss factor of different ratio of composites

Table 3 Peak of loss factor's curve

Fig.8 Loss factor of composites at 0℃and 60℃

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