Microstructure and Properties of Titanium Alloy/Stainless Steel Composite Plate Prepared by Spark Plasma Sintering

doi:10.11901/1005.3093.2022.293

Chinese Journal of Materials Research

2023, Vol. 37

Issue (8): 581-589 DOI: 10.11901/1005.3093.2022.293

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Microstructure and Properties of Titanium Alloy/Stainless Steel Composite Plate Prepared by Spark Plasma Sintering

LIU Ruifeng¹(

), XIAN Yunchang², ZHAO Rui², ZHOU Yinmei², WANG Wenxian³

^1.Taiyuan University of Technology, College of Aeronautics and Astronautics, Taiyuan 030024, China
^2.Shanxi Yangmei Chemical Machinery (Group) Co. Ltd., Shanxi Key Laboratory of Coal Chemical Pressure Vessels, Taiyuan 030032, China
^3.Taiyuan University of Technology, College of Materials Science and Engineering, Taiyuan 030024, China

Cite this article:

LIU Ruifeng, XIAN Yunchang, ZHAO Rui, ZHOU Yinmei, WANG Wenxian. Microstructure and Properties of Titanium Alloy/Stainless Steel Composite Plate Prepared by Spark Plasma Sintering. Chinese Journal of Materials Research, 2023, 37(8): 581-589.

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Abstract

Composite plates of titanium alloy/stainless steel were prepared by spark plasma sintering (SPS), and their microstructure, micro-nano mechanical behavior and tensile properties were investigated. Results show that the temperature of the interface of titanium alloy/stainless steel rises fast owing to the short time spark discharge under the action of high energy pulse current. The interface is relatively flat, while inter-diffusion of Ti, Fe and Cr atoms occurs obviously. A small number of intermetallic compounds TiFe, TiFe₂ and FeCr formed at the interface. The hardness of the zone with brittle intermetallic compounds reached 3.5578 GPa, which is much higher than that of metal matrix on both sides (Ti-2.943 GPa, Steel-2.717 GPa). The tensile strength of the titanium alloy/stainless steel composite is 387.5 MPa, which is 72% and 79% of the base material of titanium alloy and stainless steel respectively. During the tensile process, cleavage fracture first occurs on the stainless-steel side, while the titanium alloy side continues to bear the load until the typical ductile fracture occurs.

Key words: composite spark plasma sintering tip spark bonding interface fracture mechanism

Received: 25 May 2022

ZTFLH:

TG146.2+1

Fund: National Key Research and Development Program of China(2017YFB0602605);Major Science and Technology Projects in Shanxi Province(Nos. MC2016-01);Major Science and Technology Projects in Shanxi Province(Nos. MC2016-02);National Natural Science Foundation of China(52075360);Fundamental Research Program of Shanxi Province(20210302124653)

Corresponding Authors: LIU Reifeng, Tel: 15735161357, E-mail: liuruifeng@tyut.edu.cn

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	LIU Ruifeng
	XIAN Yunchang
	ZHAO Rui
	ZHOU Yinmei
	WANG Wenxian

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https://www.cjmr.org/EN/10.11901/1005.3093.2022.293 OR https://www.cjmr.org/EN/Y2023/V37/I8/581

Table 1 Chemical composition of 443 ferritic stainless steel (mass fraction, %)

Table 2 Chemical composition of TC1 titanium alloys (mass fraction, %)

Fig.1 Connection schematic diagram (a) and process diagram (b) of SPS process

Fig.2 Current density distribution diagram

Fig.3 Temperature distribution diagram

Fig.4 Residual stress distribution diagram

Table 3 Thermophysical parameters of 443 ferritic stainless steel

Table 4 Thermophysical parameters of TC1 titanium alloy

Fig.5 SEM micrograph of the interface of titanium alloy and stainless steel jointed by spark plasma sintering (a, b) SEM micrograph; (b~f) map scanning

Fig.6 EDS scanning results of the interface of titanium alloy and stainless steel (a) selected points of EDS point scanning; (b) EDS line scanning route; (c) results of EDS line scanning

Table 5 EDS point in Fig.6a scanning results (atomic fraction, %)

Table 6 Nanoindentation test results (GPa)

Fig.7 EBSD diagram of bonding interface of titanium alloy and stainless steel produced by SPS (a) inverse pole figure; (b) recrystallization distribution

Fig.8 XRD test results of the interface of titanium alloy and stainless steel (a) and Fe-Ti phase diagram (b)

Fig.9 Nanoindentation test results of the interface of titanium alloy and stainless steel

Fig.10 Tensile curve of titanium alloy/stainless steel heterogeneous plates

Fig.11 Tensile fracture morphology of titanium alloy/stainless steel heterogeneous plates (a, b) macroscopic morphology; (c, d) titanium alloy side; (e, f) stainless steel side

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