Synthesis and Characterization of Carbon Fibers Multi-scale Reinforcement with Grafted Graphene Oxide

doi:10.11901/1005.3093.2015.020

Chinese Journal of Materials Research

2016, Vol. 30

Issue (3): 229-234 DOI: 10.11901/1005.3093.2015.020

Orginal Article

Current Issue | Archive | Adv Search

Synthesis and Characterization of Carbon Fibers Multi-scale Reinforcement with Grafted Graphene Oxide

ZHAO Yonghua¹, MA Zhaokun^1,^*(

), SONG Huaihe¹, CHEN Ming¹, ZHOU Zhenggang²

Cite this article:

ZHAO Yonghua, MA Zhaokun, SONG Huaihe, CHEN Ming, ZHOU Zhenggang. Synthesis and Characterization of Carbon Fibers Multi-scale Reinforcement with Grafted Graphene Oxide. Chinese Journal of Materials Research, 2016, 30(3): 229-234.

Download:

HTML

PDF(2216KB)
Export: BibTeX | EndNote (RIS)

Abstract

A kind of carbon fiber / graphene oxide multi-scale reinforcement was prepared by "grafting to" method, with raw materials of the graphene oxide fabricated by a modified Hummers method and the carbon fiber treated with silane coupling agent Kh550.The prepared product was characterized by means of scanning electron microscopy (SEM), transmission electron microscopy (TEM), Ramanspectroscopy (Raman), X-ray photoelectron spectroscopy (XPS) and infrared spectroscopy (IR). The mechanical properties and the conductivity of the reinforced carbon fiber were measured by electronic tensile strength tester for fiber and resistivity instrument. The results showthatafter grafting, the graphene oxide can be grafted onto grooves and defects of the carbon fiber surface; the number of unsaturated carbon atom increases andthe size of microcrystalline decreases on the surface of the carbon fiber; andthe tensile strength andthe fractureelongation of single carbon fiber may be increased up to 9.8% and 13.1%, respectively andhowever the conductivity of carbon fiber is reduced by 11.6%.

Key words: inorganic non-metallic materials carbon fiber graphene oxide silane coupling agent grafting

Received: 13 January 2015

ZTFLH:

TB321

About author: CorrespondingAuthor*To whom correspondence should be addressed, Tel: 13911126076, E-mail: mazk@mail.buct.edu.cn

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Yonghua ZHAO
	Zhaokun MA
	Huaihe SONG
	Ming CHEN
	Zhenggang ZHOU

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2015.020 OR https://www.cjmr.org/EN/Y2016/V30/I3/229

Fig.1 (a) HRTEM of graphene oxide (GO); SEM images of the carbon fibers multi-scale reinforcement with grafted graphene oxide: (b) Carbon fiber (CF) treated with nitric acid; (c) CF-Nitric acid-SilanecouplingagentKH550; (d) CF-GO (1 mg/ml); (e) CF-GO (0.5 mg/ml); (f) CF-GO (0.25 mg/ml); (g) CF-GO (0.125 mg/ml); (h) CF-GO (0.0625 mg/ml)

Fig.2 XPS wide scan energy spectra of T300-6k carbon fiber, (a) CF; (b) CF+GO

Fig.3 C1s spectra of T300-6k carbon fiber: (a) CF; (b) CF+GO

Table 1 Surface elements analysis of T300-6k carbon fiber before and after grafting (mass fraction)

Fig.4 FT-IR patterns of the carbon fibers multi-scale reinforcement with grafted graphene oxide: (a) CF- Nitric acid; (b) CF-Nitric acid-Silanecoupling agent; (c) CF-GO

Fig.5 Reaction mechanism of the carbon fibers multi-scale reinforcement with grafted graphene oxide

Fig.6 Raman spectra of the carbon fibers multi-scale reinforcement with grafted graphene oxide: (a) CF; (b) CF+GO (0.25 mg/ml); (c) CF+GO+800℃

Table 2 D band and G band of Raman for the carbon fibers multi-scale reinforcement with grafted graphene oxide

Table 3 Mechanical properties of the carbon fibers multi-scale reinforcement with grafted graphene oxide

1	HAO Yuankai, XIAO Jiayu,High performance composite materials science ( Beijing, Chemical Industry Press, 2004)
	(郝元恺, 肖加余, 高性能复合材料学 (北京, 化学工业出版社, 2004))
2	HE Fu, Carbon fiber and its application technology (Beijing: Chemical Industry Press, 2004)
	(贺福, 碳纤维及其应用技术 (北京, 化学工业出版, 2004))
3	De. Riccardis, M. F, Carbone. D, Dikonimos, M. T. Anchorage of carbon nanotubes grown on carbon fibres, Carbon, 44, 671(2006)
4	Sharma S P, Lakkad S C, Compressive strength of carbon nanotubes grown on carbon fiber reinforced epoxy matrix multi-scale hybrid composites, Surface and Coatings Technology, 205, 350(2010)
5	Novoselov K S, Geim A K, Morozov S V, Electric field effect in atomically thin carbon films, Science, 306, 666(2004)
6	WANG Xuefei, ZHANG Yonggang, CHEN Yousi, QIAN Xin, JIANG Chi, SONG Chen, YANG Jianhang, Research progress of carbon fiber multi-scale reinforcement body , With the application of high-tech fibers, 38(5), 40(2013)
	(王雪飞, 张永刚, 陈友汜, 钱鑫, 江驰, 宋晨, 杨建行, 碳纤维多尺度增强体的研究进展, 高科技纤维与应用, 38(5), 40(2013))
7	Stankovich S, Piner R D, Nguyen S T, Ruoff R S, Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets, Carbon, 44, 3342(2006)
8	LIU Xiuying, SONG ying, LI Cunmei, WANG Fuping, Carbon fiber grafted graphene oxide new enhanced synthesis and characterization of body system, Chinese Journal of Inorganic Chemistry, 27(11), 2128(2011)
	(刘秀影, 宋英, 李存梅, 王福平, 氧化石墨烯接枝碳纤维新型增强体的制备与表征, 无机化学学报, 27(11), 2128(2011))
9	Li Yibin, Peng Qingyu, He Xiaodong, Hu Pingan, Wang Chao, Shang Yuanyuan, Wang Rongguo, Jiao Weicheng, Lv Hongzhen, Synthesis and characterization of a new hierarchical reinforcement bychemically grafting graphene oxide onto carbon ﬁbers, Journal of Materials Chemistry, 22, 18748(2012)
10	Huang ShY, Wu G P, Chen Ch M, Yu Y, Zhang ShCh, Lu Ch X, Electrophoretic deposition and thermal annealing of a grapheme oxide thin on carbon fiber surfaces, Carbon, 52, 605(2013)
11	Fan X Y, Zh X Q, Yan Ch, Li Hongzhou, Interfacial microstructure and propertiesof carbon fiber composites modified with graphene oxide, Applied Materials & Interfaces, 4, 1543(2012)
12	Ferrari A C, Robertson, Interpretation of Raman spectra of disordered and amorphous carbon, Physical Review B, 61(20), 14095(2000)

[1]	SONG Lifang, YAN Jiahao, ZHANG Diankang, XUE Cheng, XIA Huiyun, NIU Yanhui. Carbon Dioxide Adsorption Capacity of Alkali-metal Cation Dopped MIL125[J]. 材料研究学报, 2023, 37(9): 649-654.
[2]	SHAO Hongmei, CUI Yong, XU Wendi, ZHANG Wei, SHEN Xiaoyi, ZHAI Yuchun. Template-free Hydrothermal Preparation and Adsorption Capacity of Hollow Spherical AlOOH[J]. 材料研究学报, 2023, 37(9): 675-684.
[3]	REN Fuyan, OUYANG Erming. Photocatalytic Degradation of Tetracycline Hydrochloride by g-C₃N₄ Modified Bi₂O₃[J]. 材料研究学报, 2023, 37(8): 633-640.
[4]	LIU Mingzhu, FAN Rao, ZHANG Xiaoyu, MA Zeyuan, LIANG Chengyang, CAO Ying, GENG Shitong, LI Ling. Effect of Photoanode Film Thickness of SnO₂ as Scattering Layer on the Photovoltaic Performance of Quantum Dot Dye-sensitized Solar Cells[J]. 材料研究学报, 2023, 37(7): 554-560.
[5]	LI Yanwei, LUO Kang, YAO Jinhuan. Lithium Ions Storage Properties of Ni(OH)₂ Anode Materials Prepared with Sodium Dodecyl Sulfate as Accessory Ingredient[J]. 材料研究学报, 2023, 37(6): 453-462.
[6]	YU Moxin, ZHANG Shuhai, ZHU Bowen, ZHANG Chen, WANG Xiaoting, BAO Jiamin, WU Xiang. Preparation of Nitrogen-doped Biochar and its Adsorption Capacity for Co²⁺[J]. 材料研究学报, 2023, 37(4): 291-300.
[7]	ZHU Mingxing, DAI Zhonghua. Study on Energy Storage Properties of SrSC_0.5Nb_0.5O₃ Modified BNT-based Lead-free Ceramics[J]. 材料研究学报, 2023, 37(3): 228-234.
[8]	LIU Zhihua, YUE Yuanchao, QIU Yifan, BU Xiang, YANG Tao. Preparation of g-C₃N₄/Ag/BiOBr Composite and Photocatalytic Reduction of Nitrate[J]. 材料研究学报, 2023, 37(10): 781-790.
[9]	ZHOU Yi, TU Qiang, MI Zhonghua. Effect of Preparing Methods on Structure and Properties of Phosphate Glass-ceramics[J]. 材料研究学报, 2023, 37(10): 739-746.
[10]	XIE Feng, GUO Jianfeng, WANG Haitao, CHANG Na. Construction of ZnO/CdS/Ag Composite Photocatalyst and Its Catalytic and Antibacterial Performance[J]. 材料研究学报, 2023, 37(1): 10-20.
[11]	QI Yunchao, FANG Guodong, ZHOU Zhengong, LIANG Jun. In-plane Tensile Strength for Needle-punched Composites Prepared by Different Needling Processes[J]. 材料研究学报, 2023, 37(1): 21-28.
[12]	ZHANG Peng, HUANG Dong, ZHANG Fuquan, YE Chong, WU Xiao, WU Huang. Effect of Graphitization Degree of Mesophase Pitch-based Carbon Fibers on Carbon Fiber/Al Interface Damage[J]. 材料研究学报, 2022, 36(8): 579-590.
[13]	FANG Xiangming, REN Shuai, RONG Ping, LIU Shuo, GAO Shiyong. Fabrication and Infrared Detection Performance of Ag-modified SnSe Nanotubes[J]. 材料研究学报, 2022, 36(8): 591-596.
[14]	LI Fulu, HAN Chunmiao, GAO Jiawang, JIANG Jian, XU Hui, LI Bing. Temperature Dependent Luminescence Properties of Graphene Oxide[J]. 材料研究学报, 2022, 36(8): 597-601.
[15]	ZHU Xiaodong, XIA Yangwen, YU Qiang, Yang Daixiong, HE Lili, FENG Wei. Preparation and Characterization of Cu Doped Rutile TiO₂ and Photocatalytic Property[J]. 材料研究学报, 2022, 36(8): 635-640.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed