Short-term Oxidation Behavior of Domestic Forged and Solution Annealed 316LN Stainless Steel in High Temperature Pressurized Water

doi:10.11901/1005.3093.2014.401

Chinese Journal of Materials Research

2015, Vol. 29

Issue (6): 401-409 DOI: 10.11901/1005.3093.2014.401

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Short-term Oxidation Behavior of Domestic Forged and Solution Annealed 316LN Stainless Steel in High Temperature Pressurized Water

Yueling GUO^1,²,En-Hou HAN^2,^1,^**(

),Jianqiu WANG²

1. National Center for Materials Service Safety, University of Science and Technology Beijing,
Beijing 100083, China
2. Key Laboratory of Nuclear Materials and Safety Assessment, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

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Yueling GUO,En-Hou HAN,Jianqiu WANG. Short-term Oxidation Behavior of Domestic Forged and Solution Annealed 316LN Stainless Steel in High Temperature Pressurized Water. Chinese Journal of Materials Research, 2015, 29(6): 401-409.

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Abstract

Effect of forging on the average grain size, residue strain and grain orientation distribution of nuclear grade 316LN stainless steel (316LNss) was studied by means of electron back scattering diffraction (EBSD). The morphology and chemical composition of the oxide films formed on the as-received 316LNss as well as the forged and solution annealed 316LNss after immersion in borated and lithiated high temperature pressurized water at 300 ^oC for 190 h were also investigated. The results show that the average grain size was reduced and the residual strain was eliminated by forging and followed solution annealing. There were no obvious textures in the forged and solution annealed 316LNss. A two-layered oxide film grew on 316LNss after immersion in high temperature pressurized water. The outer layer composes of hydroxides and Fe-enriched spinal oxides and the inner layer composes of Cr-enriched spinal oxides. The forged and solution annealed 316LNss exhibited a lower oxidation rate rather than the as received ones due to the formation of a thinner and more Cr-enriched oxide film. The oxidation mechanism was also discussed.

Key words: material failure and protection 316LN stainless steel oxide film high temperature pressurized water forging corrosion nuclear power

Received: 11 August 2014

Fund: ^*Supported by National Science and Technology Major Project No. 2011ZX06004-009.

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	Yueling GUO
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https://www.cjmr.org/EN/10.11901/1005.3093.2014.401 OR https://www.cjmr.org/EN/Y2015/V29/I6/401

Table 1 Chemical compositions of 316LNss (%, mass fraction)

Table 2 Binding energies of XPS-peaks of standards^[22]

Fig.1 Microstructure and grain orientations of 316LNss, (a) GAM mapping of the as-received 316LNss, (b) PF mapping of the as-received 316LNss, (c) GAM mapping of the forged and solution anneal treated 316LNss, (d) PF mapping of the forged and solution anneal treated 316LNss

Fig.2 SEM images of oxide films grown on 316LNss after immersion in high temperature pressurized water for 190 h, (a) as-received, (b) forged and solution anneal treated

Fig.3 XRD spectra of oxide film grown on 316LNss after immersion in high temperature pressurized water for 190 h

Fig.4 Composition profiles of the oxide films grown on 316LNss after immersion in high temperature pressurized water for 190 h, (a) as-received, (b) forged and solution anneal treated

Fig.5 Normalized content (atomic fraction) of Fe, Ni, Cr contained in the oxide films of the as-received 316LNss and the forged and solution anneal treated 316LNss

Fig.6 Detailed XPS spectra of Cr 2p2/3 in the oxide film grown on 316LNss after immersion in high temperature pressurized water for 190 h, (a) as-received, (b) forged and solution anneal treated

Fig.7 Detailed XPS spectra of Ni 2p2/3 in the oxide film grown on 316LNss after immersion in high temperature pressurized water for 190 h, (a) as-received, (b) forged and solution anneal treated

Fig.8 Detailed XPS spectra of Fe 2p2/3 in the oxide films grown on 316LNss after immersion in high temperature pressurized water for 190 h, (a) as-received, (b) forged and solution anneal treated

Fig.9 Detailed XPS spectra of O 1s in the oxide film grown on 316LNss after immersion in high temperature pressurized water for 190 h, (a) as-received; (b) forged and solution anneal treated

Table 3 SEM-EDS results of the oxides grown on 316LNss after immersion in high temperature pressurized water for 190 h (%, atomic fraction)

Fig.10 Layer model of the oxide film formed on 316LNss in high temperature pressurized water

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