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| Study on Surface Modification of Low Density Polyethylene (LDPE) Film by Low Temperature Plasma Treatment |
| XIE Linkun, YE Xi, WU Zhangkang, DENG Qiping, CHAI Xijuan, LIANG Yanjun |
| Department of Wood Science and Interior Decoration, Southwest Forestry University, Kunming 650224 |
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Cite this article:
XIE Linkun YE Xi WU Zhangkang DENG Qiping CHAI Xijuan LIANG Yanjun. Study on Surface Modification of Low Density Polyethylene (LDPE) Film by Low Temperature Plasma Treatment. Chin J Mater Res, 2010, 24(6): 661-666.
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Abstract The surface of low density polyethylene film was modified using low temperature O2 plasma under the condition of working pressure of 20 Pa and treatment power of 30 W. The results were analyzed with water contact angle measurement, Fourier transformed infrared spectroscopy(FTIR), differential scanning calorimetry(DSC), scanned electron microscopy(SEM), atomic force microscopy(AFM), etc.. The results showed that the weight loss rate of per unit area was improved as linearity with the increase of the treatment time of 10 s∼300 s; the water contact angle was gradually decreased in the 0∼20 s and theirs values did not change obviously during the 40 s∼300 s treatment time; the evolution of water contact angle was gradually increased with the aging time; the surface of low density polyethylene could form some polar species such as carbonyl, hydroxyl and carboxyl groups and the thermal behaviors (mainly crystallinity) were changed after treatment by low temperature O2 plasma.
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Received: 19 April 2010
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| Fund: Supported by Yunnan Provincial Application Basic Research No. 209306 and Yunnan Provincial Department of Education No.500929. |
| 1 R. Bongiovanni, B. Gagnor, G. Malucelli, A. Priola, A. Pollicino, Surface properties and adhesion of maleinized polyethylene films, Journal of Materials Science , 33（6）,1461（1998）
2 M.R. Sanchis, V. Blanes, M. Blanes, D. Garcia, R . Balart, Surface modification of low density
polyethylene (LDPE) film by low pressure O2 plasma treatment, European Polymer Journal
, 42（7）, 1558（2006）
3 S. Debnath, R. Ranade, S.L. Wunder, G.R. Baran, J.M. Zhang, E.R. Fisher, Chemical surface
treatment of ultrahigh molecular weight polyethylene for improved adhesion to methacrylate
resins, Journal of Applied Polymer Science, 96(5),1564（2005）
4 A.R. Martin, F.S. Denes, R.M. Rowell, L.H.C. Mattoso, Mechanical behavior of cold
plasma-treated sisal and high-density polyethylene composites, Polymer Composites , 24(3), 464(2003)
5 F.J. Medel, F. García-álvarez, E. Gómez-Barrena, J.A. Puértolas, Microstructure changes of extruded ultra high molecular weight polyethylene after gamma irradiation and shelf-aging，Polymer Degradation and Stability , 88(3), 435（2005）
6 A.I.Drachev, L.A.Rishina, A.B.Gilman, N. M.Galashina , A.N.Shchegolikhin , Crystal phase transformations within propylene/hexane-1 copolymers films as induced by direct current discharge treatment, European Polymer Journal , 41(7), 1688（2005）
7 CY. Lii , CD. Liao , L. Stobinski , P. Tomasik , Exposure of granular starches to low-pressure glow ethylene plasma, European Polymer Journal , 38(8), 1601（2002）
8 L.S. Shi, Characterization of the flame retardancy of EVA copolymer by plasma grafting of acrylic acid, European Polymer Journal , 36(12), 2611（2000）
9 N. De Geyter, R . Morent , C. Leys, Surface characterization of plasma-modified polyethylene
by contact angle experiments and ATR-FTIR spectroscopy, Surface and Interface Analysis,
40(3-4), 608（2008）
10 J. Fisher , E.A. Reeves , G. H. Isaac, K. A. Saum, W. M . Sanford, Comparison of the wear of aged and non-aged ultrahigh molecular weight polyethylene sterilized by gamma irradiation and by gas plasma, Journal of Materials Science-Materials in Medicine, 8(6), 375（1997）
11 I. Gancarz, G. Pozniak, M.Bryjak , Modification of polysulfone membranes 3. Effect of nitrogen plasma, European Polymer Journal , 36(8), 1563（2000）
12 Z. M.Liu , Z. K.Xu , J.Q.Wang , Q.Yang , J. Wu , P. Seta, Surface modification of microporous polypropylene membranes by the grafting of poly(gamma-stearyl-L-glutamate), European Polymer Journal , 39(12), 2291（ 2003）
13 YAN Zhiyun, LIU Anhua, JIA Demin, The applications of low-temperature plasma treatment in
surface modification of polymeric materials, High Technology Letters, 4, 107(2004)
(严志云, 刘安华, 贾德民, 低温等离子体技术在聚合物材料表面改性中的应用, 高技术
通讯, 4, 107(2004))
14 XU Genhui, JIANG Enyong,SHENG Jing,XU Tinxian,LI Zhenhua, Plasma Technology and Application(Beijing, Chemical Industry Press,2006)p.2
(许根慧，姜恩永，盛京，徐廷献，李振花，等离子体技术与应用（北京，化学工业出版社，2006）)p.2
15 A. N. Bhoj, M. J. Kushner, Plasma-polymer interactions in a dielectric barrier discharge, IEEE Transactions Plasma Science, 33(2), 250（2005）
16 J. C. Caro, U. Lappan, F. Simon, D. Pleul, K. Lunkwitz, On the low-pressure plasma treatment of PTFE (polytetrafluoroethylene) with SO2 as process gas, European Polymer Journal , 35(6), 1149（1999）
17 D. Hegemann, H. Brunner, C. Oehr, Plasma treatment of polymers for surface and adhesion
improvement, Nuclear Instruments and Methods in Physics Research Section B：Beam
Interactions with Materials and Atoms, , 208(8), 281（2003）
18 S. Guruvenket , R. G. Mohan , M. Komath , A. M. Raichur , Plasma surface modification of polystyrene and polyethylene, Applied Surface Science, 236(1-4), 278（2004）
19 N. Inagaki, Surface modification of polymeric materials by remote plasma, Macromolecular symposia , 159(1), 151（2000）
20 G. W. Zhao, Y. S. Chen, X. L.Wang, Surface modification of polyethylene film by acrylamide graft and alcoholysis for improvement of antithrombogenicity, Applied Surface Science, 253(10), 4709（2007）
21 NIU Jiarong, GU Zhenya, Research on surface hydrophilic modification of PET and PE films by low temperature air plasma, Journal of Tianjin Institute of Textile Science and Technology, 23(4), 40( 2004)
(牛家嵘, 顾振亚, 利用低温空气等离子体改善聚酯和聚乙烯薄膜表面亲水性的研究, 天津工业大学学报, 23(4), 40( 2004))
22 LIU Yuming, AO Ling, YANG Wanzheng, Surface modification of polyester fabrics and its
aging with cold plasma, Acta Scientiarum Naturalium Universitatis Neimongol, 35（5）, 593(2004)
(刘裕明, 敖玲, 杨万政, 冷等离子体对涤棉表面改性及其时效性研究, 内蒙古大学学报(自然科学版), 35（5）, 593(2004))
23 LI Ying,MAO Sufen, Study on the surface modification of polymer films by plasma, Journal of
Functional Materials, 26（5）, 468(1995)
(李瑛, 茅素芬, 高分子薄膜等离子体表面改性的研究, 功能材料, 26（5）, 468(1995))
24 H. Drnovska, L. Lapcik, V. Bursikova, J. Zemek, Ana M.Barros-timmons, Surface properties of
polyethylene after low-temperature plasma treatment, Colloid and Polymer Science , 281（11）,1025（2003）
25 M. Lehocky, H. Drnovská, B. Lap???ková, A. Barros-Timmons, T. Trindade, M. Zembala, L. Lap???k, Plasma surface modification of polyethylene, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 222(1):125（2003）
26 T. Hirotsu, A. A. J. Ketelaars, K. Nakayama, Plasma surface treatment of PCL/PC blend
sheets, Polymer Engineering and Science , 40（11）, 2324(2000)
27 S. C. Park, S. K. Koh, K. D. Pae, Effects of surface modification by Ar+ irradiation on wettability of surfaces of poly(ethylene terephthalate) films, Polymer Engineering and Science , 38(7), 1185( 1998)
28 B. M. Wickson, J. L. Brash, Surface hydroxylation of polyethylene by plasma polymerization of allyl alcohol and subsequent silylation, Colloids and Surfaces A: Physicochemical and Engineering Aspects, 156(1–3), 201(1999)
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