Influence of Ca 2+ and Dissolved Ozone in Phosphating Solution on Phosphate Coating on A3 Carbon Steel

Chin J Mater Res

2010, Vol. 24

Issue (1): 44-50 DOI:

论文

Current Issue | Archive | Adv Search

Influence of Ca ²⁺ and Dissolved Ozone in Phosphating Solution on Phosphate Coating on A3 Carbon Steel

SHENG Minqi ¹; WANG Yi ^1;2; ZHONG Qingdong ¹; LIN Hai ¹; ZHOU Qiongyu ¹; WEI Yinyin³

1.Shanghai Key Laboratory of Modern Metallurgy and Material Processing; Shanghai University; Shanghai 200072
2.School of Energy Sources and Environment Engineering; Shanghai University of Electric Power; Shanghai 200090
3.Department of Chemistry; East China Normal University; Shanghai 200062

Cite this article:

SHENG Minqi WANG Yi ZHONG Qingdong LIN Hai ZHOU Qiongyu WEI Yinyin. Influence of Ca ²⁺ and Dissolved Ozone in Phosphating Solution on Phosphate Coating on A3 Carbon Steel. Chin J Mater Res, 2010, 24(1): 44-50.

Download:

PDF(1462KB)
Export: BibTeX | EndNote (RIS)

Abstract

Phosphate coating on the surface of A3 carbon steel was prepared through the addition of Ca2+ and ozone as an accelerator of phosphating treatment at low temperature, and was characterized by SEM, XRD, EDS, FT-IR and corrosion electrochemical testing. The effects of Ca2+ and dissolved ozone in phosphating solution on the structure and performance of phosphate coating were investigated. The results show that the coating mass decreases with increasing the Ca2+ concentration in phosphating solution. Ca2+ can reduce the crystal size of coating and increase the density and corrosion resistance of coating. The dissolved ozone in phosphating solution can reduce the crystal size of coating and promote the growth of crystal, so the nucleation and formation rates are increased and the corrosion resistance of coating is improved. When pH=2.70, concentration of Ca2+ and ozone were 1.8 g/L and 2.50 mg/L respectively, the mass of phosphate coating was 5.46 g/m2, the corrosion-resistance time of coating with CuSO4 dripping was >122 s, and the corrosion current of phosphating sample was 0.50 μA/cm2 in 5% NaCl solution.

Key words: surface and interface in the materials phosphating A3 carbon steel ozone calcium ion corrosion surface treatment

Received: 13 July 2009

Fund:

Supported by National Natural Science Fundation of China Nos.50571059 and 50615024, the Program for New Century Excellent Talents in University No.NCET-07-0536, and Program for Innovative Research Team in University No.IRT0739.

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	CHENG Min-Ai

URL:

https://www.cjmr.org/EN/ OR https://www.cjmr.org/EN/Y2010/V24/I1/44

1 D.B.Freeman, Phosphating Metal Pretreatment (Beijing, National Defense Industry Press, 1989) p.1
(D.B.弗里曼, 磷化与金属预处理 (北京, 国防工业出版社, 1989) p.1)
2 S.Feliu, V.Barranco, Study of degration mechanisms of a protective lacquer film formulate with phosphating reagents applied on galvanized steel, Surface and Coatings Technology, 182(2), 251(2004)
3 M.C.Deys, G.Bluxtein, R.Romagnoli, B.delAmo, The influence of the anion type on the anticorrosive behavior of inorganic phosphates, Surface and Coatings Technology, 150(3), 133(2002)
4 WANG Quanfa, LI Yan, Phosphating and lubrication for cold-forming processes, Lubrication Engineering, (4), 41(1994)
(汪泉发, 黎燕, 冷塑加工用磷化和润滑处理, 密封与润滑, (4), 41(1994))
5 K.Ravichandran, H.Sivanandh, S.Ganesh, T.Hariharasudan, T.S.N.Sankara Narayanan, Acceleration of the phosphating process-the utility of galvanic coupling, Metal Finishing, 98(9), 48(2000)
6 D.Zimmermann, A.G.Munoz, J.W.Schultze, Formation of Zn–Ni alloys in the phosphating of Zn layers, Surface and Coatings Technology, 197(2), 260(2005)
7 X.Sun, D.Susac, R.Li, K.C.Wong, T.Foster, K.A.R. Mitchell, Some observations for effects of copper on zinc phosphate conversion coatings on aluminum surfaces, Surface and Coatings Technology, 155(1), 46(2002)
8 LU Weiguo, LI Shuying, Phosphating accelerant, Surface Technology, 31(6), 12(2002)
(鲁维国, 李淑英, 磷化促进剂, 表面技术, 31(6), 12(2002))
9 LI Canquan, SUN Yaru, XU Binghui, SUN Fuming, Action of sodium citrate accelerating agent in phosphating at ambient temperature, Materials Protection, 39(8), 16(2006)
(李灿权, 孙雅茹, 徐炳辉, 孙福明, 柠檬酸钠在常温磷化中的作用, 材料保护, 39(8), 16(2006))
10 Guangyu Li, Liyuan Niu, Jianshe Lian, Zhonghao Jiang, A black phosphate coating for C1008 steel, Surface and Coatings Technology, 176(2), 215(2004)
11 Duan Weng, Rizhong Wang, Guoqing Zhang, Environmental impact of zinc phosphating in surface treatment of metals, Metal Finishing, 96(9), 54(1998)
12 P.A.Bingham, R.J.Hand, Vitrified metal finishing wastes I. Composition, density and chemical durability, Journal of Hazardous Materials, 119(1-3), 125(2005)
13 Hhiu Tsu Lin, Green chemistry in situ phosphating coatings, Progress in Organic Coatings, 42(3-4), 226(2001)
14 E.M.Derun, T.Demirozu, M.B.Piskin, S.Piskin, The analysis of corrosion performance of car bodies coated by no nickel and low nickel zinc phosphating processes, Materials and Corrosion, 56(6), 412(2005)
15 R.Andreozzim, V.Caprio, A.Insola, R.Marotta, R.Sanchirico, Advanced oxidation processes for the treatment of mineral oil-contaminated waste waters, Water Research, 34(2), 620(2000)
16 SHENG Minqi, CHEN Yepu, JIA Ruiping, FAN Haihua, Effect of ozone on phosphating film on carbon steel, Corrosion & Protection, 29(2), 76(2008)
(盛敏奇, 陈烨璞, 贾瑞平, 范海华, 臭氧对碳钢表面磷化的影响, 腐蚀与防护, 29(2), 76(2008))
17 Hui Zhang, Lijie Duan, Daobin Zhang, Absorption kinetics of ozone in water with ultrasonic radiation, Ultrasonics Sonochemistry, 14(5), 552(2007)

[1]	LU Yimin, MA Lifang, WANG Hai, XI Lin, XU Manman, YANG Chunlai. Carbon-base Protective Coating Grown by Pulsed Laser Deposition on Copper Substrate[J]. 材料研究学报, 2023, 37(9): 706-712.
[2]	WANG Qian, PU Lei, JIA Caixia, LI Zhixin, LI Jun. Inhomogeneity of Interface Modification of Carbon Fiber/Epoxy Composites[J]. 材料研究学报, 2023, 37(9): 668-674.
[3]	FENG Ye, CHEN Zhiyong, JIANG Sumeng, GONG Jun, SHAN Yiyin, LIU Jianrong, WANG Qingjiang. Effect of a NiCrAlSiY Coating on Cyclic Oxidation and Room Temperature Tensile Properties of Ti65 Alloy Plate[J]. 材料研究学报, 2023, 37(7): 523-534.
[4]	JIANG Menglei, DAI Binbin, CHEN Liang, LIU Hui, MIN Shiling, YANG Fan, HOU Juan. Effect of Building Dimensions by Selective Laser Melting on Pitting Properties of 304L Stainless Steel[J]. 材料研究学报, 2023, 37(5): 353-361.
[5]	ZHANG Shuaijie, WU Qian, CHEN Zhitang, ZHENG Binsong, ZHANG Lei, XU Pian. Effect of Mn on Microstructure and Properties of Mg-Y-Cu Alloy[J]. 材料研究学报, 2023, 37(5): 362-370.
[6]	YANG Baolei, LIU Tingguang, SU Xianglin, FAN Yu, QIU Liang, LU Yonghao. Effect of Thermal Aging on Mechanical Properties and Intergranular Corrosion Resistance of 316LN[J]. 材料研究学报, 2023, 37(5): 381-390.
[7]	LI Pengyu, LIU Zitong, KANG Shumei, CHEN Shanshan. Effect of Plasma Treatment on Performance of Polybutylene Adipate Coating on Biomedical AZ31 Mg-alloy[J]. 材料研究学报, 2023, 37(4): 271-280.
[8]	LIAO Hongyu, JIA Yongxin, SU Ruiming, LI Guanglong, QU Yingdong, LI Rongde. Effect of Retrogression Times on Microstructure and Corrosion Resistance of 2024 Aluminum Alloy[J]. 材料研究学报, 2023, 37(4): 264-270.
[9]	CHEN Kaiwang, ZHANG Penglin, LI Shuwang, NIU Xianming, HU Chunlian. High-temperature Tribological Properties for Plasma Spraying Coating of Ni-P Plated Mullite Powders[J]. 材料研究学报, 2023, 37(1): 39-46.
[10]	SHAN Weiyao, WANG Yongli, LI Jing, XIONG Liangyin, DU Xiaoming, LIU Shi. High Temperature Oxidation Resistance of Cr Based Coating on Zirconium Alloy[J]. 材料研究学报, 2022, 36(9): 699-705.
[11]	CHEN Jie, LI Hongying, ZHOU Wenhao, ZHANG Qingxue, TANG Wei, LIU Dan. Effect of Heat Input on Low Temperature Toughness and Corrosion Resistance of Q1100 Steel Welded Joints[J]. 材料研究学报, 2022, 36(8): 617-627.
[12]	CAI Yusheng, HAN Hongzhi, REN Dechun, JI Haibin, LEI Jiafeng. Effect of Chemical Etching Process on Surface Roughness of TC4 Ti-alloy Fabricated by Laser Selective Melting[J]. 材料研究学报, 2022, 36(6): 435-442.
[13]	YANG Liuyang, TAN Zhuowei, LI Tongyue, ZHANG Dalei, XING Shaohua, JU Hong. Dynamic Corrosion Behavior of Pipeline Defects Characterized by WBE and EIS Testing Techniques[J]. 材料研究学报, 2022, 36(5): 381-391.
[14]	ZHANG Hongliang, ZHAO Guoqing, OU Junfei, Amirfazli Alidad. Superhydrophobic Cotton Fabric Based on Polydopamine via Simple One-Pot Immersion for Oil Water Separation[J]. 材料研究学报, 2022, 36(2): 114-122.
[15]	LI Yufeng, ZHANG Nianfei, LIU Lishuang, ZHAO Tiantian, GAO Wenbo, GAO Xiaohui. Preparation of Phosphorus-containing Graphene and Corrosion Resistance of Composite Coating[J]. 材料研究学报, 2022, 36(12): 933-944.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed