Synergistic Effect of Multi-media on Carbon Steel Corrosion

doi:10.11901/1005.3093.2021.004

Chinese Journal of Materials Research

2021, Vol. 35

Issue (10): 721-731 DOI: 10.11901/1005.3093.2021.004

ARTICLES

Current Issue | Archive | Adv Search

Synergistic Effect of Multi-media on Carbon Steel Corrosion

ZHANG Shaohua¹, LI Yanrui¹, WEI Yinghui¹^,²(

), LIU Baosheng¹, HOU Lifeng², DU Huayun², LIU Xiaoda²

^1.College of Materials Science and Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, China
^2.College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Cite this article:

ZHANG Shaohua, LI Yanrui, WEI Yinghui, LIU Baosheng, HOU Lifeng, DU Huayun, LIU Xiaoda. Synergistic Effect of Multi-media on Carbon Steel Corrosion. Chinese Journal of Materials Research, 2021, 35(10): 721-731.

Download:

HTML

PDF(21679KB)
Export: BibTeX | EndNote (RIS)

Abstract

The interfacial reaction between carbon steel and CO₂-Cl^-, along with the effect of HCO₃^- on the formation of corrosion products scale on the steel in the solution of CO₂-Cl^--HCO₃^- at room temperature were investigated via electrochemical impedance spectroscopy and potentiodynamic polarization measurement. The results show that the addition of CO₂ significantly increases the dissolution rate of carbon steel, whereas affects the Cl^-concentration little and that, the addition of Cl^- with high concentration can inhibit the dissolution of CO₂, leading to a slight decrease in the corrosion rate of carbon steel. The formation of corrosion products film on the surface of carbon steel is not obvious after adding a small amount of HCO₃^- in the solution, correspondingly the formation of loose corrosion products cannot inhibit the further dissolution of carbon steel; However, excessive HCO₃^- addition may accelerate the precipitation of fine crystallites by increasing the supersaturation of FeCO₃, and thus inhibiting the corrosion process.

Key words: metallic materials synergistic effect of multi-media electrochemical techniques corrosion mechanism

Received: 12 January 2021

ZTFLH:

TE988

Fund: National Natural Science Foundation of China(52071227);Special Found Projects for Central Government Guidance to Local Science and Technology Development(YDZX20181400002967);Shanxi Municipal Science and Technology Project(20191102004);Key Scientific Research Project of Shanxi Province(201805D121003)

About author: WEI Yinghui, Tel: 18003410625, E-mail: yhwei_tyut@126.com

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Shaohua ZHANG
	Yanrui LI
	Yinghui WEI
	Baosheng LIU
	Lifeng HOU
	Huayun DU
	Xiaoda LIU

URL:

https://www.cjmr.org/EN/10.11901/1005.3093.2021.004 OR https://www.cjmr.org/EN/Y2021/V35/I10/721

Table 1 Compositions of 20 carbon steel used in the experiment (mass fraction/%)

Fig.1 Macrostructure (a) and microstructure (b) of 20 carbon steel along with EDS results of (c) Region A and (d) Region B

Fig.2 Immersion experiment system

Fig.3 Potentiodynamic polarization curves (a) and Nyquist plots of carbon steel in solutions containing 0.2/1.0 mol/L Cl^- and 0.2/1.0 mol/L Cl^-+CO₂ (1 bar), respectively (b), and the corresponding equivalent circuit diagrams (c)/(d) at 25℃

Fig.4 Representative fitting results of potentiodynamic polarization curves of carbon steel in solutions containing Cl^- (a) and Cl^-+CO₂ (1 bar) (b), and the corresponding corrosion current density and corrosion rate (c)

Table 2 Parameters of electrochemical impedance spectroscopy component of specimens in solutions containing 0.2/1.0 mol/L Cl^- and 0.2/1.0 mol/L Cl^-+CO₂ (1 bar)

Fig.5 Surface morphologies (a~d) and EDS/XRD results of carbon steel immersed in solutions containing 0.2/1.0 mol/L Cl^- and 0.2/1.0 mol/L Cl^-+CO₂ (1 bar) (e-f)/(g) at 25℃

Fig.6 Potentiodynamic polarization curves (a) and impedance diagrams of carbon steel (b/c) in solutions containing CO₂ (1 bar)+0.1 mol/L Cl^-+0/0.05/0.1/0.5 mol/L HCO₃^- at 60℃

Table 3 Parameters of potentiodynamic polarization curves of carbon steel in solutions containing CO₂ (1 bar)+0.1 mol/L Cl^-+0/0.05/0.1/0.5 mol/L HCO₃^-

Table 4 Parameters of Electrochemical Impedance Spectroscopy component values of carbon steel in solutions containing CO₂ (1 bar)+0.1 mol/L Cl^-+0/0.05/0.1/0.5 mol/L HCO₃^-

Fig.7 Cyclic voltammetry curve of carbon steel in solutions containing CO₂ (1 bar)+0.1 mol/L Cl^-+0 (a), 0.05 (b), 0.1 (c) and 0.5 (d) mol/L HCO₃^- at 60℃

Fig.8 SEM morphologies of carbon steel polarized to 1.25 V vs. SCE in solutions containing CO₂ (1 bar)+0.1 mol/L Cl^-+0 (a), 0.05 (b), 0.1 (c) and 0.5 (d) mol/L HCO₃^- at 60℃

Fig.9 Surface SEM morphologies of carbon steel after 24 h immersion tests in solutions containing CO₂ (1 bar)+0.1 mol/L Cl^-+0 (a), 0.05 (b), 0.1 (c) and 0.5 (d) mol/L HCO₃^- at 60℃

Fig.10 Cross-sectional SEM morphologies of carbon steel after 24 h immersion tests in solutions containing CO₂ (1 bar)+0.1 mol/L Cl^-+0 (a), 0.05 (b), 0.1 (c) and 0.5 (d) mol/L HCO₃^- at 60℃

Fig.11 XRD patterns of corrosion products formed on the steel surfaces immersed in solutions containing CO₂ (1 bar)+0.1 mol/L Cl^-+0.05/0.5 mol/L HCO₃^- over the immersion time period of 24 h at 60℃

Fig.12 Nyquist plots of impedance diagrams for carbon steel after 24 h immersion in solutions containing CO₂ (1 bar)+0.1 mol/L Cl^-+0/0.05/0.1/0.5 mol/L HCO₃^- at 60℃

1	Zhao J H, Wang X Q, Kang J, et al. Crack propagation behavior during DWTT for X80 pipeline steel processed via ultra-fast cooling technique [J]. Chin. J. Mater. Res., 2017, 31(10): 728
	赵金华, 王学强, 康健等. 超快冷工艺下X80管线钢的DWTT裂纹扩展行为 [J]. 材料研究学报, 2017, 31(10): 728
2	Han X, Yu S, Li H, et al. Preparation and Properties of CuO Superhydrophobic Coating on X90 Pipeline Steel [J]. Chin. J. Mater. Res., 2017, 31(9): 672
	韩祥祥, 于思荣, 李好等. X90管线钢表面CuO超疏水涂层的制备和性能 [J]. 材料研究学报, 2017, 31(9): 672
3	Sun J, Zhang G, Liu W, et al. The formation mechanism of corrosion scale and electrochemical characteristic of low alloy steel in carbon dioxide-saturated solution [J]. Corros. Sci., 2012, 57: 131
4	Zhang G A, Lu M X, Wu Y S. Morphology and microstructure of CO₂ corrosion scales [J]. Chin. J. Mater. Res., 2005, 19(5): 537
	张国安, 路民旭, 吴荫顺. CO₂腐蚀产物膜的微观形貌和结构特征 [J]. 材料研究学报, 2005, 19(5): 537
5	Nešić S. Key issues related to modelling of internal corrosion of oil and gas pipelines-A review [J]. Corros. Sci., 2007, 49(12): 4308
6	Nesic S, Postlethwaite J, Olsen S. An electrochemical model for prediction of corrosion of mild steel in aqueous carbon dioxide solutions [J]. Corrosion, 1996, 52(4): 280
7	Zhu J Y, Tan C T, Bao F H, et al. CO₂ corrosion behaviour of a novel Al-containing low Cr steel in a simulated oilfield formation water [J]. Chin. J. Mater. Res., 2020, 34(6): 443
	朱金阳, 谭成通, 暴飞虎等. 一种新型含Al低Cr合金钢在模拟油田采出液环境下的CO₂腐蚀行为 [J]. 材料研究学报, 2020, 34(6): 443
8	Han J, Nešić S, Yang Y. Spontaneous passivation observations during scale formation on mild steel in CO₂ brines [J]. Electrochim. Acta, 2011, 56(15): 5396
9	Zhang S, Hou L, Du H, et al. A study on the interaction between chloride ions and CO₂ towards carbonsteel corrosion [J]. Corros. Sci., 2020, 167: 108531
10	Xu L, Xiao H, Shang W, et al. Passivation of X65 (UNS K03014) carbon steel in NaHCO₃ solution in a CO₂ environment [J]. Corros. Sci., 2016, 109: 246
11	Liu Z, Gao X, Li J, et al. Corrosion behaviour of low-alloy martensite steel exposed to vapour-saturated CO₂ and CO₂-saturated brine conditions [J]. Electrochim. Acta, 2016, 213: 842
12	Barker R, Burkle D, Charpentier T, et al. A review of iron carbonate (FeCO₃) formation in the oil and gas industry [J]. Corros. Sci., 2018, 142: 312
13	Linter B R, Burstein G T. Reactions of pipeline steels in carbon dioxide solutions [J]. Corros. Sci., 1999, 41(1): 117
14	Remita E, Tribollet B, Sutter E, et al. Hydrogen evolution in aqueous solutions containing dissolved CO₂: quantitative contribution of the buffering effect [J]. Corros. Sci., 2008, 50(5): 1433
15	Almeida T D C, Bandeira M C E, Moreira R M. New insights on the role of CO₂ in the mechanism of carbon steel corrosion [J]. Corros. Sci., 2017, 120: 239
16	Kahyarian A, Brown B, Nesic S. Electrochemistry of CO₂ corrosion of mild steel: Effect of CO₂ on iron dissolution reaction [J]. Corros. Sci., 2017, 129: 146
17	Ashley G W, Burstein G T. Initial stages of the anodic oxidation of iron in chloride solutions [J]. Corrosion, 1991, 47(12): 908
18	Darwish N A, Hilbert F, Lorenz W J, et al. The influence of chloride ions on the kinetics of iron dissolution [J]. Electrochim. Acta, 1973, 18(6): 421
19	Barcia O E, Mattos O R. The role of chloride and sulphate anions in the iron dissolution mechanism studied by impedance measurements [J]. Electrochim. Acta, 1990, 35(6): 1003
20	Mao X, Liu X, Revie R W. Pitting corrosion of pipeline steel in dilute bicarbonate solution with chloride ions [J]. Corrosion, 1994, 50(9): 651
21	Zhang G, Lu M, Chai C, et al. Effect of HCO₃^- concentration on CO₂ corrosion in oil and gas fields [J]. Int. J. Min. Met. Mater., 2006, 13(1): 44
22	Wright R F, Brand E R, Ziomek-Moroz M, et al. Effect of HCO₃^- on electrochemical kinetics of carbon steel corrosion in CO₂-saturated brines [J]. Electrochim. Acta, 2018, 290: 626
23	Onyejia L, Mohammed S, Kale G. Electrochemical response of micro-alloyed steel under potentiostatic polarization in CO₂ saturated brine [J]. Corros. Sci., 2018, 138: 146
24	Popoola L T, Grema A S, Latinwo G K, et al. Corrosion problems during oil and gas production and its mitigation [J]. Int. J. Ind. Chem., 2013, 4(1): 35
25	Heuer J K, Stubbins J F. An XPS characteristic of FeCO₃ films from CO₂ corrosion [J]. Corros. Sci., 1999, 41(7): 1231
26	Zhang D L, Wei E Z, Jing H, et al. Construction of super-hydrophobic structure on surface of super ferritic stainless steel B44660 and its corrosion resistance [J]. Chin. J. Mater. Res., 2021, 35(1): 7
	张大磊, 魏恩泽, 荆赫等. 超级铁素体不锈钢表面超疏水结构的制备及其耐腐蚀性能 [J]. 材料研究学报, 2021, 35(1): 7
27	Davies D H, Burstein G T. The effect of bicarbonate on the corrosion and passivation of iron [J]. Corrosion, 1980, 36(8): 416
28	Kermani M B, Morshed A. Carbon dioxide corrosion in oil and gas production-A compendium [J]. Corrosion, 2003, 59(8): 659

[1]	MAO Jianjun, FU Tong, PAN Hucheng, TENG Changqing, ZHANG Wei, XIE Dongsheng, WU Lu. Kr Ions Irradiation Damage Behavior of AlNbMoZrB Refractory High-entropy Alloy[J]. 材料研究学报, 2023, 37(9): 641-648.
[2]	SONG Lifang, YAN Jiahao, ZHANG Diankang, XUE Cheng, XIA Huiyun, NIU Yanhui. Carbon Dioxide Adsorption Capacity of Alkali-metal Cation Dopped MIL125[J]. 材料研究学报, 2023, 37(9): 649-654.
[3]	ZHAO Zhengxiang, LIAO Luhai, XU Fanghong, ZHANG Wei, LI Jingyuan. Hot Deformation Behavior and Microstructue Evolution of Super Austenitic Stainless Steel 24Cr-22Ni-7Mo-0.4N[J]. 材料研究学报, 2023, 37(9): 655-667.
[4]	SHAO Hongmei, CUI Yong, XU Wendi, ZHANG Wei, SHEN Xiaoyi, ZHAI Yuchun. Template-free Hydrothermal Preparation and Adsorption Capacity of Hollow Spherical AlOOH[J]. 材料研究学报, 2023, 37(9): 675-684.
[5]	XING Dingqin, TU Jian, LUO Sen, ZHOU Zhiming. Effect of Different C Contents on Microstructure and Properties of VCoNi Medium-entropy Alloys[J]. 材料研究学报, 2023, 37(9): 685-696.
[6]	OUYANG Kangxin, ZHOU Da, YANG Yufan, ZHANG Lei. Microstructure and Tensile Properties of Mg-Y-Er-Ni Alloy with Long Period Stacking Ordered Phases[J]. 材料研究学报, 2023, 37(9): 697-705.
[7]	XU Lijun, ZHENG Ce, FENG Xiaohui, HUANG Qiuyan, LI Yingju, YANG Yuansheng. Effects of Directional Recrystallization on Microstructure and Superelastic Property of Hot-rolled Cu71Al18Mn11 Alloy[J]. 材料研究学报, 2023, 37(8): 571-580.
[8]	XIONG Shiqi, LIU Enze, TAN Zheng, NING Likui, TONG Jian, ZHENG Zhi, LI Haiying. Effect of Solution Heat Treatment on Microstructure of DZ125L Superalloy with Low Segregation[J]. 材料研究学报, 2023, 37(8): 603-613.
[9]	LIU Jihao, CHI Hongxiao, WU Huibin, MA Dangshen, ZHOU Jian, XU Huixia. Heat Treatment Related Microstructure Evolution and Low Hardness Issue of Spray Forming M3 High Speed Steel[J]. 材料研究学报, 2023, 37(8): 625-632.
[10]	YOU Baodong, ZHU Mingwei, YANG Pengju, HE Jie. Research Progress in Preparation of Porous Metal Materials by Alloy Phase Separation[J]. 材料研究学报, 2023, 37(8): 561-570.
[11]	REN Fuyan, OUYANG Erming. Photocatalytic Degradation of Tetracycline Hydrochloride by g-C₃N₄ Modified Bi₂O₃[J]. 材料研究学报, 2023, 37(8): 633-640.
[12]	WANG Hao, CUI Junjun, ZHAO Mingjiu. Recrystallization and Grain Growth Behavior for Strip and Foil of Ni-based Superalloy GH3536[J]. 材料研究学报, 2023, 37(7): 535-542.
[13]	LIU Mingzhu, FAN Rao, ZHANG Xiaoyu, MA Zeyuan, LIANG Chengyang, CAO Ying, GENG Shitong, LI Ling. Effect of Photoanode Film Thickness of SnO₂ as Scattering Layer on the Photovoltaic Performance of Quantum Dot Dye-sensitized Solar Cells[J]. 材料研究学报, 2023, 37(7): 554-560.
[14]	QIN Heyong, LI Zhentuan, ZHAO Guangpu, ZHANG Wenyun, ZHANG Xiaomin. Effect of Solution Temperature on Mechanical Properties and γ' Phase of GH4742 Superalloy[J]. 材料研究学报, 2023, 37(7): 502-510.
[15]	GUO Fei, ZHENG Chengwu, WANG Pei, LI Dianzhong. Effect of Rare Earth Elements on Austenite-Ferrite Phase Transformation Kinetics of Low Carbon Steels[J]. 材料研究学报, 2023, 37(7): 495-501.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed