Effect of Polyamide 650 on Ring-opening Polymerization of Benzoxazine and Performance of Polybenzoxazine

doi:10.11901/1005.3093.2019.223

Chinese Journal of Materials Research

2019, Vol. 33

Issue (11): 857-864 DOI: 10.11901/1005.3093.2019.223

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Effect of Polyamide 650 on Ring-opening Polymerization of Benzoxazine and Performance of Polybenzoxazine

ZHU Yongfei(

),LI Peilin,SU Junming,YU Shujuan

Guangxi Key Laboratory of Natural Polymer Chemistry and Physics, College of Chemistry and Materials of Nanning Normal University, Nanning 530001, China

Cite this article:

ZHU Yongfei,LI Peilin,SU Junming,YU Shujuan. Effect of Polyamide 650 on Ring-opening Polymerization of Benzoxazine and Performance of Polybenzoxazine. Chinese Journal of Materials Research, 2019, 33(11): 857-864.

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Abstract

The mixtures of polyamide 650 (O-PA) and benzoxazine were prepared to investigate the effect of O-PA on the ring-opening polymerization (ROP) of benzoxazine and the toughness of polybenzoxazine, while the ROP process of O-PA/benzoxazine mixtures was monitored by means of gelation time measurement, DSC and FTIR. The results show that O-PA could accelerate the ROP reaction of benzoxazine resulting in remark decrease of the gelation time, initial and peak temperatures of ROP of benzoxazine. However, the structures evolution during the ROP process of benzoxazine and chemical structures of polybenzoxazine hardly changed with the incorporation of O-PA. The toughness of polybenzoxazine increased obviously with the addition of O-PA. The addition of O-PA made the thermal stability of polybenzoxazine decrease a little. Thereby, polyamide 650 is a kind of excellent catalysis for benzoxazine.

Key words: organic polymer materials benzoxazine polyamide 650 ring-opening polymerization toughness thermal stability

Received: 30 April 2019

ZTFLH:

TQ323

Fund: Natural Science Foundation of Guangxi Autonomous Region(2018GXNSFAA138057)

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	Yongfei ZHU
	Peilin LI
	Junming SU
	Shujuan YU

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https://www.cjmr.org/EN/10.11901/1005.3093.2019.223 OR https://www.cjmr.org/EN/Y2019/V33/I11/857

Table 1 Effect of O-PA on the gelation time of Ba (160℃), Pddm (170℃) and Pa (180℃)

Fig.1 DSC curves of O-PA/benzoxazine (a) O-PA/Ba; (b) O-PA/Pa; (c) O-PA/Pddm

Table 2 DSC results of O-PA/Pa, O-PA/Ba and O-PA/Pddm mixtures

Fig.2 Interaction between O-PA and benzoxazine or polybenzoxazine

Fig.3 FTIR spectra of Ba (a) and 10Ba (b) at the different cured stages

Fig.4 DSC curves of Ba (a) and 10Ba (b) for the different heating rate

Fig.5 Kissinger (a) and Ozawa (b) fitting curves of Ba and 10Ba

Fig.6 FTIR spectra of PBa and the cured O-PA/Ba

Fig.7 Effect of O-PA on the impact strength of polybenzoxazine

Fig.8 Effect of O-PA on the thermal stability of PBa (a) TGA curves; (b) DTG curves

Table 3 TGA results of the effect of O-PA on the thermal stability of polybenzoxazine

Fig.9 TGA results of the cured O-PA/benzoxazineO-PA/PPddm (a) and O-PA/PPa (b)

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