Preparation and Electrochemical Behavior of MoP Nanoparticles as Anode Material for Lithium-ion Batteries

doi:10.11901/1005.3093.2017.793

Chinese Journal of Materials Research

2019, Vol. 33

Issue (1): 65-71 DOI: 10.11901/1005.3093.2017.793

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Preparation and Electrochemical Behavior of MoP Nanoparticles as Anode Material for Lithium-ion Batteries

Yadan XIAO,Xiaozhe JIN,Hao HUANG(

),Aimin WU,Song GAO,Jia LIU

Key Laboratory of Materials Modification by Laser, Ion and Electron Beams Ministry of Education, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China

Cite this article:

Yadan XIAO,Xiaozhe JIN,Hao HUANG,Aimin WU,Song GAO,Jia LIU. Preparation and Electrochemical Behavior of MoP Nanoparticles as Anode Material for Lithium-ion Batteries. Chinese Journal of Materials Research, 2019, 33(1): 65-71.

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Abstract

Molybdenum phosphide (MoP) is successfully prepared by a facile 2-step process. First as precursor, nano metal Mo-powders were prepared via DC arc plasma method, which then react with red phosphorus through solid-phase reaction to yield MoP nanoparticles. The prepared MoP nanoparticles were further characterized by means of XRD and TEM. Results show that the MoP nanoparticles are spherical with particle diameter of 20-50 nm. As the anode material for lithium-ion batteries, MoP nanoparticles deliver the initial discharge capacity of 746 mAh/g at the current density of 100 mA/g and the capacity maintains at 241.9 mAh/g after 50 charge-discharge cycles. As the current density increased to 2000 mA/g the discharge capacity decreases to 99.90 mAh/g. The constant capacity of 247.60 mAh/g can be restored when the current density is back to 100 mA/g.

Key words: inorganic non-metallic materials molybdenum phosphide nanoparticles DC arc disch-arge electrochemical perfor-mance lithium-ion battery anode material

Received: 19 January 2018

ZTFLH:

O646，TM912.9

Fund: Fundamental Research Funds for the Central Universities(DUT17ZD101);National Natural Sci-ence Foundation of China(51171033);Science and Technology Supported Plan (Industry Field) of Changzhou(CE20160022)

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	Yadan XIAO
	Xiaozhe JIN
	Hao HUANG
	Aimin WU
	Song GAO
	Jia LIU

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https://www.cjmr.org/EN/10.11901/1005.3093.2017.793 OR https://www.cjmr.org/EN/Y2019/V33/I1/65

Fig.1 XRD patterns of (a) Mo and (b) MoP and (c) the crystalline structure of MoP

Fig.2 TEM images of the as-prepared (a, b) Mo and (c, d) MoP at different magnifications

Fig.3 Cyclic voltammogram of MoP nanoparticles

Fig.4 Electrochemical performance of MoP anode (a) cycling performance of MoP at 100 mA/g; (b) discharge/charge curves for MoP at 100 mA/g; (c) cycle performance of the MoP at different current densities

Fig.5 EIS curves (a) and equivalent circuit (b) of MoP anode materials

Table 1 Equivalent circuit parameters of MoP anode materials

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