Influence of Ionic Liquid [Emim]BF4 on Nucleation and Growth of PbO2 during Electrodeposition

doi:10.11901/1005.3093.2016.581

Chinese Journal of Materials Research

2017, Vol. 31

Issue (10): 765-772 DOI: 10.11901/1005.3093.2016.581

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Influence of Ionic Liquid [Emim]BF₄ on Nucleation and Growth of PbO₂ during Electrodeposition

Juanqin XUE(

), Jian ZHANG, Lei WANG, Lihua YU, Changbin TANG, Qiang BI

School of Metallurgical Engineering, Xi'an University Of Architecture and Technology, Xi'an 710055, China

Cite this article:

Juanqin XUE, Jian ZHANG, Lei WANG, Lihua YU, Changbin TANG, Qiang BI. Influence of Ionic Liquid [Emim]BF₄ on Nucleation and Growth of PbO₂ during Electrodeposition. Chinese Journal of Materials Research, 2017, 31(10): 765-772.

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Abstract

The effect of 1- ethyl -3- methyl imidazole tetrafluoroborate ([Emim]BF₄) on the nucleation and growth of PbO₂coating on glassy carbon electrode was studied during the electrodeposition process by means of in-situ cyclic voltammetry, chronopotentiometry and chronoamperometry with an electrochemical workstation. Besides, the surface morphology and crystal structure of PbO₂ coating was characterized by SEM and XRD. The results show that PbO₂ electrodeposition process follows the three-dimensional continuous nucleation model, the addition of ionic liquid in the electrolyte does not significantly change the electrocrystallization mechanism of PbO₂, but can inhibit the nucleation and crystal growth rate of PbO₂, so as to decrease the PbO₂ grain size, densify the coating and enhance the electrochemical performance of the resulted PbO₂ electrode.

Key words: metallic materials PbO₂ electrodeposition nucleation growth ionic liquid [Emim]BF₄

Received: 08 October 2016

ZTFLH:

TQ153

Fund: Supported by National Natural Science Foundation of China (Nos.51478379 & 51408468), Major Basic Research Projects of Shaanxi Provincial Natural Science Foundation (No.2017ZDJC-25) and Special Research Project of Shaanxi Provincial Department of Education (No.16JK1422)

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	Juanqin XUE
	Jian ZHANG
	Lei WANG
	Lihua YU
	Changbin TANG
	Qiang BI

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https://www.cjmr.org/EN/10.11901/1005.3093.2016.581 OR https://www.cjmr.org/EN/Y2017/V31/I10/765

Fig.1 Cyclic voltammetry curves of PbO₂ in the electrodeposition on glassy carbon (GC) electrode

Fig.2 Potential time transient curves of PbO₂ in the electrodeposition process on GC electrode

Fig.3 Current time transient curves of PbO₂ in the electrodeposition process on GC electrode under different over potentials: (a) blank, (b) 50 mg/L[Emim]BF₄

Fig.4 Comparisons current time transient non-dimensional curves of PbO₂ in the electrode electrodeposition on GC under different over potentials and the theoretical nucleation curves (a) blank, (b) 50 mg/L[Emim]BF4

Table 1 Kinetic parameters obtained from transient current curves of PbO₂during electrode deposition on GC electrode

Table 2 Kinetic parameters of transient current curves of PbO₂ during electrode deposition in the bath with 50 mg/L[Emim]BF₄

Fig.5 Relationships between crystal growth rate and over potential

Fig.6 Relationships between the nucleation rate constant and the over potential

Fig.7 Relationships between the saturated nucleation density and the over potential

Fig.8 SEM morphologies of PbO₂ planted on Ti in different plating solutions: (a, c) blank, (b, d) 50 mg/L[Emim]BF₄

Fig.9 SEM cross sections of PbO₂planted on Ti in different plating solutions (a, c) blank, (b, d) 50 mg/L[Emim]BF₄

Fig.10 XRD spetra of PbO₂ coatings electroplated in different plating solutions

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