Preparation and Properties of CuO Superhydrophobic Coating on X90 Pipeline Steel

doi:10.11901/1005.3093.2016.416

Chinese Journal of Materials Research

2017, Vol. 31

Issue (9): 672-678 DOI: 10.11901/1005.3093.2016.416

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Preparation and Properties of CuO Superhydrophobic Coating on X90 Pipeline Steel

Xiangxiang HAN, Sirong YU(

), Hao LI, Jinhui HU

College of Mechanical and Electronic Engineering,China University of Petroleum,Qingdao 266580,China

Cite this article:

Xiangxiang HAN, Sirong YU, Hao LI, Jinhui HU. Preparation and Properties of CuO Superhydrophobic Coating on X90 Pipeline Steel. Chinese Journal of Materials Research, 2017, 31(9): 672-678.

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Abstract

Superhydrophobic coating of CuO was prepared on X90 pipeline steel substrate by a three step process, i.e. first a Cu protective layer was electrodeposited on the substrate, which then was treated by hydrothermal reaction and finally modified with perfluorooctanoic solution. The phase constitution, microstructure, chemical composition, and wettability of the coating were investigated by X-ray diffractometer, scanning electron microscope, Fourier transform infrared spectrometer, and contact angle tester. Its mechanical stability, anti-adhesion behavior and corrosion resistance were also examined. The results show that the perfluorooctanoic was successfully grafted on the surface of coating consisted of petal-like CuO with micro-nano hybrid structure. The contact angle of water to the coating surface was 161.24°, and the sliding angle was about 3°. Meanwhile, the as-prepared coating surface exhibits excellent mechanical stability, anti-adhesion behavior and corrosion resistance.

Key words: metallic materials superhydrophobic mechanical stability anti-adhesion corrosion resistance

Received: 19 July 2016

ZTFLH:

TB34

Fund: Supported by National Natural Science Foundation of China (No.51075184)

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	Xiangxiang HAN
	Sirong YU
	Hao LI
	Jinhui HU

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https://www.cjmr.org/EN/10.11901/1005.3093.2016.416 OR https://www.cjmr.org/EN/Y2017/V31/I9/672

Fig.1 Surface topography and wettability of coating surface after different procedures (a) electrodeposition, (b) hydrothermal reaction, (c) PFOA modification

Fig.2 XRD patterns of coating surface before (a) and after (b) hydrothermal reaction

Fig.3 FT-IR patterns of PFOA (a) and coating surface after modification (b)

Fig.4 Schematic illustration of the abrasion test (a) and the CA and SA of the CuO superhydrophobic coating surface changed with the abrasion length (b)

Fig.5 Surface topography of CuO superhydrophobic surface after abrasion for1000 mm (a) 5000x, (b) 20000x

Fig.6 Contact, squeezing, and departure processes of 3 μL water droplet with the CuO superhydrophobic coating surface; The arrows show the moving direction of droplet

Fig.7 Evolution process of the self-cleaning behavior of the CuO superhydrophobic coating surface (a) hover, (b) sliding, (c) cleaning

Fig.8 Water droplet adsorbed and took away the pollutant particles on the CuO superhydrophobic coating surface (a) contact, (b) moving, (c) hover; The arrows show the moving direction of droplet

Fig.9 Potentiodynamic polarization curves of X90 pipeline steel, Cu coating, CuO coating and CuO superhydrophobic coating

Table 1 Relevant electrochemical parameters of potentiodynamic polarization curves of surface after different procedures

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