Preparation and Electrorheological Properties of Imidazolium-based Poly (ionic liquid) Microspheres

doi:10.11901/1005.3093.2016.594

Chinese Journal of Materials Research

2017, Vol. 31

Issue (9): 679-686 DOI: 10.11901/1005.3093.2016.594

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Preparation and Electrorheological Properties of Imidazolium-based Poly (ionic liquid) Microspheres

Zhigang ZHANG, Hongyang ZHANG, Bonan HAO, Meng WANG, Haiquan ZHANG, Yingdan LIU(

), Zhenlin ZHANG(

)

State Key Laboratory of Metastable Materials Science and Technology, College of Materials Science and Engineering, Yanshan University, Qinhuangdao 066004, China

Cite this article:

Zhigang ZHANG, Hongyang ZHANG, Bonan HAO, Meng WANG, Haiquan ZHANG, Yingdan LIU, Zhenlin ZHANG. Preparation and Electrorheological Properties of Imidazolium-based Poly (ionic liquid) Microspheres. Chinese Journal of Materials Research, 2017, 31(9): 679-686.

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Abstract

Imidazolium-based poly(ionic liquid) (PIL) microspheres, poly(1-dodecyl-3-vinylimidazolium tetrafluoroborate) (P[C₁₂VIm][BF₄]), were synthesized through a dispersion polymerization process. The structure and morphology of the PIL microspheres were characterized by means of ¹H nuclear magnetic resonance, Fourier infrared spectrometer, X- ray diffractometer and scanning electron microscopy. Their electrorheological and dielectric properties were measured by rotational rheometer and broad-band dielectric spectrometer, respectively. The results show that imidazolium-based PIL material is well-defined microspheres and has excellent thermal stability. In this PIL electrorheological system, a remarkable electrorheological effect was observed, in which shear stress, viscosity and dynamic modulus increase with the increasing electric field strength.

Key words: organic polymer materials poly(ionic liquid) electrorheology dispersion polymerization imidazolium

Received: 11 October 2016

ZTFLH:

O632.6

Fund: Supported by National Natural Science of Foundation of China (Nos.21403186 & 51703193), Natural Science Foundation of Hebei Province (No.E2015203257), and Colleges and Universities Science and Technology Research Project of Hebei Province (No.QN20131070)

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	Articles by authors
	Zhigang ZHANG
	Hongyang ZHANG
	Bonan HAO
	Meng WANG
	Haiquan ZHANG
	Yingdan LIU
	Zhenlin ZHANG

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https://www.cjmr.org/EN/10.11901/1005.3093.2016.594 OR https://www.cjmr.org/EN/Y2017/V31/I9/679

Fig.1 Synthesis route of P[C₁₂VIm][BF₄] microspheres

Fig.2 SEM images of P[C₁₂VIm][BF₄] spherical particles (a) low magnification, (b) high magnification

Fig.3 XRD patterns of P[C₁₂VIm][BF₄] particles

Fig.4 ¹H NMR spectrum of [C₁₂VIm][BF₄] monomer and P[C₁₂VIm][BF₄] particles

Fig.5 FT-IR spectra of (a)[C₁₂VIm][BF₄], (b) P[C₁₂VIm][BF₄]

Fig.6 TGA curve of P[C₁₂VIm][BF₄] particles

Fig.7 P[C₁₂VIm][BF₄] spherical particles based ER fluid at a fixed shear rate (γ=1 s^-1) in the electric field with a square voltage pulse (t = 30 s)

Fig.8 Shear stress of P[C₁₂VIm][BF₄] ER fluid as a function of the shear rate under various electric strengths (T=23℃)

Table 1 Parameters in the equations of CCJ model obtained by fitting the models CCJ to the shear stress curves of P[C₁₂VIm][BF₄] based ER fluid

Fig.9 Dynamic yield stress as a function of electric field strength for P[C₁₂VIm][BF₄] particles based ER fluid

Fig.10 Flow curves of shear viscosity vs. shear rate for the ER fluid of P[C₁₂VIm][BF₄] particles under various electric fields (T=23℃)

Fig.11 Amplitude sweep of the P[C₁₂VIm][BF₄] microsphere (15 w) ER fluid at 10 rads^-1of angular frequency under various electric field strengths (storage modulus G', solid symbol and loss modulus G′′, open symbol)

Fig.12 Frequency sweep of the P[C₁₂VIm][BF₄] microsphere (15 w) ER fluid with a fixed strain amplitude of 0.003%, which is selected in the linear viscoelastic range of the sample (storage modulus G', solid symbol and loss modulus G′′, open symbol)

Fig.13 Dielectric spectra (Dielectric constant (ε′): solid symbol; Dielectric loss factor (ε″):open symbol) (a) and Cole- Cole equation fitting curve (b) of the P[C₁₂VIM][BF₄] particles based ER fluid

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