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Chinese Journal of Materials Research  2016, Vol. 30 Issue (11): 855-860    DOI: 10.11901/1005.3093.2015.479
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Preparation and Properties of Graphene-based Conductive Paper
Songnan NAN1,2,Hongwei ZHANG1,Qingwen WANG1,**()
1. State Key Lab of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
2. Patent Examination Cooperation Center of the Patent Office, SIPO, Zhengzhou 450002, China
Cite this article: 

Songnan NAN, Hongwei ZHANG, Qingwen WANG. Preparation and Properties of Graphene-based Conductive Paper. Chinese Journal of Materials Research, 2016, 30(11): 855-860.

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Abstract  

Tea polyphenols and aluminum flakes was utilized as the reductants to reduce graphene oxide and then synthesize graphene, the as-prepared graphene was then to prepare the graphene-based conductive paper recombination with cellulose. The influence of composite ratio between cellulose and graphene, the conductive paper ration, the folding times and angles to the conductive paper’s electrical property were discussed. The results show that graphene oxide can be reduced effectively by tea polyphenols and aluminum flakes, the sp2structure can be restored effectively. The optimal conditions is composite ratio between cellulose and graphene 1:1, the conductive paper ration 72 g/m2, the sheet resistanceand elasticity modulus of the as-prepared conductive paper is 66.33 Ω/sqand 1234.00 MPa. The conductive paper reserved good conductivity after 500 times folding and different folding angles, the ratio between after-folded resistanceand initial resistance is near 1.0. Besides, the specific capacitance of the conductive paper is 5.47 mF/cm2, which suggests a good capacitive performance.

Key words:  inorganic non-metallic materials      cellulose      grapheme      conductive paper      sheet resistance     
Received:  27 August 2015     
Fund: *Supported by State Key Laboratory of Pulp and Paper Engineering Nos. 2014C24, ZD201401 & 2016C13.

URL: 

https://www.cjmr.org/EN/10.11901/1005.3093.2015.479     OR     https://www.cjmr.org/EN/Y2016/V30/I11/855

Fig.1  Preparation process of graphene-based conductive paper
Fig.2  FTIR spectra of GO and RGO
Fig.3  AFM images of RGO nanosheets
Fig.4  Influence of different composite ratio between cellulose and graphene to conductive paper's sheet resistance
Fig.5  Influence of different composite ratio between cellulose and graphene to conductive paper's elasticity modulus
Fig.6  Influence of paper weight to conductive paper's sheet resistance
Fig.7  Influence of paperweight to conductive paper's elasticity modulus
Fig.8  Influence of folding cycles and angels to the conduction stability of conductive paper
Fig.9  Electrical pathways presentation of conductive paper (a) Bending angle is 0° (b) bending angle is 90°
Fig.10  CV curves of graphene-based conductive paper
1 Geim A K, Graphene: status and prospects, Science, 324(5934), 1530(2009)
2 Geim A K, Novoselov K S,The rise of graphene, Nature materials. 6(3), 183(2007)
3 Liu L, Niu Z, Zhang L, Zhou W, Chen X, Xie S, Nanostructured Graphene Composite Papers for Highly Flexible and Foldable Supercapacitors, Advanced Materials, 26(28), 4855(2014)
4 Kang Y, Li Y, Hou F, Wen Y, Su D, Fabrication of electric papers of graphene nanosheet shelled cellulose fibres by dispersion and infiltration as flexible electrodes for energy storage, Nanoscale, 4(10), 3248(2012)
5 Ruoff R.Graphene: Calling all chemists, Nature Nanotechnology, 3(1), 10(2008)
6 Chua C K, Pumera M, Chemical reduction of graphene oxide: a synthetic chemistry viewpoint, Chemical Society Reviews, 43(1), 291(2013)
7 Park S, Ruoff R S, Chemical methods for the production of graphenes, Nature nanotechnology, 4(4), 217(2009)
8 Yang D, Velamakanni A, Bozoklu G, Park S, Stoller M, Piner R D, Stankovich S, Jung I, Field D A, Ventrice C A, Ruoff R S, Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and micro-raman spectroscopy, Carbon, 47(1), 145(2009)
9 Shin K Y, Hong J Y, Jang J, Micropatterning of graphene sheets by inkjet printing and its wideband dipole-antenna application, Advanced Materials, 23(18), 2113(2011)
10 Murugan A V, Muraliganth T, Manthiram A, Rapid, Facile microwave-solvothermal synthesis of graphene nanosheets and thei-polyaniline nanocomposites for energy strorage, Chemistry of Materials, 21(21), 5004(2009)
11 Shin H, Kim K K, Benayad A, Yoon S, Park H K, Jung I, Jin M H, Jeong H, Kim J M, Choi J, Lee Y H, Efficient reduction of graphite oxide by sodium borohydride and its effect on electrical conductance, Advanced Functional Materials, 19(12), 1987(2009)
12 Chen C, Chen T, Wang H, Sun G, Yang X, A rapid, one-step, variable-valence metal ion assisted reduction method for graphene oxide, Nanotechnology, 22(40), 405602(2011)
13 HU Xiufang, SHEN Shengrong, Jae-il Park, YANG Xianqiang, Review on Antioxidative Mechanism of Tea Polyphenols, Journal of Tea Science, (02), 93(1999)
13 (胡秀芳, 沈生荣, 朴宰日, 杨贤强, 茶多酚抗氧化机理研究现状, 茶叶科学, (02), 93(1999))
14 LI Hua, LIU Yuming, Studies on antioxidation of tea-polyphenol-silver and tea-polyphenol-zine complexes, Chemistry and Industry of Forest Products, (04), 94(2004)
14 (李华, 刘玉明,茶多酚银、茶多酚锌配合物抗氧化活性的研究, 林产化学与工业, (04), 94(2004))
15 Department of inorganic chemistry, Dalian University of Technology, Inorganic Chemistry, Fourth edition, (Beijing, Higher Education Press, 2001)
15 (大连理工大学无机化学教研室, 无机化学, 第四版, (北京, 高等教育出版社, 2001))
16 Fan Z, Wang K, Wei T, Yan J, Song L, Shao B, An environmentally friendly and efficient route for the reduction of graphene oxide by aluminum powder, Carbon, 48(5), 1686(2010)
17 LI Hua, The study of the relationship between structures and antioxidant activities of TP and TP-metal, Master thesis, Sichuan University, 2004
17 (李华, 茶多酚及其金属化合物构效关系的研究, 硕士学位论文, 四川大学, 2004)
18 Hummers W S, Offeman R E, Preparation of Graphitic Oxide, Journal of the American Chemical Society, 80(6), 1339(1958)
19 GB/T1552-1995,Test method for measuring resistivity of monocrystal silicon and germanium with a collinear four-probe array, National Technical Supervision Bureau, 1995
19 (GB/T 1552-1995, 硅、锗单晶电阻率测定直排四探针法, 国家技术监督局, 1995)
20 Feng Y, Feng N, Du G, A green reduction of graphene oxide via starch-based materials, RSC Advances, 3(44), 21466(2013)
21 Dey R S, Hajra S, Sahu R K, Raj C R, Panigrahi M K, A rapid room temperature chemical route for the synthesis of graphene: metal-mediated reduction of graphene oxide, Chemical Communications, 48(12), 1787(2012)
22 Nethravathi C, Rajamathi M, Chemically modified graphene sheets produced by the solvothermal reduction of colloidal dispersions of graphite oxide, Carbon, 46(14), 1994(2008)
23 Szabó T, Berkesi O, Dékány I, Drift study of deuterium-exchanged graphite oxide, Carbon, 43(15), 3186(2005)
24 Zhao Yaoxing, Sun Xiangyu, Spectral identification of organic molecular structure, Second Edition, (Beijing, Science Press, 2003)
24 (赵瑶兴, 孙祥玉, 有机分子结构光谱鉴定, 第二版, (北京, 科学出版社, 2003))
25 ZHU Hongwei, XU Zhiping, XIE Dan, Graphene: Structure, Preparation and Characterization, (Beijing, Science Press, 2011)
25 (朱宏伟, 徐志平, 谢丹,石墨烯, 结构、制备方法与性能表征, (清华大学出版社, 2011)
26 CHEN Yongsheng, HUANGYi, Graphene: a new two-dimensional carbon nanomaterials (Beijing, Science Press, 2011)
26 (陈永胜, 黄毅, 石墨烯, 新型二维碳纳米材料 (北京, 科学出版社, 2013))
27 Ouyang W, Sun J, Memon J, Wang C, Geng J, Huang Y, Scalable preparation of three-dimensional porous structures of reduced graphene oxide/cellulose composites and their application in supercapacitors, Carbon, 62, 501(2013)
28 Hyun W J, Park O O, Chin B D, Foldable Graphene Electronic Circuits Based on Paper Substrates, Advanced Materials, 25(34), 4729(2013)
29 Gao K, Shao Z, Wu X, Wang X, Li J, Zhang Y, Wang W, Wang F.Cellulose nanofibers/reduced graphene oxide flexible transparent conductive paper, Carbohydrate Polymers, 97(1), 243(2013)
30 Gao Y, Shi W, Wang W, Leng Y, Zhao Y, Inkjet Printing Patterns of Highly Conductive Pristine Graphene on Flexible Substrates, Industrial & Engineering Chemistry Research, 53(43), 16777(2014)
31 HU Huili, LI Ning, Electrochemical measurement (Beijing, National Defence Industry Press, 2007)
31 (胡会利, 李宁, 电化学测量(北京, 国防工业出版社, 2007))
32 Yan J, Fan Z, Wei T, Cheng J, Shao B, Wang K, Song L, Zhang M, Carbon nanotube/MnO2 composites synthesized by microwave-assisted method for supercapacitors with high power and energy densities, Journal of Power Sources, 194(2), 1202(2009)
33 Conway B E,Electrochemical supercapacitors: scientific fundamentals and technological applications,New York: Kluwer Academic/Plenum Publishers, 1999: Chap.15
34 Carlberg J C, Ingan?s O.Poly (3, 4-ethylenedioxythiophene) as Electrode Material in Electrochemical Capacitors, Journal of the Electrochemical Society, 144(4), L61(1997)
35 Alper J P, Vincent M, Carraro C, Maboudian R, Silicon carbide coated silicon nanowires as robust electrode material for aqueous micro-supercapacitor, Applied Physics Letters, 100(16), 163901(2012)
36 An K H, Kim W S, Park Y S, Moon J M, Bae D J, Lim S C ? L, Electrochemical Properties of High-Power Supercapacitors Using Single-Walled Carbon Nanotube Electrodes, Advanced Functional Materials, 11(5), 387(2001)
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