Influenced of Hydrothermal- and High temperature-Treatment on Luminescence Properties of BiPO4: Tb3+ Nanocrystals

doi:10.11901/1005.3093.2015.415

Chinese Journal of Materials Research

2016, Vol. 30

Issue (2): 156-160 DOI: 10.11901/1005.3093.2015.415

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Influenced of Hydrothermal- and High temperature-Treatment on Luminescence Properties of BiPO₄: Tb³⁺ Nanocrystals

YANG Liusai^**(

), XIE Aili, YANG Qintao, PENG Siyan

(School of Chemistry and Chemical Engineering, Shangrao Normal University, Shangrao 334001, China)

Cite this article:

YANG Liusai, XIE Aili, YANG Qintao, PENG Siyan. Influenced of Hydrothermal- and High temperature-Treatment on Luminescence Properties of BiPO₄: Tb³⁺ Nanocrystals. Chinese Journal of Materials Research, 2016, 30(2): 156-160.

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Abstract

Nanocrystals of BiPO₄ and BiPO₄: Tb³⁺were prepared by a room-temperature co-precipitation method, and then followed by post hydrothermal- and high temperature-treatment. X-ray diffraction (XRD) analyses indicated that all the prepared samples are crystalline as a pure low-temperature monoclinic phase of BiPO₄. The spectra of BiPO₄: Tb³⁺ powders showed the characteristics of Tb³⁺ emission at 544 nm corresponding to the transition of ⁵D₄→⁷F₅ under irradiation of 370 nm light. Finally, the processing parameters were further optimized to acquire the BiPO₄: Tb³⁺to possess proper crystallinity, surface hydration layers and ethanol species, and thereby to get optimal luminescence performance for the BiPO₄: Tb³⁺powders.

Key words: inorganic non-metallic materials BiPO4: Tb3+ hydrothermal annealing treatment nanocrystals luminescence properties

Received: 21 July 2015

ZTFLH:

TB34

Fund: *Supported by Youth Foundation of Shangrao Normal University No.2013QN02 and Innovative Education Program for College Students No.098006

About author: **To whom correspondence should be addressed, Tel: 15270501837, E-mail: yangliusai@126.com

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	Liusai YANG
	Aili XIE
	Qintao YANG
	Siyan PENG

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https://www.cjmr.org/EN/10.11901/1005.3093.2015.415 OR https://www.cjmr.org/EN/Y2016/V30/I2/156

Fig.1 XRD spectra of BiPO₄ and BiPO₄: Tb³⁺ nanocrystals. Vertical bars at the bottom denote the standard data for low-temperature monoclinic phase LT-BiPO₄ (JCPDS, No. 15-0767)

Table 1 Comparison of luminescence intensity, morphology and crystalsizes of BiPO₄and BiPO₄: Tb³⁺

Fig.2 TEM images and size distributions of BiPO₄ and BiPO₄: Tb³⁺nanocrystals

Fig.3 FT-IR spectra of BiPO₄and BiPO₄: Tb³⁺nanocrystals

Fig.4 Photoluminescence excitation (λ_em=544 nm) and emission spectra (λ_ex=370 nm) of BiPO₄and BiPO₄: Tb³⁺nanocrystals

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